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91.发明授权公开(公告)号：US09908840B2
公开(公告)日：2018-03-06
申请号：US14043917
申请日：2013-10-02
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor： Robert H. Grubbs , Alexey Fedorov , Anton Toutov , Nicholas A. Swisher
IPC: C07D249/18 , C07D213/48 , C07D213/74 , C07D235/10 , C07D239/42 , C07D241/20 , C07C223/06 , C07C309/31 , C07C209/28 , C07C37/50 , C07C1/22 , C07C37/055 , C07C209/62 , C07C319/06 , C07F7/08
CPC classification number: C07C209/28 , C07B2200/05 , C07C1/22 , C07C37/055 , C07C37/50 , C07C209/62 , C07C319/06 , C07F7/081 , C07F7/0814 , C07C39/15 , C07C15/06 , C07C15/16 , C07C15/18 , C07C15/14 , C07C15/04 , C07C15/02 , C07C15/24 , C07C211/48 , C07C321/26
Abstract: The present invention describes chemical systems and methods for reducing C—O, C—N, and C—S bonds, said system comprising a mixture of (a) at least one organosilane and (b) at least one strong base, said system being substantially free of a transition-metal compound, and said system optionally comprising at least one molecular hydrogen donor compound, molecular hydrogen, or both.
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92.发明授权公开(公告)号：US09895467B2
公开(公告)日：2018-02-20
申请号：US15154039
申请日：2016-05-13
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor： Robert H. Grubbs , Shane L. Mangold
IPC: C08F2/46 , C08F2/50 , C08G61/04 , A61L27/50 , C08F222/38 , A61L27/04 , A61L27/14 , A61F2/16 , A61F9/00
CPC classification number: A61L27/50 , A61F2/1627 , A61F2/1635 , A61F2/1659 , A61F9/00 , A61L27/047 , A61L27/14 , A61L2400/06 , A61L2400/12 , A61L2430/16 , C08F2/48 , C08F222/385 , C08F220/20
Abstract: This disclosure relates compositions comprising upconverting nanocrystals and photoactive compositions and methods using these compositions to modify treat myopia and other ocular conditions. In some cases, the methods use near infrared irradiation to adjust the refractive power of light adjustable ocular lenses. Other methods improve the mechanical strength of the sclera directly.
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公开(公告)号：US09809607B2
公开(公告)日：2017-11-07
申请号：US14818417
申请日：2015-08-05
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor： Anton Toutov , Kerry Betz , Alexey Fedorov , Brian M. Stoltz , Wenbo Liu , Robert H. Grubbs
IPC: C08G75/00 , C07F7/08 , C07D209/12
CPC classification number: C07F7/0801 , C07D209/12 , C07F7/0827 , C07F7/0832
Abstract: The present invention describes chemical systems and methods for silylating aromatic organic substrates, said system or method comprising or consisting essentially of a mixture of (a) at least one organosilane and (b) at least one strong base, the definition of strong base now also including KOH, said system being preferably, but not necessarily substantially free of a transition-metal compound, and said methods comprising contacting a quantity of the organic substrate with a mixture of (a) at least one organosilane and (b) at least one strong base, under conditions sufficient to silylate the aromatic substrate.
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公开(公告)号：US09701704B2
公开(公告)日：2017-07-11
申请号：US15074545
申请日：2016-03-18
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor： Choon Woo Lee , Robert H. Grubbs , Pablo E. Guzman , Tonia S. Ahmed , T. Patrick Montgomery
IPC: C07F15/00 , B01J31/28 , C07C67/30 , C07D313/00 , C07C67/475 , B01J31/12
CPC classification number: C07F15/0046 , B01J31/122 , B01J31/28 , B01J2231/543 , B01J2531/821 , C07B2200/09 , C07C67/293 , C07C67/30 , C07C67/333 , C07C67/475 , C07C2601/10 , C07D313/00 , C08F2500/25 , C08G61/08 , C08G2261/3322 , C08G2261/418 , C07C69/74 , C07C69/16 , C07C69/78 , C07C69/76
Abstract: This invention relates generally to olefin metathesis catalyst compounds, to the preparation of such compounds, and the use of such catalysts in the metathesis of olefins and olefin compounds, more particularly, in the use of such catalysts in (E)-selective olefin metathesis reactions. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.
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公开(公告)号：US09636428B2
公开(公告)日：2017-05-02
申请号：US14492324
申请日：2014-09-22
Inventor： Carl M. Blumenfeld , Karn Sorasaenee , Harry B. Gray , Robert H. Grubbs
CPC classification number: A61K49/16 , A61K47/557 , A61K49/00 , A61K49/0052 , A61K49/0058
Abstract: The present disclosure is directed to sulfonic esters of metal oxides including those of formulas I and II:
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Patent Agency Ranking
公开(公告)号：US09586883B2
公开(公告)日：2017-03-07
申请号：US14255049
申请日：2014-04-17
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor： Zachary K. Wickens , Bill Morandi , Robert H. Grubbs , Kacper Skakuj , Sarah M. Bronner
IPC: C07C45/34 , C07C249/04 , C07C253/00 , C07C201/12 , C07C205/44 , C07C209/60 , C07C213/00 , C07C227/08 , C07C51/373 , C07C59/235 , C07C211/48 , C07C217/48 , C07D301/22
CPC classification number: C07C45/34 , C07C51/373 , C07C201/12 , C07C205/44 , C07C209/60 , C07C213/00 , C07C227/08 , C07C249/04 , C07C253/00 , C07D301/22 , C07C59/235 , C07C211/48 , C07C217/48 , C07C229/18 , C07C47/02 , C07C47/11 , C07C47/14 , C07C47/19 , C07C47/198 , C07C47/277
Abstract: This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising: (a) a dichloro-palladium complex; (b) a copper complex; (c) a source of nitrite; under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde.
Abstract translation: 本公开涉及制备有机醛的方法，每种方法包括使末端烯烃与氧化混合物接触，所述氧化混合物包含：（a）二氯 - 钯络合物; （b）铜络合物; （c）亚硝酸盐源; 在需氧反应条件下，足以将至少一部分末端烯烃转化为醛。
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公开(公告)号：US09575212B2
公开(公告)日：2017-02-21
申请号：US14188961
申请日：2014-02-25
Applicant: California Institute of Technology
Inventor： Robert H. Grubbs , Garret M. Miyake , Raymond Weitekamp , Victoria Piunova
CPC classification number: G02B1/005 , G02B5/3016 , G02B6/1225
Abstract: Described herein are copolymers constructed from chiral, non-racemic monomers, which self-assemble to photonic crystals. The difficulty of incorporating chiral elements into photonic crystals has limited the ability to generate unique bandstructures for different circular polarizations of light. The materials and methods described herein relate to easily, predictably fabricating chiral photonic crystals having desirable optical properties.
Abstract translation: 本文描述的是由手性非外消旋单体构成的共聚物，其自组装成光子晶体。 将手性元素掺入光子晶体的困难限制了为不同的光的圆偏振产生独特的带结构的能力。 本文所述的材料和方法涉及容易地，可预测地制造具有期望的光学性质的手性光子晶体。
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公开(公告)号：US09573125B2
公开(公告)日：2017-02-21
申请号：US13928155
申请日：2013-06-26
Applicant: California Institute of Technology
Inventor： Raymond Weitekamp , Robert H. Grubbs
IPC: B01J31/22 , C08F4/44 , C07D233/02 , B01J31/16 , C07F9/6506 , B01J31/02
CPC classification number: B01J31/22 , B01J31/0259 , B01J31/1625 , B01J31/2273 , B01J2231/543 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2540/64 , C07F9/6506 , Y02P20/582
Abstract: An efficient method for the preparation of backbone-substituted imidazolinium salts for use as N-heterocyclic carbene ligands, e.g., for organometallic catalysts is provided. These functionalized N-heterocyclic carbene ligands are used to prepare solid-supported catalysts, e.g., for olefin metathesis.
Abstract translation: 提供了用于制备用作N-杂环卡宾配体的骨架取代的咪唑啉鎓盐的有效方法，例如用于有机金属催化剂。 这些官能化的N-杂环卡宾配体用于制备固体负载的催化剂，例如用于烯烃复分解。
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99.发明授权Birefringent polymer brush structures formed by surface initiated ring-opening metathesis polymerization 有权通过表面起始开环易位聚合形成的双折射聚合物刷结构公开(公告)号：US09234985B2
公开(公告)日：2016-01-12
申请号：US14061070
申请日：2013-10-23
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor： Robert H. Grubbs , Raymond Weitekamp
CPC classification number: G02B5/3083 , G02B1/04 , G02B1/08 , G02B1/10 , H01L51/0041 , H01L51/0579 , Y02E10/549
Abstract: The disclosure describes a polymer brush structure exhibiting birefringence, said polymer brush structure comprising a plurality of substantially parallel oriented polymers and characterized by a longitudinal z-direction having a first refractive index, nz, and a lateral x,y-direction having a second refractive index, nx,y, wherein the difference, Δn, between the first refractive index and the second refractive index is in a range of about 0.1 to about 0.6, as measured by ellipsometry and fit to a Cauchy analytical model.
Abstract translation: 本发明描述了显示双折射的聚合物刷结构，所述聚合物刷结构包括多个基本上平行的取向聚合物，其特征在于具有第一折射率nz的纵向z方向和具有第二折射率的横向x，y方向 指数，nx，y，其中第一折射率和第二折射率之间的差值Dgr n在约0.1至约0.6的范围内，如通过椭偏仪测量并适合于Cauchy分析模型。
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公开(公告)号：US20150202331A1
公开(公告)日：2015-07-23
申请号：US14492324
申请日：2014-09-22
Inventor： Carl M. Blumenfeld , Karn Sorasaenee , Harry B. Gray , Robert H. Grubbs
CPC classification number: A61K49/16 , A61K47/557 , A61K49/00 , A61K49/0052 , A61K49/0058
Abstract: The present disclosure is directed to sulfonic esters of metal oxides including those of formulas I and II:
Abstract translation: 本公开涉及包括式I和II的金属氧化物的磺酸酯：
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