公开(公告)号：US09334174B2

公开(公告)日：2016-05-10

申请号：US14353132

申请日：2012-01-27

Applicant: Kazuya Kobiro ,  Pengyu Wang ,  Takeshi Ohama

Inventor： Kazuya Kobiro ,  Pengyu Wang ,  Takeshi Ohama

IPC: C01G23/053 ,  C12N15/89 ,  B82Y5/00 ,  B82Y40/00

CPC classification number: C01G23/053 ,  B82Y5/00 ,  B82Y40/00 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/32 ,  C12N15/895 ,  Y02P20/544 ,  Y10S977/773 ,  Y10S977/896 ,  Y10S977/916 ,  Y10T428/2982

Abstract: Problem. Provided are a method for synthesizing spherical porous titanium oxide nanoparticles, which is easy to operate, does not take a long time for synthesis, and can easily adjust the particle diameter and the pore diameter of the spherical porous titanium oxide nanoparticles in accordance with the application thereof; spherical porous titanium oxide nanoparticles produced by the synthesizing method; and a gene gun carrier consisting of the spherical porous titanium oxide nanoparticles. Solution. A method for synthesizing spherical porous titanium oxide nanoparticles, includes: a step of reacting titanium isopropoxide and carboxylic acid in supercritical fluid, wherein the supercritical fluid is supercritical methanol, and the carboxylic acid is formic acid, acetic acid, benzoic acid, o-phthalic acid, fumaric acid, or maleic acid.

Abstract translation: 问题。 提供了一种合成球形多孔氧化钛纳米粒子的方法，其易于操作，不需要很长时间的合成，并且可以根据应用容易地调节球形多孔氧化钛纳米颗粒的粒径和孔径 的; 通过合成方法生产的球形多孔氧化钛纳米颗粒; 和由球形多孔氧化钛纳米颗粒组成的基因枪载体。 解。 一种球形多孔氧化钛纳米粒子的合成方法，其特征在于，在超临界流体中使异丙醇钛与羧酸反应，超临界流体为超临界甲醇，羧酸为甲酸，乙酸，苯甲酸，邻苯二甲酸 酸，富马酸或马来酸。

公开(公告)号：US20160108313A1

公开(公告)日：2016-04-21

申请号：US14878424

申请日：2015-10-08

Applicant: INTELLIGENT MATERIAL SOLUTIONS, INC. ,  THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA

Inventor： Joshua E. COLLINS ,  Howard Y. BELL ,  Xingchen YE ,  Christopher Bruce MURRAY

IPC: C09K11/77 ,  C01F17/00

CPC classification number: C09K11/7791 ,  B42D15/00 ,  B82Y30/00 ,  C01F17/0031 ,  C01F17/0043 ,  C01F17/0062 ,  C01F17/0087 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/84 ,  C01P2004/04 ,  C01P2004/10 ,  C01P2004/11 ,  C01P2004/16 ,  C01P2004/20 ,  C01P2004/32 ,  C01P2004/40 ,  C01P2004/42 ,  C01P2004/52 ,  C01P2004/62 ,  C01P2004/64 ,  C09K11/7773 ,  C30B7/08 ,  Y10T428/2933

Abstract: Monodisperse particles having: a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology are disclosed. Due to their uniform size and shape, the monodisperse particles self assemble into superlattices. The particles may be luminescent particles such as down-converting phosphor particles and up-converting phosphors. The monodisperse particles of the invention have a rare earth-containing lattice which in one embodiment may be an yttrium-containing lattice or in another may be a lanthanide-containing lattice. The monodisperse particles may have different optical properties based on their composition, their size, and/or their morphology (or shape). Also disclosed is a combination of at least two types of monodisperse particles, where each type is a plurality of monodisperse particles having a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology; and where the types of monodisperse particles differ from one another by composition, by size, or by morphology. In a preferred embodiment, the types of monodisperse particles have the same composition but different morphologies. Methods of making and methods of using the monodisperse particles are disclosed.

公开(公告)号：US09318739B2

公开(公告)日：2016-04-19

申请号：US13925971

申请日：2013-06-25

Applicant: SUMITOMO METAL MINING CO., LTD.

Inventor： Hiroyuki Toya ,  Kazuomi Ryoshi ,  Toshiyuki Osako

IPC: H01M4/88 ,  H01M4/485 ,  C01G53/00 ,  H01M10/052 ,  H01M4/131 ,  H01M4/36 ,  H01M4/48 ,  H01M4/1391 ,  H01M10/04 ,  H01M4/02

CPC classification number: H01M4/131 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/88 ,  H01M4/1391 ,  H01M4/362 ,  H01M4/483 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0427 ,  H01M10/052 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54

Abstract: To obtain a non-aqueous electrolyte secondary battery having high capacity, high output and good cyclability, nickel manganese composite hydroxide particles are a precursor for a cathode active material having lithium nickel manganese composite oxide with a hollow structure and a small and uniform particle size.An aqueous solution for nucleation includes a metallic compounds that contains nickel and a metallic compound that contains manganese, but does not include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt. After nucleation is performed, an aqueous solution for particle growth is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 9.5 to 11.5, and is less than the pH value in the nucleation step.

Abstract translation: 为了获得具有高容量，高产出和良好循环性能的非水电解质二次电池，镍锰复合氢氧化物颗粒是具有中空结构和小而均匀粒径的具有锂镍锰复合氧化物的阴极活性材料的前体。 用于成核的水溶液包括含有镍的金属化合物和含有锰的金属化合物，但不包括与镍，锰和钴形成复合离子的复合离子形成剂。 在成核后，控制用于颗粒生长的水溶液使溶液的温度为60℃或更高，并且使得在25℃的标准溶液温度下测量的pH值为9.5至 11.5，并且小于成核步骤中的pH值。

公开(公告)号：US20160101988A1

公开(公告)日：2016-04-14

申请号：US14749212

申请日：2015-06-24

Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： Matthew Law ,  Sean Seefeld ,  James Puthussery

IPC: C01G49/12 ,  C23C16/22 ,  B05D1/18 ,  C23C16/56 ,  B05D1/00 ,  B05D1/02

CPC classification number: C01G49/12 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/64 ,  C01P2006/22 ,  C23C16/22 ,  C23C16/305 ,  C23C16/4417 ,  C23C16/56 ,  H01L31/032 ,  H01L31/072 ,  Y02E10/50

Abstract: Systems and methods are provided for the fabrication and manufacture of efficient, low-cost p-n heterojunction pyrite solar cells. The p-n heterojunction pyrite solar cells can include a pyrite thin cell component, a window layer component, and a top surface contact component. The pyrite thin cell component can be fabricated from nanocrystal paint deposited onto metal foils or microcrystalline pyrite deposited onto foil by chemical vapor deposition. A method of synthesizing colloidal pyrite nanocrystals is provided. Methods of manufacturing the efficient, low-cost p-n heterojunction pyrite solar cells are also provided.

Abstract translation: 提供了制造和制造高效，低成本的p-n异质结黄铁矿太阳能电池的系统和方法。 p-n异质结黄铁矿太阳能电池可以包括黄铁矿薄电池组件，窗口层组件和顶表面接触部件。 黄铁矿薄电池组件可以由沉积在通过化学气相沉积沉积到箔上的金属箔或微晶黄铁矿上的纳米晶体涂料制成。 提供了一种合成胶体黄铁矿纳米晶体的方法。 还提供了制造有效的低成本p-n异质结黄铁矿太阳能电池的方法。

公开(公告)号：US09302258B2

公开(公告)日：2016-04-05

申请号：US14238917

申请日：2012-08-14

Applicant: Jong-San Chang ,  U-Hwang Lee ,  Young Kyu Hwang ,  Dong Won Hwang ,  You-Kyong Seo ,  Ji Sun Lee ,  Ji Woong Yoon ,  Kyu Eun Shim

Inventor： Jong-San Chang ,  U-Hwang Lee ,  Young Kyu Hwang ,  Dong Won Hwang ,  You-Kyong Seo ,  Ji Sun Lee ,  Ji Woong Yoon ,  Kyu Eun Shim

IPC: B01J31/06 ,  C01G23/00 ,  C01G25/00 ,  C01G31/00 ,  C01G37/00 ,  C01G49/00 ,  C01G3/00 ,  B01J20/26 ,  B01J20/30 ,  B01J20/22 ,  B01J20/28

CPC classification number: B01J31/06 ,  B01J20/226 ,  B01J20/26 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/3028 ,  B01J20/3064 ,  C01G3/006 ,  C01G23/002 ,  C01G25/006 ,  C01G31/006 ,  C01G37/006 ,  C01G49/009 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  Y02P20/129 ,  Y10T428/2982

Abstract: The present invention relates to a complex and a method for manufacturing same, the complex comprising: at least one crystalline hybrid nanoporous material powder, in which a metal ion, or a metal ion cluster to which oxygen is bound, and an organic ligand, or the organic ligand and a negative ion ligand are in a coordinate covalent bond; and at least one organic polymer additive, or at least one organic polymer additive and an inorganic additive, wherein the shape of the complex is spherical or pseudo-spherical, the size of the complex is 0.1 to 100 mm, a total volume of pores is 5 or more volume % based on the sum of a total volume of nanoporous material having a size of at most 10 nm and a total volume of pores having a size of at least 0.1 μm, and wherein a non-surface value per weight (m2/g) of the complex as at least 83% of a non-surface value per weight (m2/g) of the nanoporous material powder.

Abstract translation: 复合物及其制造方法本发明涉及复合物及其制造方法，该复合物包括：至少一种结晶杂化纳米多孔材料粉末，其中金属离子或与其结合的金属离子簇和有机配体，或 有机配体和负离子配体处于配位共价键; 和至少一种有机聚合物添加剂或至少一种有机聚合物添加剂和无机添加剂，其中络合物的形状是球形或假球形，复合物的尺寸为0.1至100mm，孔的总体积为 基于总体积为至多10nm的纳米多孔材料和总体积为至少0.1μm的孔的总体积的5或更多体积％，并且其中每重量的非表面值（m2 / g）为每重量％（m 2 / g）的非表面值的至少83％的纳米多孔材料粉末。

公开(公告)号：US20160089334A1

公开(公告)日：2016-03-31

申请号：US14892385

申请日：2014-05-14

Applicant: MITSUI CHEMICALS, INC.

Inventor： Norio NAKAYAMA ,  Hongbo WANG ,  Haruyuki MAKIO

IPC: A61K9/14 ,  F16L59/02 ,  C08K7/26 ,  C01B33/12

CPC classification number: A61K9/14 ,  C01B13/32 ,  C01B33/12 ,  C01B37/02 ,  C01P2004/04 ,  C01P2004/32 ,  C01P2004/45 ,  C01P2004/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/16 ,  C01P2006/17 ,  C08K7/24 ,  C08K7/26 ,  C08L101/00 ,  C09D7/40 ,  C09D7/61 ,  C09D7/66 ,  C09D11/00 ,  C09D11/037 ,  C09D201/00 ,  F16L59/028

Abstract: Provided are porous metal oxide particles, in which 50% mean particle size by volume is equal to or larger than 50 nm and equal to or smaller than 300 nm, ratio of 90% mean particle size by volume to 50% mean particle size by volume (D90/D50) is equal to or lower than 2.0, the particles have mesopores having a pore size determined by BJH method of equal to or larger than 5 nm and equal to or smaller than 30 nm, and the structure of the pores is a three-dimensional cubic phase structure.

Abstract translation: 提供的是多孔金属氧化物颗粒，其中平均粒径为50％的平均粒径等于或大于50nm且等于或小于300nm，平均粒径为90体积％至平均粒径的50％ （D90 / D50）等于或低于2.0，颗粒具有通过BJH方法确定的孔径等于或大于5nm且等于或小于30nm的中孔，并且孔的结构为 三维立方相结构。

公开(公告)号：US09296952B2

公开(公告)日：2016-03-29

申请号：US13376135

申请日：2010-06-01

Applicant: Stanislaw Budzyn ,  Victor Iwanicki ,  Andrzej Sumara ,  Wieslaw Zmuda ,  Christian D'Emal

Inventor： Stanislaw Budzyn ,  Victor Iwanicki ,  Andrzej Sumara ,  Wieslaw Zmuda ,  Christian D'Emal

IPC: C08J11/14 ,  C10B53/07 ,  B82Y30/00 ,  C09C1/48 ,  C10B47/18 ,  C10G1/10

CPC classification number: C10B53/07 ,  B82Y30/00 ,  C01P2004/32 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/19 ,  C08J11/14 ,  C09C1/482 ,  C10B47/18 ,  C10G1/10 ,  C10G2300/1003 ,  C10G2300/4006 ,  C10G2300/4056 ,  C10G2300/4081 ,  C10G2300/805 ,  Y02P20/143

Abstract: The present invention relates to a rubber granulate conversion process comprising steps consisting in: a) pyrolysing the rubber granulates at a temperature between 400 and 500° C. in the presence of water, to obtain a carbonized substance and a gaseous phase; and b) recovering the carbonized substance obtained during the previous step. The invention also relates to the products resulting from the conversion process and to the use of said products.

Abstract translation: 橡胶颗粒转化方法技术领域本发明涉及橡胶颗粒转化方法，其包括以下步骤：a）在水存在下，在400-500℃的温度下热解橡胶颗粒，得到碳化物质和气相; 和b）回收上一步骤中获得的碳化物质。 本发明还涉及由转化过程产生的产物和所述产品的使用。

公开(公告)号：US09296622B2

公开(公告)日：2016-03-29

申请号：US13671150

申请日：2012-11-07

Applicant: HY-POWER NANO INC.

Inventor： Hadi K Mahabadi ,  Juan-Pablo Bravo-Vasquez ,  Sinoj Abraham ,  Guibun Ma ,  Nathan Gerein

IPC: F21V9/04 ,  F21V9/06 ,  G02B5/22 ,  G02B5/26 ,  C01G19/02 ,  G02B1/00 ,  H01B1/08 ,  C01G19/00 ,  G02B5/20 ,  B82Y20/00 ,  B82Y30/00 ,  C03C17/00 ,  C01G17/02 ,  C01G21/02

CPC classification number: C01G19/02 ,  B82Y20/00 ,  B82Y30/00 ,  C01G19/00 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/80 ,  C03C17/007 ,  C03C2217/231 ,  C03C2218/114 ,  G02B1/002 ,  G02B5/206 ,  G02B5/208 ,  G02B2207/101 ,  H01B1/08

Abstract: Disclosed herein are indium-tin-oxide nanoparticles and a method for continuously producing precipitated indium-tin nanoparticles having a particle size range of substantially from about 10 nm to about 200 nm and a substantially consistent ratio of indium to tin in the resultant nanoparticles across the duration of the continuous process, based on the ratio of indium to tin in a seeding solution. The method comprises preparing intermediate indium and tin compounds of the general formula [M(OH)xCy], where M represents the indium or tin ionic component of indium or tin salts, C represents the cationic component of indium or tin salt(s), x is a number greater than 0 and y=[M*valance−x]/C* valance in the seeding solution. The intermediate compounds are continuously precipitated with a base solution in a reaction vessel initially having a solvent contained therein. The method also provides a means for controlling the shape of the resultant nanoparticles. The resultant indium-tin nanoparticles may be further processed into dispersions.

Abstract translation: 本文公开了铟锡氧化物纳米颗粒和用于连续生产具有基本上约10nm至约200nm的粒度范围的沉淀的铟锡纳米颗粒的方法，并且在所得纳米颗粒中的铟与锡的比例基本上一致 基于接种溶液中铟与锡的比例，连续过程的持续时间。 该方法包括制备通式[M（OH）xCy]的中间体铟和锡化合物，其中M表示铟或锡盐的铟或锡离子组分，C表示铟或锡盐的阳离子组分， x是接种溶液中大于0且y = [M * valance-x] / C *值的数。 中间体化合物在最初具有其中包含溶剂的反应容器中用碱溶液连续沉淀。 该方法还提供了用于控制所得纳米颗粒的形状的手段。 所得的铟锡纳米颗粒可进一步加工成分散体。

公开(公告)号：US20160087262A1

公开(公告)日：2016-03-24

申请号：US14962498

申请日：2015-12-08

Applicant: SUMITOMO METAL MINING CO., LTD.

Inventor： Hiroyuki TOYA ,  Kazuomi RYOSHI ,  Toshiyuki OSAKO

IPC: H01M4/131 ,  H01M4/505 ,  H01M4/525

CPC classification number: H01M4/485 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/88 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/362 ,  H01M4/483 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0427 ,  H01M10/052 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54

Abstract: Provided are nickel manganese composite hydroxide particles that are a precursor for forming cathode active material including lithium nickel manganese composite oxide having hollow structure of particles having a small and uniform particle size for obtaining a non-aqueous electrolyte secondary battery having high capacity, high output and good cyclability. When obtaining the nickel manganese composite hydroxide particles from a crystallization reaction, an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel and a metallic compound that contains manganese, and does not include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 11.5 to 13.5, and after nucleation is performed, an aqueous solution for particle growth, which includes the nuclei that were formed in the nucleation step and does not substantially include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 9.5 to 11.5, and is less than the pH value in the nucleation step.

Abstract translation: 提供作为用于形成正极活性物质的前体的镍锰复合氢氧化物颗粒，其包括具有小而均匀粒径的中空结构的锂镍锰复合氧化物，用于获得具有高容量，高产量的非水电解质二次电池， 良好的循环性。 当从结晶反应获得镍锰复合氢氧化物颗粒时，用于成核的水溶液包括至少含有镍的金属化合物和含有锰的金属化合物，并且不包括形成复合离子的复合离子形成剂 控制镍，锰和钴，使得溶液的温度为60℃或更高，并且使得在25℃的标准溶液温度下测量的pH值为11.5至13.5，之后 进行成核，用于颗粒生长的水溶液，其包括在成核步骤中形成的并且基本上不包括与镍，锰和钴形成复合离子的复合离子形成剂的控制，使得温度 该溶液为60℃以上，在25℃的标准溶液温度下测定的pH值为9.5〜11.5，更低 比成核步骤中的pH值。

公开(公告)号：US20160083557A1

公开(公告)日：2016-03-24

申请号：US14889239

申请日：2014-05-19

Applicant: NIPPON ELECTRIC GLASS CO., LTD.

Inventor： Noriaki MASUDA ,  Yohei HOSODA ,  Shingo NAKANE ,  Hiroki YAMAZAKI

IPC: C08K3/40 ,  C09C1/40 ,  C03C3/085 ,  C08K7/20 ,  C03C3/097 ,  C03C3/083

CPC classification number: C08K3/40 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/22 ,  C01P2006/32 ,  C01P2006/60 ,  C03C3/06 ,  C03C3/085 ,  C03C3/097 ,  C03C8/24 ,  C03C10/0009 ,  C03C10/0027 ,  C03C2201/02 ,  C03C2203/10 ,  C08K7/20 ,  C09C1/28

Abstract: Provided is a filler powder that has a lower coefficient of thermal expansion than silica powder and is less likely to cause quality and color alteration of a resin when blended into the resin. The filler powder is made of a crystallized glass in which β-quartz solid solution and/or β-eucryptite is precipitated. The filler powder preferably has an average particle size D50 of 5 μm or less. The filler powder preferably has a coefficient of thermal expansion of 5×10−7/° C. or less in a range of 30 to 150° C.

Abstract translation: 具有比二氧化硅粉末低的热膨胀系数的填料粉末，并且当混入树脂时不太可能引起树脂的质量和颜色变化。 填充剂粉末由结晶玻璃制成，其中沉淀了石英固溶体和/或重铬酸盐。 填料粉末的平均粒径D50优选为5μm以下。 填料粉末的热膨胀系数优选在30〜150℃的范围内为5×10 -7 /℃以下。