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194 条记录 (耗时 0.055 秒)

    Amicloamine derivatives of carboxylic and thiocarboxylic-functionalized hydrocarbon polymers
    153.
    发明授权
    Amicloamine derivatives of carboxylic and thiocarboxylic-functionalized hydrocarbon polymers 失效

    公开(公告)号：US5672573A

    公开(公告)日：1997-09-30

    申请号：US630055

    申请日：1996-04-10

    申请人： Antonio Gutierrez ,  James P. Stokes

    发明人： Antonio Gutierrez ,  James P. Stokes

    IPC分类号： C10L1/22 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/24 ,  C10L1/26 ,  C10L1/30 ,  C10L10/00 ,  C10M149/06 ,  C10M149/18

    CPC分类号： C10L1/238 ,  C10L1/221 ,  C10L1/2383 ,  C10L1/2475 ,  C10L1/2493 ,  C10L1/2691 ,  C10L1/303 ,  C10L10/04 ,  C10M149/06 ,  C10M2217/024 ,  C10M2217/06 ,  C10N2270/02

    摘要： Processes for preparing amidoamine products derived from hydrocarbon polymers containing carboxylic acid, thioacid, ester or thioester functional groups are disclosed. More particularly, a process is disclosed which comprises the steps of: (A) reacting (i) a hydrocarbon polymer functionalized to contain functional groups of formula --CO--Y--R.sup.3, the hydrocarbon polymer having a number average molecular weight of at least about 500 prior to functionalization, wherein Y is O or S, R.sup.3 is hydrogen, hydrocarbyl, or substituted hydrocarbyl and wherein at least 50 mole % of the functional groups are attached to a tertiary carbon atom of the polymer, with (ii) a volatile amine containing at least two reactive amino groups under conditions effective to amidate at least a portion of the --CO--Y--R.sup.3 functional groups and form a first amidoamine adduct containing at least one reactive amino group; and (B) reacting the first amidoamine adduct with an .alpha.,.beta.-unsaturated compound to form a second amidoamine adduct, wherein the .alpha.,.beta.-unsaturated compound has the formula: ##STR1## wherein X is O or S; Z is OR.sup.7, --SR.sup.7, or --NR.sup.7 (R.sup.8); and R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are the same or different and are hydrogen, hydrocarbyl, or substituted hydrocarbyl. In reaction step (B), the reactive amino groups in the first amidoamine adducts react non-selectively with both the carbon--carbon double bonds and the --C(.dbd.X)Z functional groups in the unsaturated compounds or, with suitable control of the reaction conditions, react selectively with the carbon--carbon double bonds only. In the case of selective reaction, the second amidoamine adduct is characterized by having unreacted --C(.dbd.X)Z functional groups, and the adduct can be further reacted with a second amine in order to amidate the --C(.dbd.X)Z functional groups. The amidoamine products are useful as additives in fuels and lubricating oils.

    Lubricating oil mannich base dispersants derived from heavy polyamine
    156.
    发明授权
    Lubricating oil mannich base dispersants derived from heavy polyamine 失效
    来自重多胺的润滑油甘露糖基分散剂

    公开(公告)号：US5565128A

    公开(公告)日：1996-10-15

    申请号：US322715

    申请日：1994-10-12

    申请人： Antonio Gutierrez

    发明人： Antonio Gutierrez

    IPC分类号： C10L1/234 ,  C08F8/32 ,  C10L1/14 ,  C10L1/22 ,  C10L1/238 ,  C10L10/08 ,  C10L10/18 ,  C10M159/16 ,  C10N30/04 ,  C10N40/25 ,  C01M159/16

    CPC分类号： C10M159/16 ,  C08F8/44 ,  C10L1/143 ,  C10L1/221 ,  C10L1/238 ,  C08F2800/20

    摘要： An oil-soluble lubricating oil additive useful as a dispersant, comprising Mannich Base condensates of an alkyl (hydrocarbon or polymer) substituted hydroxy aromatic compound with an aldehyde and a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.

    摘要翻译： 可用作分散剂的油溶性润滑油添加剂，其包含烷基（烃或聚合物）取代的羟基芳族化合物与醛和重多胺的曼尼希碱缩合物。 重多胺是包含少量低聚多元胺低聚物如四亚乙基五胺和五胺的聚亚烷基多胺的混合物，但主要是具有7个或更多个氮的低聚物，每个分子2个或更多个伯胺，以及比常规多胺混合物更广泛的分支。