Abstract:
Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. The methods include mixing sorbent substrate particles with a sulfide salt and a metal salt to form a metal sulfide on the outer surface of the sorbent particles.
Abstract:
A nanostructured substance, a process for sequestration of ionic waste, and an ion-sequestration apparatus are disclosed in the specification. The nanostructured substance can comprise a Lewis acid transition metal bound to a phosphate, wherein the phosphate comprises a primary structural component of the substance and the Lewis acid transition metal is a reducing agent. The nanostructured substance has a Brunner-Emmet-Teller (BET) surface area greater than or equal to approximately 100 m2/g, and a distribution coefficient for an analyte, Kd, greater than or equal to approximately 5000 ml/g. The process can comprise contacting a fluid and a nanostructured metal phosphate. The apparatus can comprise a vessel and a nanostructured metal phosphate. The vessel defines a volume wherein a fluid contacts the nanostructured metal phosphate.
Abstract:
An exhaust system for an internal combustion engine has a catalysed ceramic wall flow particulate filter coated with a washcoat composition. The washcoat composition includes an oxidation catalyst of at least one platinum group metal and a NOx absorbent. The washcoat composition has a D50 of less than or equal to 8 μm. The NOx absorbent absorbs NOx contained in an exhaust gas when the composition of the exhaust gas is lambda >1, and releases the NOx absorbed in the NOx absorbent when the exhaust gas composition is 1≦lambda. The exhaust system has a platinum group metal catalyst upstream of the filter for oxidising NO to NO2 at least when the composition of the exhaust gas is lambda >1. The uncoated portions of the ceramic wall flow particulate filter have a porosity of >40% and a mean pore size of 8-25 μm.
Abstract:
Rare earth metal compounds, particularly lanthanum, cerium, and yttrium, are formed as porous particles and are effective in binding metals, metal ions, and phosphate. A method of making the particles and a method of using the particles is disclosed. The particles may be used in the gastrointestinal tract or the bloodstream to remove phosphate or to treat hyperphosphatemia in mammals. The particles may also be used to remove metals from fluids such as water.
Abstract:
Supported perovskite-type oxides are described. The perovskite-type oxides have the general formula of AxA′x′ByB′y′O3-δ, wherein A is an ion of a metal of Group IIIa or IIIb of the periodic table of elements or mixtures thereof; A′ is an ion of a metal of Groups Ia or IIa of the periodic table or mixtures thereof; B and B′ are ions of a d-block transition metal of the periodic table or mixtures thereof; x, x′, y and y′ vary from 0 to 1; 0.95
Abstract translation:描述了支承的钙钛矿型氧化物。 钙钛矿型氧化物具有以下通式:A A x B x Y B'y' 其中A是元素周期表IIIa或IIIb族金属的离子或其混合物; A'是周期表的Ia或IIa族金属的离子或其混合物; B和B'是周期表的d-块过渡金属的离子或其混合物; x,x',y和y'从0变化到1; 0.95
Abstract:
A method and recyclable magnetic adsorbent are provided for removing contaminants from a fluid stream that has by-products. The method includes providing an adsorbent material that has incorporated at least one ferromagnetic material. Contacting the ferromagnetic adsorbent material to at least a portion of contaminated stream to adsorb the contaminant. The contaminated adsorbent is then separated from the by-products using a magnetic separation process. The adsorbent is recovered from the solid by-products and reusable in the present method.
Abstract:
The present invention relates to ceric oxide that has excellent heat resistance and oxygen absorbing and desorbing capability useful as a co-catalyst material suitable for a catalyst for purifying exhaust gas, that is capable of maintaining a large specific surface area even in use in a high temperature environment, and that is suitable for use in a high temperature environment, yet capable of exhibiting high oxygen absorbing and desorbing capability also in a lower temperature range, a method for preparing such ceric oxide, and a catalyst for purifying exhaust gas utilizing such ceric oxide. The ceric oxide is an oxide composed essentially of ceric oxide, and has a specific surface area of not smaller than 30.0 m2/g after calcination at 900null C. for 5 hours.
Abstract:
Rare earth metal compounds, particularly lanthanum, cerium, and yttrium, are formed as porous particles and are effective in binding metals, metal ions, and phosphate. A method of making the particles and a method of using the particles is disclosed. The particles may be used in the gastrointestinal tract or the bloodstream to remove phosphate or to treat hyperphosphatemia in mammals. The particles may also be used to remove metals from fluids such as water.
Abstract:
Regenerable gas purifier materials are provided capable of reducing the level of contaminants such as oxygen and moisture in a hydride gas stream to parts-per-billion levels or sub-parts-per-billion levels. The purifier materials of this invention comprise a thin layer of one or more reduced forms of a metal oxide coated on the surface of a nonreactive substrate. The thin layer may further contain the completely reduced form of the metal. In one embodiment, the total surface area of the thin layer is less than 100 m2/g.
Abstract:
To more effectively remove contaminants from fluid streams, several types of metal precursors can be incorporated onto highly ordered mesoporous molecular sieves, such as SBA-15, without producing of clogging effects within pore structures. Lanthanum and aluminum are the most favorable incorporated metals in terms of their adsorption capacities and fluid velocities. The lanthanum impregnated SBA-15 also has a very strong selectivity for arsenic because its adsorption capacities do not deteriorate even if several other anionic species, such as sulfate and nitrate, are found in high concentrations in the fluid along with any arsenic. As a result, these hybrid materials have many advantages for use in POE/POU applications, among others, due to its rapid and high adsorption capacity, and its high selectivity of arsenic for removal from the fluid stream.