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11.发明授权Selective catalysts having high temperature alumina supports for naphtha hydrodesulfurization 有权具有用于石脑油加氢脱硫的高温氧化铝载体的选择性催化剂公开(公告)号：US08637423B2
公开(公告)日：2014-01-28
申请号：US12087979
申请日：2007-01-12
IPC分类号： B01J21/18
CPC分类号： C10G45/08 , B01J21/04 , B01J23/882 , B01J31/16 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/2213 , B01J31/2217 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J37/0018 , B01J37/0203 , B01J37/08 , B01J37/10 , B01J37/20 , B01J2531/64 , B01J2531/845 , C10G2400/02
摘要： This invention relates to a catalyst and method for hydrodesulfurizing naphtha. More particularly, a Co/Mo metal hydrogenation component is loaded on a high temperature alumina support in the presence of a dispersion aid to produce a catalyst that is then used for hydrodesulrurizing naphtha. The high temperature alumina support has a defined surface area that minimizes olefin saturation.
摘要翻译： 本发明涉及一种用于加氢脱硫石脑油的催化剂和方法。 更具体地说，在分散助剂的存在下，将Co / Mo金属氢化组分负载在高温氧化铝载体上，以产生一种催化剂，然后将该催化剂用于石脑油的加氢硬化。 高温氧化铝载体具有使烯烃饱和度最小化的限定表面积。
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公开(公告)号：US08592220B2
公开(公告)日：2013-11-26
申请号：US12447143
申请日：2007-10-26
申请人： H. Sam Bergh , Jason Wells , Victor Wong , John Gallipeo , Lynn Van Erden , Anthony F. Volpe , Jeffrey Maag
发明人： H. Sam Bergh , Jason Wells , Victor Wong , John Gallipeo , Lynn Van Erden , Anthony F. Volpe , Jeffrey Maag
IPC分类号： G01N1/10
CPC分类号： G01N31/10 , B01J19/0046 , B01J2219/00286 , B01J2219/00306 , B01J2219/00389 , B01J2219/00477 , B01J2219/00495 , B01J2219/00585 , B01J2219/00596 , B01J2219/00601 , B01J2219/00689 , B01J2219/00704 , B01J2219/00736 , B01J2219/00747 , C40B60/12
摘要： The present invention discloses an apparatus and method for rapid analysis of members of a combinatorial library. The apparatus includes a plurality of reactor vessels for containing individual library members, a fluid handling system that apportions a test fluid about equally between each of the vessels and a housing for enclosing the reactor vessels, the housing defining a pressure chamber, wherein the housing is configured to sustain a pressure substantially above atmospheric pressure. This allows for simultaneous screening of library members at high pressure by providing a small pressure differential on reactor components. The disclosed apparatus is especially useful for screening library members based on their ability to catalyze the conversion of fluid reactants.
摘要翻译： 本发明公开了一种用于快速分析组合图书馆成员的装置和方法。 该装置包括用于容纳单个文件库构件的多个反应堆容器，在每个容器之间大致相等地分配测试流体的流体处理系统和用于封闭反应堆容器的壳体，壳体限定压力室，其中壳体 被配置为维持基本上高于大气压的压力。 这允许通过在反应器组件上提供小的压差同时筛选高压力下的文库构件。 基于它们催化流体反应物转化的能力，所公开的装置对于筛选文库成员特别有用。
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13.发明授权Selective catalysts having silica supports for naphtha hydrodesulfurization 有权具有用于石脑油加氢脱硫的二氧化硅载体的选择性催化剂公开(公告)号：US08216958B2
公开(公告)日：2012-07-10
申请号：US12087978
申请日：2007-01-12
申请人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. McConnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, Jr. , Jun Han
发明人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. McConnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, Jr. , Jun Han
CPC分类号： C10G45/08 , B01J21/08 , B01J23/882 , B01J31/04 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2208 , B01J35/10 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/0203 , B01J37/20 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2300/80 , C10G2400/02
摘要： A method for hydrodesulfurizing FCC naphtha is described. More particularly, a Co/Mo metal hydrogenation component is loaded on a silica or modified silica support in the presence of organic ligand and sulfided to produce a catalyst which is then used for hydrodesulfurizing FCC naphtha. The silica support has a defined pore size distribution which minimizes olefin saturation.
摘要翻译： 描述了FCC石脑油加氢脱硫方法。 更具体地说，在有机配体存在下将Co / Mo金属氢化组分负载在二氧化硅或改性二氧化硅载体上并硫化以产生催化剂，然后将其用于加氢脱硫FCC石脑油。 二氧化硅载体具有确定的最小化烯烃饱和度的孔径分布。
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公开(公告)号：US08030240B2
公开(公告)日：2011-10-04
申请号：US12316979
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
IPC分类号： B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/405 , B01J29/44 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/12 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括至少两种沸石，包括具有低二氧化硅与氧化铝比的沸石。 催化剂可以与低表面粘合剂组合，或者配制的催化剂可以具有高比例的沸石表面积与外表面积。
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15.发明授权公开(公告)号：US07951746B2
公开(公告)日：2011-05-31
申请号：US11973505
申请日：2007-10-09
申请人： Chuansheng Bai , El-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Jun Han , Daniel Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe, Jr. , David Michael Lowe
发明人： Chuansheng Bai , El-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Jun Han , Daniel Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe, Jr. , David Michael Lowe
IPC分类号： B01J27/047 , B01J27/051 , B01J21/18 , B01J31/00
CPC分类号： B01J31/04 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/049 , B01J27/051 , B01J31/2204 , B01J31/2213 , B01J31/2217 , B01J35/002 , B01J37/086 , B01J37/20 , B01J2231/641 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08 , C10G45/50
摘要： Bulk metallic catalysts comprised of a Group VIII metal and a Group VIB metal and methods for synthesizing bulk metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic acid, such as glyoxylic acid, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要翻译： 提供了由VIII族金属和VIB族金属组成的块状金属催化剂以及合成本体金属催化剂的方法。 催化剂通过其中两种金属的前体混合并与至少一种有机酸相互作用的方法制备，所述有机酸例如乙醛酸，干燥，煅烧和硫化。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。
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16.发明授权Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途公开(公告)号：US07670589B2
公开(公告)日：2010-03-02
申请号：US11521155
申请日：2006-09-14
申请人： Guang Cao , Machteld Maria Mertens , Matu J. Shah , Marc H. Anthonis , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder , Anthony F. Volpe, Jr.
发明人： Guang Cao , Machteld Maria Mertens , Matu J. Shah , Marc H. Anthonis , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder , Anthony F. Volpe, Jr.
IPC分类号： C01B39/04
CPC分类号： C01B39/48 , B01J29/70 , B01J29/7015 , B01J29/80 , C01B37/02 , C01B39/023 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/1011 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R1R2R3N—R4]+Q− wherein R1 and R2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R1 and R2 may be joined to form a nitrogen-containing heterocyclic structure, R3 is an alkyl group having 2 to 4 carbon atoms and R4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R3 and R4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q− is a anion.
摘要翻译： 包含菱沸石型骨架分子筛的结晶材料，特别是高硅石沸石的合成在具有下式的有机导向剂的存在下进行：[R 1 R 2 R 3 N-R 4] + Q-，其中R 1和R 2是 独立地选自具有1至3个碳原子的烃基和羟基取代的烃基，条件是R 1和R 2可以连接形成含氮杂环结构，R 3是具有2至4个碳原子的烷基，R 4是 选自4至8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代; 和具有1至3个杂原子的4至8元杂环基，所述杂环基任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的每个杂原子被选定 由O，N和S组成的组，或R3和R4是具有1至3个碳原子的烃基连接以形成含氮杂环结构; 和Q-是阴离子。
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公开(公告)号：US20090176643A1
公开(公告)日：2009-07-09
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/44 , B01J29/06 , B01J29/40 , B01J29/068
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。
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公开(公告)号：US20090111959A1
公开(公告)日：2009-04-30
申请号：US11599231
申请日：2006-11-14
申请人： Guang Cao , Machteld Maria Mertens , Karl G. Strohmaier , Hailian Li , Robert J. Saxton , Anil S. Guram , Jeffrey C. Yoder , Mark T. Muraoka , Anthony F. Volpe, JR.
发明人： Guang Cao , Machteld Maria Mertens , Karl G. Strohmaier , Hailian Li , Robert J. Saxton , Anil S. Guram , Jeffrey C. Yoder , Mark T. Muraoka , Anthony F. Volpe, JR.
CPC分类号： B01J35/002 , B01D69/148 , B01D71/028 , B01J29/035 , B01J29/70 , B01J2229/62 , C01B37/02 , C01B39/48 , C07C1/20 , C07C1/207 , C07C1/2076 , C07C1/2078 , C07C1/30 , C07C1/322 , C07C1/323 , C07C7/144 , C07C2521/12 , C07C2527/12 , C07C2531/02 , C07C11/02 , C07C9/04
摘要： A crystalline material has a DDR framework type and, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element, Y is a tetravalent element and n is from 0 to less than 0.01 and wherein the crystals of said material have an average diameter less than or equal to 2 microns. The material is synthesized in the presence of an N-ethyltropanium compound as directing agent.
摘要翻译： 结晶材料具有DDR框架型，并且以其煅烧的无水形式具有涉及摩尔关系的组成：<？in-line-formula description =“In-line formula”end =“lead”？>（n） X 2 O 3：YO 2，<β在线式描述=“在线式”末端=“尾”→其中X为三价元素，Y为四价元素，n为0至小于0.01，其中 所述材料的晶体具有小于或等于2微米的平均直径。 该物质在N-乙基anium化合物作为引导剂的存在下合成。
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19.发明申请公开(公告)号：US20080132407A1
公开(公告)日：2008-06-05
申请号：US11973505
申请日：2007-10-09
申请人： Chuansheng Bai , El-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Jun Han , Daniel Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe , David Michael Lowe
发明人： Chuansheng Bai , El-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Jun Han , Daniel Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe , David Michael Lowe
CPC分类号： B01J31/04 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/049 , B01J27/051 , B01J31/2204 , B01J31/2213 , B01J31/2217 , B01J35/002 , B01J37/086 , B01J37/20 , B01J2231/641 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08 , C10G45/50
摘要： Bulk metallic catalysts comprised of a Group VIII metal and a Group VIB metal and methods for synthesizing bulk metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic acid, such as glyoxylic acid, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要翻译： 提供了由VIII族金属和VIB族金属组成的块状金属催化剂以及合成本体金属催化剂的方法。 催化剂通过其中两种金属的前体混合并与至少一种有机酸相互作用的方法制备，所述有机酸例如乙醛酸，干燥，煅烧和硫化。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。
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公开(公告)号：US20100075831A1
公开(公告)日：2010-03-25
申请号：US12316979
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/068 , B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/405 , B01J29/44 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/12 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括至少两种沸石，包括具有低二氧化硅与氧化铝比的沸石。 催化剂可以与低表面粘合剂组合，或者配制的催化剂可以具有高比例的沸石表面积与外表面积。
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