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公开(公告)号：US20150114552A1
公开(公告)日：2015-04-30
申请号：US14404544
申请日：2013-05-30
IPC分类号： C08J5/00 , C08K3/36 , C08L23/06 , B29C43/30 , B29C43/00 , B29C43/32 , B32B37/24 , B29C43/24 , C08K7/26 , C08K3/26
CPC分类号： E04F15/107 , B29B17/0042 , B29C43/003 , B29C43/24 , B29C43/305 , B29C43/32 , B29K2023/0633 , B29K2023/12 , B29K2105/16 , B29K2105/26 , B29K2509/00 , B29L2007/002 , B29L2009/00 , B32B27/20 , B32B27/32 , B32B37/10 , B32B37/12 , B32B37/182 , B32B37/24 , B32B2264/02 , B32B2264/10 , B32B2264/12 , B32B2272/00 , B32B2305/30 , B32B2305/70 , B32B2323/04 , B32B2323/10 , B32B2419/04 , B32B2471/00 , C08J5/00 , C08J2323/06 , C08J2323/12 , C08J2497/02 , C08K3/013 , C08K3/22 , C08K3/26 , C08K3/36 , C08K7/02 , C08K7/14 , C08K7/26 , C08K11/00 , C08K2003/2206 , C08K2003/265 , C08L23/06 , C08L2205/16 , C08L2207/066 , C08L2207/20 , E04F15/02038 , E04F15/105 , Y02W30/62 , Y10T428/24149 , Y10T428/24157 , Y10T428/249991 , Y10T428/28 , Y10T428/2848 , Y10T428/3167 , Y10T428/31678 , Y10T428/31913 , Y10T428/31938 , C08L23/10
摘要： A polymeric composite derived from a reclaimed polymeric material. The polymeric composite in particulate form can be thermally compressed into panels and other embodiments that require a component that possesses sufficient mechanical strength and moisture resistance. In certain embodiments, the panel may be utilized as one layer in a multilayered article.
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12.发明授权Pressure-sensitive adhesive blends comprising ethylene/propylene-derived polymers and propylene-derived polymers and articles therefrom 有权包含乙烯/丙烯衍生的聚合物和丙烯衍生的聚合物的压敏粘合剂共混物及其制品公开(公告)号：US06489400B2
公开(公告)日：2002-12-03
申请号：US09746612
申请日：2000-12-21
IPC分类号： C08L2314
CPC分类号： C08L23/14 , C08L23/10 , C08L2205/02 , C08L2666/04 , C09J123/14 , Y10T428/28 , Y10T428/2878 , Y10T428/31855
摘要： The present invention relates to a blend of at least one amorphous ethylene/propylene-derived copolymer, at least one non-stereoregular propylene-derived polymer having a melt viscosity of greater than about 500 Poise, and an optional tackifier that provide pressure-sensitive adhesive compositions in which a good balance of adequate adhesion to both low and relatively high surface energy substrates can be achieved.
摘要翻译： 本发明涉及至少一种非晶形乙烯/丙烯衍生的共聚物，至少一种熔体粘度大于约500泊的非立构规则丙烯衍生的聚合物和任选的增粘剂，其提供压敏粘合剂 其中可以实现与低和相对高的表面能基底的良好平衡的良好平衡的组合物。
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公开(公告)号：US5616670A
公开(公告)日：1997-04-01
申请号：US537032
申请日：1995-09-29
IPC分类号： C08F220/18 , C08L33/08 , C09J4/00 , C09J7/02 , C09J9/02 , C09J133/08 , F16F9/30 , H05K3/32 , C08F218/00
CPC分类号： F16F9/306 , C08F220/18 , C08L33/08 , C09J133/08 , C09J4/00 , C09J7/0217 , C09J9/02 , C08F2220/1858 , C09J2201/606 , C09J2205/31 , H05K3/323
摘要： A pressure sensitive adhesive that includes the polymerization product of:(a) 25-97 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(b) 3-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(c) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C. The relative amounts of the acrylic acid ester, the non-polar ethylenically unsaturated monomer, and the polar ethylenically unsaturated monomer are chosen such that the 90.degree. peel adhesion of the pressure sensitive adhesive to a surface provided with 1.5.+-.0.25 mg/in.sup.2 oil is greater than zero after a 10 second dwell at room temperature as measured according to Test Procedure B.
摘要翻译： 一种压敏粘合剂，其包括以下聚合产物：（a）25-97重量份的均聚物Tg小于0℃的一元醇的丙烯酸酯; （b）3-75重量份其均聚物的溶解度参数不大于10.50且Tg大于15℃的非极性烯属不饱和单体; 和（c）0-5重量份的均聚物的溶解度参数大于10.50且Tg大于15℃的极性烯属不饱和单体。丙烯酸酯，非极性烯属不饱和单体的相对量 单体和极性烯键式不饱和单体的选择使得压敏粘合剂与提供有1.5 +/- 0.25mg / in 2油的表面的90°剥离粘合力在室温下停留10秒后大于零，如所测量 根据测试程序B.
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公开(公告)号：US5602221A
公开(公告)日：1997-02-11
申请号：US537034
申请日：1995-09-29
IPC分类号： C08F220/18 , C08L33/08 , C09J4/00 , C09J7/02 , C09J9/02 , C09J133/06 , C09J133/08 , F16F9/30 , H05K3/32 , C08F218/00
CPC分类号： F16F9/306 , C08F220/18 , C08L33/08 , C09J133/06 , C09J133/08 , C09J4/00 , C09J7/0217 , C09J9/02 , C08F2220/1858 , C09J2201/606 , C09J2205/31 , H05K3/323
摘要： A pressure sensitive adhesive that includes the polymerization product of:(a) 25-97 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(b) 3-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(c) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C. The relative amounts of the acrylic acid ester, the non-polar ethylenically unsaturated monomer, and the polar ethylenically unsaturated monomer are chosen such that the 90.degree. peel adhesion of the pressure sensitive adhesive to a polypropylene surface is at least 2 lbs/0.5 in. after a 72 hour dwell at room temperature as measured according to Test Procedure B.
摘要翻译： 一种压敏粘合剂，其包括以下聚合产物：（a）25-97重量份的均聚物Tg小于0℃的一元醇的丙烯酸酯; （b）3-75重量份其均聚物的溶解度参数不大于10.50且Tg大于15℃的非极性烯属不饱和单体; 和（c）0-5重量份的均聚物的溶解度参数大于10.50且Tg大于15℃的极性烯属不饱和单体。丙烯酸酯，非极性烯属不饱和单体的相对量 单体和极性烯键式不饱和单体，使得压敏粘合剂与聚丙烯表面的90°剥离粘合力在室温下72小时停留后至少为2磅/ 0.5英寸，根据测试程序B 。
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15.发明授权公开(公告)号：US06861141B2
公开(公告)日：2005-03-01
申请号：US10225755
申请日：2002-08-22
申请人： Gina M. Buccellato , Cristina U. Thomas , Bimal V. Thakkar , Greggory S. Bennett , Sithya S. Khieu , Gary R. Miron
发明人： Gina M. Buccellato , Cristina U. Thomas , Bimal V. Thakkar , Greggory S. Bennett , Sithya S. Khieu , Gary R. Miron
CPC分类号： C09J4/00 , E01F9/512 , E01F9/553 , E01F9/573 , Y10T428/28 , Y10T428/2848 , Y10T428/2852 , Y10T428/2857 , Y10T428/2878 , Y10T428/2883 , C08F220/00
摘要： A pavement marking article that has an adhesive composition for adhering the article to a pavement substrate, where the adhesive composition includes a reaction product of an acrylic acid ester of a monohydric alcohol whose homopolymer has a Tg less than 0° C., a non-polar ethylenically unsaturated monomer, and 0-10 parts by weight of a polar ethylenically unsaturated monomer. Preferably the amount of the acrylic acid ester is about 60-90 parts by weight, and the amount of the non-polar ethylenically unsaturated monomer is about 10-40 parts by weight.Also, a raised pavement marker that comprises: (a) a pavement marker body having upper and lower surfaces and an apparent flexural modulus of at least about 50,000 psi and (b) a pressure sensitive adhesive layer disposed upon the lower surface of the marker, wherein the adhesive has: (i) a transition region that begins at a frequency of about 10,000 radians/s or more and extends to a frequency of about 100 radians/s or less at about 25° C.; and (ii) a minimum shear modulus of about 1×105 Pa at an impact frequency of about 100 radians/s at 25° C.; and (iii) a shear modulus value of about 2×104 to 2×105 Pa at a frequency of 1 rad/sec at 25° C. Raised pavement markers that use a pressure sensitive adhesive meeting parameters (i)-(iii) can demonstrate good adhesion to roadways and are capable of withstanding repeated impacts from motor vehicle tires.
摘要翻译： 一种路面标记制品，其具有用于将所述制品粘附到路面基材上的粘合剂组合物，其中所述粘合剂组合物包含均聚物的Tg低于0℃的一元醇的丙烯酸酯的反应产物， 极性烯属不饱和单体和0-10重量份极性烯属不饱和单体。 优选地，丙烯酸酯的量为约60-90重量份，非极性烯键式不饱和单体的量为约10-40重量份。此外，升高的路面标记包括：（a） 路面标记体具有上表面和下表面以及至少约50,000psi的表观弯曲模量和（b）设置在所述标记物的下表面上的压敏粘合剂层，其中所述粘合剂具有：（i）开始的过渡区域 在约10,000弧度/秒或更大的频率下，在约25℃下延伸至约100弧度/秒以下的频率; 和（ii）在25℃下约100弧度/秒的冲击频率下的约1×10 5 Pa的最小剪切模量; 在25℃下，以1rad / sec的频率，剪切模量值为约2×10 4至2×10 5 Pa。使用满足参数（i） - （iii）的压敏粘合剂的引导路面标记可显示出对 能够承受汽车轮胎的重复冲击。
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公开(公告)号：US06599602B2
公开(公告)日：2003-07-29
申请号：US09324148
申请日：1999-06-02
IPC分类号： B32B1508
CPC分类号： B32B7/12 , B32B15/09 , B32B27/08 , B32B27/365 , B32B2307/414 , B32B2307/714 , B32B2369/00 , B32B2429/02 , C08L33/08 , C08L39/04 , C09J4/00 , C09J5/00 , C09J2400/163 , C09J2433/00 , C09J2469/006 , G11B7/24 , G11B7/2534 , G11B7/2535 , G11B7/256 , G11B7/2585 , G11B7/259 , G11B7/2595 , G11B7/26 , Y10T428/21 , Y10T428/31507 , Y10T428/31551 , Y10T428/31663 , Y10T428/31678 , Y10T428/31681 , Y10T428/31797 , Y10T428/31935 , C08F220/18 , C08F226/06
摘要： An article is disclosed that includes a) a first polycarbonate substrate; b) a second polycarbonate substrate; and c) an adhesive composition disposed between the first polycarbonate substrate and the second polycarbonate substrate such that the first polycarbonate substrate is bonded to said second polycarbonate substrate through the adhesive composition; the adhesive composition includes an adhesive polymer that includes the reaction product of 1) an N-vinyl containing monomer selected from the group consisting of N-vinyl caprolactam, N-vinyl pyrrolidone, and N-vinyl imidazole, and combinations thereof, and 2) an acrylic acid ester monomer of a non-tertiary alcohol having an alkyl group that includes 4 to 20 carbon atoms.
摘要翻译： 公开了一种制品，其包括：a）第一聚碳酸酯基材; b）第二聚碳酸酯基材; 以及c）粘合剂组合物，其设置在所述第一聚碳酸酯基材和所述第二聚碳酸酯基材之间，使得所述第一聚碳酸酯基材通过所述粘合剂组合物结合到所述第二聚碳酸酯基材; 粘合剂组合物包括粘合剂聚合物，其包含1）选自N-乙烯基己内酰胺，N-乙烯基吡咯烷酮和N-乙烯基咪唑的含N-乙烯基单体及其组合的反应产物，和2） 具有含有4〜20个碳原子的烷基的非叔醇的丙烯酸酯单体。
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公开(公告)号：US6126865A
公开(公告)日：2000-10-03
申请号：US816064
申请日：1997-03-11
IPC分类号： C08F220/16 , C08F220/18 , C09J4/00 , C09J7/02 , C09J9/02 , C09J133/06 , C09J133/08 , F16F9/30 , H05K3/32 , H01B1/02
CPC分类号： F16F9/306 , C08F220/18 , C09J133/08 , C09J4/00 , C09J7/0217 , C09J9/02 , C08F2220/1858 , C09J2201/606 , C09J2205/31 , H05K3/321 , H05K3/323 , Y10T428/2804 , Y10T428/2848 , Y10T428/2857 , Y10T428/2891
摘要： Pressure sensitive adhesives and heat activatable adhesives that are the reaction product of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.; a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and an electrically conductive agent.
摘要翻译： 压敏粘合剂和可热活化的粘合剂，其是均聚物Tg小于0℃的一元醇的丙烯酸酯的反应产物; 其均聚物的溶解度参数不大于10.50且Tg大于15℃的非极性烯属不饱和单体; 0-5重量份的均聚物的溶解度参数大于10.50且Tg大于15℃的极性烯属不饱和单体; 和导电剂。
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公开(公告)号：US5773485A
公开(公告)日：1998-06-30
申请号：US522294
申请日：1995-08-23
IPC分类号： B05D7/02 , B05D7/24 , C08F2/02 , C08F2/40 , C08F2/46 , C08F2/48 , C08F2/50 , C08F20/10 , C08F220/10 , C08F291/00 , C09D4/00 , C09D4/06 , C09J4/00 , C09J4/06 , C09J7/00 , C09J7/02 , G03F7/027 , C08F216/36 , C08F131/02
CPC分类号： G03F7/027 , C08F2/48 , C08F2/50 , C08F291/00 , C09D4/06 , C09J4/06 , Y10S522/904 , Y10S522/905
摘要： Solute polymers in solvent monomers form a coatable syrup that can be cured to a viscoelastomeric material when radiation-sensitive hydrogen abstracting groups in either the polymer or one of the monomers are exposed to ultraviolet radiation. The solute polymers can be formed from the solvent monomers.
摘要翻译： PCT No.PCT / US95 / 09502 Sec。 371日期1995年8月23日 102（e）日期1995年8月23日PCT 1995年7月28日PCT Filed溶剂单体中的溶剂聚合物形成可涂覆的糖浆，当聚合物或单体之一中的辐射敏感性氢取代基团可以固化为粘弹性材料时 暴露于紫外线辐射。 溶质聚合物可以由溶剂单体形成。
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公开(公告)号：US5708110A
公开(公告)日：1998-01-13
申请号：US796394
申请日：1997-02-06
IPC分类号： C08F220/18 , C08L33/08 , C09J4/00 , C09J7/02 , C09J9/02 , C09J133/06 , C09J133/08 , F16F9/30 , H05K3/32 , C08F218/00
CPC分类号： F16F9/306 , C08F220/18 , C08L33/08 , C09J133/06 , C09J133/08 , C09J4/00 , C09J7/0217 , C09J9/02 , C08F2220/1858 , C09J2201/606 , C09J2205/31 , H05K3/323
摘要： A pressure sensitive adhesive that includes the polymerization product of: (a) 25-97 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.; (b) 3-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and (c) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C. The relative amounts of the acrylic acid ester, the non-polar ethylenically unsaturated monomer, and the polar ethylenically unsaturated monomer are chosen such that the 90.degree. peel adhesion of the pressure sensitive adhesive to a polypropylene surface is at least 2 lbs/0.5 in. after a 72 hour dwell at room temperature as measured according to Test Procedure B.
摘要翻译： 一种压敏粘合剂，其包括以下聚合产物：（a）25-97重量份的均聚物Tg小于0℃的一元醇的丙烯酸酯; （b）3-75重量份其均聚物的溶解度参数不大于10.50且Tg大于15℃的非极性烯属不饱和单体; 和（c）0-5重量份的均聚物的溶解度参数大于10.50且Tg大于15℃的极性烯属不饱和单体。丙烯酸酯，非极性烯属不饱和单体的相对量 单体和极性烯键式不饱和单体，使得压敏粘合剂与聚丙烯表面的90°剥离粘合力在室温下72小时停留后至少为2磅/ 0.5英寸，根据测试程序B 。
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公开(公告)号：US5708109A
公开(公告)日：1998-01-13
申请号：US796393
申请日：1997-02-06
IPC分类号： C08F220/18 , C08L33/08 , C09J4/00 , C09J7/02 , C09J9/02 , C09J133/08 , F16F9/30 , H05K3/32 , C08F218/00
CPC分类号： F16F9/306 , C08F220/18 , C08L33/08 , C09J133/08 , C09J4/00 , C09J7/0217 , C09J9/02 , C08F2220/1858 , C09J2201/606 , C09J2205/31 , H05K3/323
摘要： A pressure sensitive adhesive that includes the polymerization product of: (a) 25-97 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.; (b) 3-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and (c) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C. The relative amounts of the acrylic acid ester, the non-polar ethylenically unsaturated monomer, and the polar ethylenically unsaturated monomer are chosen such that the 90.degree. peel adhesion of the pressure sensitive adhesive to a surface provided with 1.5.+-.0.25 mg/in.sup.2 oil is greater than zero after a 10 second dwell at room temperature as measured according to Test Procedure B.
摘要翻译： 一种压敏粘合剂，其包括以下聚合产物：（a）25-97重量份的均聚物Tg小于0℃的一元醇的丙烯酸酯; （b）3-75重量份其均聚物的溶解度参数不大于10.50且Tg大于15℃的非极性烯属不饱和单体; 和（c）0-5重量份的均聚物的溶解度参数大于10.50且Tg大于15℃的极性烯属不饱和单体。丙烯酸酯，非极性烯属不饱和单体的相对量 单体和极性烯键式不饱和单体的选择使得压敏粘合剂与提供有1.5 +/- 0.25mg / in 2油的表面的90°剥离粘合力在室温下停留10秒后大于零，如所测量 根据测试程序B.
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