公开(公告)号：US20170349702A1

公开(公告)日：2017-12-07

申请号：US15472379

申请日：2017-03-29

Applicant: SIRRUS, INC.

Inventor： Aniruddha Palsule ,  Jeffrey M. Sullivan ,  Kshitij K. Parab ,  Elliott King ,  William Barrett

IPC: C08G63/60 ,  C07C69/593 ,  C08G64/42 ,  C12P7/62

CPC classification number: C08G63/60 ,  B32B27/36 ,  C07C69/593 ,  C08G63/16 ,  C08G63/52 ,  C08G63/87 ,  C08G64/42 ,  C12P7/62 ,  C12P7/625

Abstract: Disclosed are compositions comprising polyester macromers containing in one or more chains the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes, and optionally one or more dihydrocarbyl dicarboxylates, and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols. The chains may contain the residue of the one or more diols and one or more diesters comprising one or more diesters 1,1-diester-1 alkenes and optionally one or more dihydrocarbyl dicarboxylates randomly disposed along the chains. Disclosed are methods of preparing the polyester macromers and incorporating them in a variety of polyester containing compositions such as coatings and films.

公开(公告)号：US20170349700A1

公开(公告)日：2017-12-07

申请号：US15592829

申请日：2017-05-11

Applicant: SIRRUS, INC.

Inventor： Aniruddha Palsule ,  Jeffrey M. Sullivan ,  Kshitij K. Parab ,  Ami Doshi ,  Alexander R. Holzer ,  Matthew Reilman

IPC: C08G63/16 ,  B32B27/36 ,  C08G63/87 ,  C12P7/62

CPC classification number: C08G63/16 ,  B32B27/36 ,  C08G63/52 ,  C08G63/54 ,  C08G63/87 ,  C08G63/916 ,  C08G64/42 ,  C12P7/625

Abstract: Functionalized compounds including residues of one or more 1,1-disubstituted alkene compounds. Preferably the functionalized compound includes the residue of two or more 1,1-disubstituted alkene compounds, which are spaced apart. The functionalized compound may be produced by a transesterification reaction. The functionalized compounds may be employed in a polymerizable composition and may be used to prepare new polymers, (for example by reacting the alkene group).

公开(公告)号：US09828324B2

公开(公告)日：2017-11-28

申请号：US14868795

申请日：2015-09-29

Applicant: Sirrus, Inc.

Inventor： Jeffrey M. Sullivan ,  Adam G. Malofsky ,  Bernard M. Malofsky ,  Tanmoy Dey

IPC: C07C45/00 ,  C07C49/00 ,  C08L27/12 ,  B03D1/016 ,  C08F214/06 ,  C08L27/00 ,  C07C49/84 ,  C07C45/75 ,  C07C49/203 ,  C07C49/794 ,  C07C49/796 ,  C07D333/22 ,  C07C49/557 ,  C07C49/227 ,  C07D307/46 ,  C07C49/80

CPC classification number: C07C49/84 ,  C07C45/75 ,  C07C49/203 ,  C07C49/227 ,  C07C49/557 ,  C07C49/794 ,  C07C49/796 ,  C07C49/80 ,  C07C2601/14 ,  C07D307/46 ,  C07D333/22

Abstract: The present teachings are directed at 1,1-disubstituted alkene monomers (e.g., methylene beta-diketone monomers), methods for producing the same, and compositions and products formed therefrom. In the method for producing the monomer, a beta-diketone is preferably reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to vaporization in order to isolate the monomer. The monomer(s) may be employed in compositions and products, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

公开(公告)号：US20170240657A1

公开(公告)日：2017-08-24

申请号：US15589274

申请日：2017-05-08

Applicant: Sirrus, Inc.

Inventor： Aniruddha Palsule ,  Alexander R. Holzer ,  Peter Rulon Stevenson ,  Kshitij Kishen Parab ,  Jeffrey M. Sullivan

IPC: C08F2/06 ,  C09D153/00 ,  B05D3/00 ,  C09D135/02

CPC classification number: C08F2/06 ,  B05D3/007 ,  C08F2/26 ,  C08F222/14 ,  C08F297/02 ,  C09D135/02 ,  C09D153/00 ,  C09J135/02 ,  C09J153/00

Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in a solution (for example using one or more solvents). Polymerization of 1,1-disubstituted alkene compounds in a solution provides opportunities to better control the polymerization compared with bulk polymerization. The solution polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US09683147B2

公开(公告)日：2017-06-20

申请号：US15094705

申请日：2016-04-08

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Aniruddha Sudhir Palsule ,  Jeffrey M. Sullivan

IPC: C09J135/02 ,  C08K3/00 ,  C08K5/00 ,  C08F18/02 ,  C08F18/14 ,  C08F16/36

CPC classification number: C09J135/02 ,  C08F222/14 ,  C08K3/01 ,  C08K5/0008 ,  C08K5/11 ,  C08L27/06 ,  C09J4/06

Abstract: A polymerizable system includes a curable composition and one or more encapsulated initiator particles. The curable composition can include one or more 1,1-disubstituted alkene compounds and the encapsulated initiator particles can include one or more polymerization initiators encapsulated by a cured composition. The cured composition includes one or more 1,1-disubstituted alkene compounds.

公开(公告)号：US09676875B2

公开(公告)日：2017-06-13

申请号：US14966247

申请日：2015-12-11

Applicant: Sirrus, Inc.

Inventor： Aniruddha Palsule ,  Alexander R. Holzer ,  Peter Rulon Stevenson ,  Kshitij Kishen Parab ,  Jeffrey M. Sullivan

IPC: C08F2/06 ,  C08F22/10 ,  C09J135/02 ,  C09J153/00 ,  C08F222/14

CPC classification number: C08F2/06 ,  B05D3/007 ,  C08F2/26 ,  C08F222/14 ,  C08F297/02 ,  C09D135/02 ,  C09D153/00 ,  C09J135/02 ,  C09J153/00

Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in a solution (for example using one or more solvents). Polymerization of 1,1-disubstituted alkene compounds in an solution provides opportunities to better control the polymerization compared with bulk polymerization. The solution polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US09512058B2

公开(公告)日：2016-12-06

申请号：US14352356

申请日：2012-10-18

Applicant: Sirrus, Inc.

Inventor： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Larry Hines ,  Matthew M. Ellison

IPC: C07C67/03 ,  C09J133/06 ,  C07C45/75 ,  C07C49/794 ,  C07C49/798 ,  C07C49/80 ,  C07D307/46 ,  C07C69/604 ,  C07C49/796 ,  C07D333/22 ,  C08F116/36 ,  C08F128/06 ,  C09D129/12 ,  C09D141/00 ,  C07C67/30 ,  C07C69/738 ,  C07D307/54 ,  C07D333/24 ,  C08F20/28 ,  C08F20/68 ,  C08F24/00 ,  C08F28/06 ,  C08F222/14 ,  C08F222/10

CPC classification number: C08F20/28 ,  C07C45/75 ,  C07C49/794 ,  C07C49/796 ,  C07C49/798 ,  C07C49/80 ,  C07C67/03 ,  C07C67/30 ,  C07C69/604 ,  C07C69/738 ,  C07D307/46 ,  C07D307/54 ,  C07D333/22 ,  C07D333/24 ,  C08F20/14 ,  C08F20/30 ,  C08F20/38 ,  C08F20/68 ,  C08F22/20 ,  C08F24/00 ,  C08F28/06 ,  C08F116/36 ,  C08F128/06 ,  C08F222/1006 ,  C08F222/14 ,  C08K3/013 ,  C08K5/0008 ,  C08L21/00 ,  C08L33/14 ,  C08L33/16 ,  C08L35/02 ,  C09D4/00 ,  C09D129/12 ,  C09D133/14 ,  C09D133/16 ,  C09D135/02 ,  C09D141/00 ,  C09J133/06 ,  C09J133/14 ,  C09J133/16 ,  C09J135/02 ,  Y02P20/127

Abstract: The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

Abstract translation: 本发明提供多官能单体，包括但不限于多官能亚甲基丙二酸酯和亚甲基β-酮酯单体; 生产方法; 以及由其形成的组合物和产品。 本发明的多官能单体可以通过酯交换反应或通过直接合成由单官能亚甲基丙二酸酯单体或亚甲基β-酮酯单体制备。 本发明还包括由本发明的亚甲基β-酮酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和基于聚合物的产品（例如纤维，薄膜，片材 ，医用聚合物，复合聚合物和表面活性剂）。

公开(公告)号：US20150104660A1

公开(公告)日：2015-04-16

申请号：US14388582

申请日：2013-03-29

Applicant: Sirrus, inc.

Inventor： Bernard M. Malofsky ,  Adam G. Malofsky ,  Matthew M. Ellison

IPC: C09D11/02 ,  C09D11/037

CPC classification number: C09D4/00 ,  C08F222/14 ,  C08K3/04 ,  C08K3/22 ,  C08K5/23 ,  C08K5/3437 ,  C08K5/3467 ,  C08K2003/2241 ,  C09D11/02 ,  C09D11/037 ,  C09D11/101 ,  C09D11/106 ,  C09D11/107 ,  C09D11/322 ,  Y10T428/31935

Abstract: Ink and coating compositions, printing and coating processes, and printed and coated substrates utilizing a polymerizable composition comprising one or more di-activated vinyl compounds, with the proviso that said a di-activated vinyl compound is not a cyanoacrylate. Exemplary compositions include methylene malonates, methylene β-ketoesters, methylene β-diketones, dialkyl disubstituted vinyls, and dihaloalkyl disubstituted vinyls. Exemplary compositions are polymerizable at ambient temperatures.

公开(公告)号：US20150056879A1

公开(公告)日：2015-02-26

申请号：US14388601

申请日：2013-03-29

Applicant: Sirrus, Inc.

Inventor： Bernard M. Malofsky ,  Adam G. Malofsky ,  Matthew M. Ellison

IPC: C09J4/00 ,  C08K7/14 ,  C08K3/36 ,  C09J11/08 ,  C08K3/22 ,  C09J11/04 ,  C08K7/06

Abstract: A composite material comprises a reinforcing material carried in a polymer matrix material which is the polymerization product of a polymerizable composition comprising a di-activated vinyl compound, with the proviso that the di-activated vinyl compound is not a cyanoacrylate. The reinforcing materials may be a wide variety of substrates including thermally sensitive materials. Exemplary composites can be molded and cured at ambient temperatures. Also disclosed are laminate materials having layered materials adhered by curing a di-activated vinyl polymerizable composition.

Abstract translation: 复合材料包括承载在聚合物基体材料中的增强材料，其是包含二活化乙烯基化合物的可聚合组合物的聚合产物，条件是二活化乙烯基化合物不是氰基丙烯酸酯。 增强材料可以是各种各样的基材，包括热敏材料。 典型的复合材料可以在环境温度下模制和固化。 还公开了具有通过固化二活化的乙烯基聚合性组合物而附着的层状材料的层压材料。

公开(公告)号：US20220112151A1

公开(公告)日：2022-04-14

申请号：US17405561

申请日：2021-08-18

Applicant: Sirrus, Inc.

Inventor： Alexander Y. Polykarpov ,  Aniruddha Palsule ,  Anushree Deshpande

IPC: C07C69/73 ,  C07C67/31 ,  C08F122/10

Abstract: A method forming a blocked 1,1-dicarbonyl substituted comprises reacting an alkene of a 1,1-dicarbonyl substituted alkene with a blocking Michael addition donor compound such as an alcohol or thiol. The blocked 1,1-dicarbonyl substituted alkene may be polymerized by providing sufficient thermal energy whereby at least portion of the blocked alkenes revert to alkenes and may be addition polymerized or Michael added with a multifunctional Michael addition donor compound (e.g., polyol or polythiol).