公开(公告)号：US10215073B2

公开(公告)日：2019-02-26

申请号：US15574910

申请日：2016-05-18

Applicant: BASF Corporation

Inventor： Alfred Punke ,  Gerd Grubert ,  Marcus Hilgendorff ,  Torsten Neubauer ,  Matthew Caudle ,  Yuejin Li

IPC: F01N3/28 ,  B01D53/94 ,  B01J23/44 ,  B01J23/42 ,  B01J37/02 ,  B01J29/76 ,  B01J29/78 ,  B01J35/04 ,  B01J37/04 ,  B01J37/08 ,  B01J35/00 ,  F01N3/20 ,  F01N3/035 ,  F01N13/00

Abstract: The present invention relates to catalyzed soot filter comprising a porous wall flow substrate, a catalyst for selective catalytic reduction (SCR), a palladium component, and a platinum component, the wall flow substrate comprising an inlet end, an outlet end, a substrate axial length extending between the inlet end and the outlet end, and a plurality of channels defined by internal walls of the wall flow substrate, wherein the plurality of channels comprise inlet channels having an open inlet end and a closed outlet end, and outlet channels having a closed inlet end and an open outlet end, and the SCR catalyst is provided on the entire surface of the inlet channel walls and on at least a portion of the surface of the pores within the channel walls underneath the surface of the channel walls coated with the SCR catalyst.

公开(公告)号：US09687818B2

公开(公告)日：2017-06-27

申请号：US14058559

申请日：2013-10-21

Applicant: BASF Corporation

Inventor： Attilio Siani ,  Torsten W. Müller-Stach ,  Torsten Neubauer ,  Xinyi Wei

IPC: B01D53/94 ,  B01J21/00 ,  B01J21/04 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/10 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J20/00 ,  B01J23/38 ,  B01J23/48 ,  B01J37/02 ,  B01J37/04 ,  B01J37/16 ,  B01J35/00

CPC classification number: B01J23/44 ,  B01D53/94 ,  B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/104 ,  B01D2255/106 ,  B01J21/04 ,  B01J23/38 ,  B01J23/42 ,  B01J23/48 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0203 ,  B01J37/04 ,  B01J37/16

Abstract: The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.

公开(公告)号：US09358503B2

公开(公告)日：2016-06-07

申请号：US14274300

申请日：2014-05-09

Applicant: BASF Corporation

Inventor： Chung-Zong Wan ,  Xiaolai Zheng ,  Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  R. Samuel Boorse

IPC: B01D50/00 ,  B01D53/94 ,  F01N3/035 ,  F01N3/08 ,  F01N3/20 ,  F01N3/10 ,  F01N13/02

CPC classification number: B01D53/9431 ,  B01D53/58 ,  B01D53/92 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2251/2062 ,  B01D2255/102 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/206 ,  B01D2255/2063 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/50 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2258/012 ,  F01N3/02 ,  F01N3/021 ,  F01N3/035 ,  F01N3/0807 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/10 ,  F01N3/103 ,  F01N3/206 ,  F01N3/2066 ,  F01N3/2073 ,  F01N13/02 ,  F01N2510/063 ,  F01N2510/0682 ,  Y02T10/24

Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

Abstract translation: 提供了具有氨生成成分的排气流的排放处理系统，例如NOx储存还原（NSR）催化剂或稀NOx捕集器（LNT）催化剂，以及设置在产氨催化剂下游的SCR催化剂。 SCR催化剂可以是具有CHA晶体结构的分子筛，例如可与铜进行离子交换的SSZ-13或SAPO-34。 LNT可以是层状的，具有包含载体材料的底涂层涂层，至少一种贵金属和至少一种选自碱土金属元素，稀土元素及其组合的NO x吸附剂，以及顶部洗涂层 包括支撑材料，至少一种贵金属和颗粒形式的二氧化铈，所述顶部修补基面涂层基本上不含碱土金属组分。 排放物处理系统有利地用于处理来自柴油发动机和贫燃汽油发动机的废气流。

公开(公告)号：US09044734B2

公开(公告)日：2015-06-02

申请号：US13624524

申请日：2012-09-21

Applicant: BASF SE ,  BASF Corporation

Inventor： Gerd Grubert ,  Torsten Neubauer ,  Alfred Punke ,  Marcus Hilgendorff ,  Torsten Müller-Stach ,  Olga Gerlach ,  Xinyi Wei ,  Jeffrey Hoke ,  Shiang Sung ,  Stanley Roth

IPC: B01J23/63 ,  B01D53/94 ,  B01J29/04 ,  B01J37/02 ,  B01J29/70 ,  B01J35/04 ,  B01J35/02 ,  B01J37/00

CPC classification number: B01J29/04 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/9025 ,  B01D2258/012 ,  B01J23/63 ,  B01J29/7007 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0244 ,  B01J37/0246 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/48 ,  B01J2523/49 ,  B01J2523/31 ,  B01J2523/824 ,  B01J2523/828

Abstract: The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.

Abstract translation: 本发明涉及层状柴油氧化催化剂（DOC），其包括：a）载体基材; b）一种柴油氧化催化材料，其包含：b1）位于所述载体基底上的第一层，所述第一层包含浸渍在载体材料上的钯，所述载体材料包含基于载体材料总重量至少45重量％的二氧化铈 ，并且任选地包含铂; b2）位于所述第一层上的第二层，所述第二层包含钯和铂，各自浸渍在包含金属氧化物的载体材料上; 其中第一层的铂与钯的重量比低于第二层的铂与钯的重量比。

公开(公告)号：US20140248200A1

公开(公告)日：2014-09-04

申请号：US14274300

申请日：2014-05-09

Applicant: BASF Corporation

Inventor： Chung-Zong Wan ,  Xiaolai Zheng ,  Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  R. Samuel Boorse

IPC: B01D53/94

CPC classification number: B01D53/9431 ,  B01D53/58 ,  B01D53/92 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2251/2062 ,  B01D2255/102 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/206 ,  B01D2255/2063 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/50 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2258/012 ,  F01N3/02 ,  F01N3/021 ,  F01N3/035 ,  F01N3/0807 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/10 ,  F01N3/103 ,  F01N3/206 ,  F01N3/2066 ,  F01N3/2073 ,  F01N13/02 ,  F01N2510/063 ,  F01N2510/0682 ,  Y02T10/24

Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

公开(公告)号：US20140205523A1

公开(公告)日：2014-07-24

申请号：US14157865

申请日：2014-01-17

Applicant: BASF SE ,  BASF Corporation

Inventor： Mirko Arnold ,  Stefan Kotrel ,  Attilio Siani ,  Stephan Siemund ,  Thomas Schmitz ,  Burkhard Rabe ,  Gary A. Gramiccioni ,  Oliver Seel ,  Torsten Neubauer ,  Knut Wassermann

IPC: B01J23/63 ,  B01D53/94

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2258/014 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/101 ,  F01N2510/0684 ,  Y02A50/2324 ,  Y02T10/22

Abstract: Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.

Abstract translation: 提供催化剂复合材料，其催化材料有效地基本上同时氧化一氧化碳和碳氢化合物并还原氮氧化物。 催化剂复合材料在载体上具有双金属层，所述双金属层包含由包含难熔金属氧化物组分或第一氧化铈 - 氧化锆复合材料的第一载体负载的铑组分; 由包含第二氧化铈 - 氧化锆复合材料的第二载体负载的钯组分; 一种或多种促进剂，稳定剂或粘合剂; 其中所述二金属层中的所述第一和第二氧化铈 - 氧化锆复合材料的总量的量等于或大于所述难熔金属氧化物组分的量。 还提供了制备和使用它们的方法。

公开(公告)号：US20230330598A1

公开(公告)日：2023-10-19

申请号：US18028800

申请日：2021-09-29

Applicant: BASF Corporation

Inventor： Gerd Grubert ,  Alfred Punke ,  Arne Tobias Niggebaum ,  Sven Jare Lohmeier ,  Emre Emmez ,  Torsten Neubauer ,  Jeffrey B. Hoke ,  Shiang Sung

IPC: B01D53/94 ,  B01J29/67 ,  B01J29/74 ,  B01J23/34 ,  B01J35/00 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  F01N13/00

CPC classification number: B01D53/9422 ,  B01D53/9477 ,  B01D53/9418 ,  B01D53/944 ,  B01J29/67 ,  B01J29/7415 ,  B01J23/34 ,  B01J35/0006 ,  F01N3/106 ,  F01N3/2066 ,  F01N3/2803 ,  F01N3/2026 ,  F01N13/009 ,  B01D2255/50 ,  B01D2255/91 ,  B01D2258/012 ,  B01D2257/404 ,  B01D2255/1023 ,  B01D2255/1021 ,  B01D2255/2073 ,  B01D2255/2092 ,  B01D2255/9022 ,  F01N2610/1453 ,  F01N2370/04 ,  F01N2330/30

Abstract: The present invention relates a system for the treatment of an exhaust gas of a diesel combustion engine, said system comprising a specific NOx adsorber component, a diesel oxidation catalyst (DOC) component, a selective catalytic reduction (SCR) component, a gas heating component, and a reductant injector, wherein in said system, the specific NOx adsorber component is arranged upstream of the gas heating component, the reductant injector is arranged up-stream of the SCR component, the gas heating component is arranged upstream of the reductant injector, the DOC component is arranged upstream of the reductant injector, and the DOC component and the gas heating component are directly consecutive components. Further, the present invention relates a process for preparing such a system and use thereof.

公开(公告)号：US20200032686A1

公开(公告)日：2020-01-30

申请号：US16591822

申请日：2019-10-03

Applicant: BASF CORPORATION

Inventor： Shiang Sung ,  Torsten Neubauer ,  Pushkaraj Patwardhan

IPC: F01N3/035 ,  F01N3/08 ,  F01N3/20 ,  F01N3/28 ,  F01N3/022 ,  F01N3/10 ,  B01D53/94 ,  B01D46/00 ,  B01D46/24 ,  B01J35/04 ,  B01J23/58 ,  B01J29/78 ,  B01J29/76 ,  B01J21/04 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08

Abstract: The disclosure provides a monolithic wall-flow filter catalytic article including a substrate having an aspect ratio of from about 1 to about 20, and having a functional coating composition disposed on the substrate, the functional coating composition including a first sorbent composition, an oxidation catalyst composition, and optionally, a second sorbent composition. The monolithic wall-flow filter catalytic article may be in a close-coupled position close to the engine. The disclosure further provides an integrated exhaust gas treatment system including the monolithic wall-flow filter catalytic article and may additionally include a flow-through monolith catalytic article. The flow-through monolith catalytic article includes a substrate having a selective catalytic reduction (SCR) coating composition disposed thereon. The integrated exhaust gas treatment system simplifies the traditional four-article system into a two-article Catalyzed Soot Filter (CSF) plus Selective Catalytic Reduction (SCR) CSF+SCR arrangement.

公开(公告)号：US09321009B2

公开(公告)日：2016-04-26

申请号：US14046216

申请日：2013-10-04

Applicant: BASF Corporation

Inventor： Chung-Zong Wan ,  Xiaolai Zheng ,  Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  R. Samuel Boorse

IPC: B01D50/00 ,  B01D47/00 ,  B01D53/94 ,  F01N3/035 ,  F01N3/08 ,  F01N3/20 ,  F01N3/10 ,  F01N13/02

CPC classification number: B01D53/9431 ,  B01D53/58 ,  B01D53/92 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2251/2062 ,  B01D2255/102 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/206 ,  B01D2255/2063 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/50 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2258/012 ,  F01N3/02 ,  F01N3/021 ,  F01N3/035 ,  F01N3/0807 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/10 ,  F01N3/103 ,  F01N3/206 ,  F01N3/2066 ,  F01N3/2073 ,  F01N13/02 ,  F01N2510/063 ,  F01N2510/0682 ,  Y02T10/24

Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

公开(公告)号：US09266092B2

公开(公告)日：2016-02-23

申请号：US14157865

申请日：2014-01-17

Applicant: BASF Corporation ,  BASF SE

Inventor： Mirko Arnold ,  Stefan Kotrel ,  Attilio Siani ,  Stephan Siemund ,  Thomas Schmitz ,  Burkhard Rabe ,  Gary A Gramiccioni ,  Oliver Seel ,  Torsten Neubauer ,  Knut Wassermann

IPC: B01D50/00 ,  B01D53/34 ,  F01N3/00 ,  F23J11/00 ,  B01D53/56 ,  B01D53/94 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J21/04 ,  B01J23/63 ,  B01J37/02 ,  F01N3/10 ,  B01J35/00 ,  B01J35/10

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2258/014 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/101 ,  F01N2510/0684 ,  Y02A50/2324 ,  Y02T10/22

Abstract: Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.

Abstract translation: 提供催化剂复合材料，其催化材料有效地基本上同时氧化一氧化碳和碳氢化合物并还原氮氧化物。 催化剂复合材料在载体上具有双金属层，所述双金属层包含由包含难熔金属氧化物组分或第一氧化铈 - 氧化锆复合材料的第一载体负载的铑组分; 由包含第二氧化铈 - 氧化锆复合材料的第二载体负载的钯组分; 一种或多种促进剂，稳定剂或粘合剂; 其中所述二金属层中的所述第一和第二氧化铈 - 氧化锆复合材料的总量的量等于或大于所述难熔金属氧化物组分的量。 还提供了制备和使用它们的方法。