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公开(公告)号：US5034563A
公开(公告)日：1991-07-23
申请号：US505392
申请日：1990-04-06
申请人： Henry Ashjian , Quang N. Le , David O. Marler , Joosup Shim , Stephen S. Wong
发明人： Henry Ashjian , Quang N. Le , David O. Marler , Joosup Shim , Stephen S. Wong
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/08 , C07C2529/70
摘要： Long chain alkyl substituted naphthalenes are produced by the alkylation of naphthalene with an olefin or other alkylating agent possessing at least 6 carbon atoms, usually 12 to 20 carbon atoms, in the presence of an alkylation catalyst comprising a zeolite which contains cations having a radius of at least 2.5 .ANG.. Cations of this size may be provided by hydrated cations such as hydrated ammonium, sodium or potassium cations or by organoammonium cations such as tetraalkylammonium cations. The zeolite is usually a large pore size ze USY. The presence of the bulky cations in the zeolite increases the selectivity of the catalyst for the production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products.
摘要翻译： 长链烷基取代的萘是通过在含有至少6个碳原子，通常12至20个碳原子的烯烃或其它烷基化剂的烷基化催化剂的存在下，在包含含有阳离子的沸石的烷基化催化剂的存在下， 至少2.5 ANGSTROM。 这种大小的阳离子可由水合阳离子如水合铵，钠或钾阳离子或有机铵阳离子如四烷基铵阳离子提供。 沸石通常是大孔尺寸的USY。 沸石中大体积阳离子的存在增加了催化剂对于生产长链单烷基取代的萘的选择性，优于更高取代的产物。
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公开(公告)号：US4885426A
公开(公告)日：1989-12-05
申请号：US327378
申请日：1989-03-23
申请人： Yung F. Chu , David O. Marler , John P. McWilliams
发明人： Yung F. Chu , David O. Marler , John P. McWilliams
IPC分类号： C07C6/12
CPC分类号： C07C6/126 , C07C2529/40
摘要： A process is provided for transalkylation of polyalkylaromatics over a catalyst comprising a molecular sieve having a high lattice aluminum content whereby its silica/alumina mole ratio is less than 40 and an alpha value of at least about 140.
摘要翻译： 提供了一种方法，用于在包含具有高格子铝含量的分子筛的催化剂上进行多烷基芳族化合物的烷基转移，由此其二氧化硅/氧化铝摩尔比小于40，α值至少为约140。
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公开(公告)号：US4851604A
公开(公告)日：1989-07-25
申请号：US92842
申请日：1987-09-02
CPC分类号： C07C6/123 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52
摘要： An improved process is provided for vapor-phase disproportionation of toluene over catalyst comprising a molecular sieve having a high lattice aluminum content whereby its silica/alumina mole ratio is less than 55 and a diffusion rate constant of less than about 150 sec.sup.-1.
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14.发明申请DRYING DEVICE FOR PRODUCING SMALL QUANTITIES OF CONTROLLED PARTICLE SIZE CATALYSTS WHICH ARE APPROPRIATE FOR USE IN FLUIDIZED BED OPERATIONS SUCH AS FLUID CATALYTIC CRACKING 审中-公开用于生产适用于流化床操作的受控粒度催化剂的小量数量的干燥装置，如流体催化裂化公开(公告)号：US20110152062A1
公开(公告)日：2011-06-23
申请号：US12957817
申请日：2010-12-01
申请人： William A. Wachter , Brenda A. Raich , Theodore E. Datz , David O. Marler , Nicholas Rollman , Jeffrey T. Elks , Gordon F. Stuntz
发明人： William A. Wachter , Brenda A. Raich , Theodore E. Datz , David O. Marler , Nicholas Rollman , Jeffrey T. Elks , Gordon F. Stuntz
CPC分类号： B01J29/06 , B01J29/70 , B01J37/0018 , B01J37/0072 , B01J37/0236 , B01J37/08 , B01J2229/36 , B01J2229/42 , C10G11/05
摘要： Catalysts for experimentation are produced having a controlled matrix pore structure. The manufacturing process utilizes tape casting in the drying procedure in which a catalyst slurry is cast on a substrate and dried at a temperature of between about 50° C. to 200° C. for a period of time of about 0.1 to 1.0 hour. The dried catalyst particles can be removed from the substrate by several techniques, including scraping, burning, and deforming the substrate material, The resulting catalytic particles can be produced in an amount of about ca. 3 g to 300 g from slurries with volumes between 5 cc to 500 cc, which are suitable for small scale FCC reactors and for high throughput experimentation.
摘要翻译： 生产具有受控矩阵孔结构的用于实验的催化剂。 制造方法在干燥过程中使用带铸造，其中将催化剂浆料浇铸在基材上并在约50℃至200℃的温度下干燥约0.1至1.0小时的时间。 干燥的催化剂颗粒可以通过几种技术从基材中除去，包括刮擦，燃烧和使基材变形。所得到的催化剂颗粒可以以约约 3克至300克，体积在5毫升至500毫升之间的浆料，适用于小规模的FCC反应器和高通量实验。
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公开(公告)号：US07816573B2
公开(公告)日：2010-10-19
申请号：US11698533
申请日：2007-01-26
CPC分类号： B01J29/7038 , B01J29/04 , B01J29/06 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/002 , B01J37/0009 , B01J37/06 , B01J2229/12 , B01J2229/18 , B01J2229/42 , B01J2229/64 , C01B39/04 , C01B39/48 , C07C2/66 , C07C15/085 , C07C2529/08 , C07C2529/18 , C07C2529/40 , Y02P20/52
摘要： The invention relates to a process for converting hydrocarbons with a catalyst comprising a crystalline molecular sieve composition which is obtainable by crystallizing a pre-formed extrudate mixture in a reactor and, during crystallization, removing excess alkali metal hydroxide from the pre-formed extrudate. The pre-formed extrudate mixture comprises at least one source of ions of tetravalent element Y, at least one source of alkali metal hydroxide, water, optionally at least one seed crystal, and optionally at least one source of ions of trivalent element X. The reaction mixture has the following mole composition: Y:X2=10 to infinity; OH−:Y=0.001 to 2; and M+:Y=0.001 to 2; wherein M is an alkali metal. The amount of water in the mixture is at least sufficient to permit extrusion of said reaction mixture.
摘要翻译： 本发明涉及一种用催化剂转化烃的方法，该催化剂包括结晶分子筛组合物，其可通过在反应器中结晶预形成的挤出物混合物并在结晶过程中从预形成的挤出物中除去过量的碱金属氢氧化物而获得。 预形成的挤出物混合物包含至少一种四价元素Y的离子源，至少一种碱金属氢氧化物源，水，任选的至少一种晶种和任选的至少一种三价元素X的离子源。 反应混合物具有以下摩尔组成：Y：X2 = 10至无穷大; OH-：Y = 0.001〜2; 和M +：Y = 0.001〜2; 其中M是碱金属。 混合物中的水的量至少足以允许挤出所述反应混合物。
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公开(公告)号：US07361619B2
公开(公告)日：2008-04-22
申请号：US10819379
申请日：2004-04-06
CPC分类号： C10G2/33 , B01J23/75 , B01J23/8896 , B01J37/12 , B01J37/18
摘要： Dispersed Active Metal catalyst for hydrogenation reactions is produced by treating a substantially catalytically inactive metal particulate with a solution capable of oxidizing the metal particulate and comprising of at least one compound of a hydrogenation catalyst metal thereby forming a layer of at least one of hydroxides and oxides thereon. The metal particulate is activated by treatment with a hydrogen-containing gas at elevated temperatures to form a porous layer of Dispersed Active Metal catalyst. Preferably, the treated metal particulate is dried prior to activation, and also preferably calcined in an oxidant-containing atmosphere prior to activation. The treatment solution may advantageously contain a compound of at least one promoter metal for the added catalyst metal. The porosity of the layer provides enhanced catalyst activity as well as improved methane selectivity in the Fischer-Tropsch process.
摘要翻译： 用于氢化反应的分散活性金属催化剂通过用能够氧化金属颗粒并且包含至少一种氢化催化剂金属的化合物的溶液处理基本上催化惰性的金属颗粒而产生，从而形成氢氧化物和氧化物中的至少一种的层 上。 通过在高温下用含氢气体处理来活化金属颗粒以形成分散活性金属催化剂的多孔层。 优选地，处理的金属颗粒在活化之前被干燥，并且还优选在活化之前在含氧化剂的气氛中煅烧。 处理溶液可以有利地含有用于加入的催化剂金属的至少一种助催化剂金属的化合物。 该层的孔隙率提高了催化剂活性以及在费 - 托工艺中提高的甲烷选择性。
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公开(公告)号：US5705724A
公开(公告)日：1998-01-06
申请号：US548850
申请日：1995-10-26
CPC分类号： C10G29/205 , C07C2/66 , C07C2/68 , C07C2/70 , C10G1/002 , C10G1/10 , C10G50/00 , C07C2521/12 , C07C2527/054 , C07C2527/1206 , C07C2527/1213 , C07C2527/126 , C07C2527/128 , C07C2527/135 , C07C2527/138 , C07C2527/16 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： A process is disclosed for the production of alkylaromatic compounds employing olefinic liquid from thermally or catalytically cracked plastics as alkylating agent. The process comprises contacting a feedstream comprising alkylatable aromatics and the olefinic liquid with acidic alkylation catalyst under alkylation conditions in an alkylation zone; and recovering an effluent stream comprising alkylaromatic compounds. The alkylation can be performed with the product of plastics pyrolysis or with non-degraded plastic feedstock in-situ with thermal/catalytic degradation of the plastic.
摘要翻译： 公开了用于使用来自热或催化裂化塑料的烯烃液体作为烷基化剂生产烷基芳族化合物的方法。 该方法包括在烷基化区域的烷基化条件下将包含可烷基化芳族化合物和烯烃液体的进料流与酸性烷基化催化剂接触; 并回收包含烷基芳族化合物的流出物流。 烷基化可以用塑料热分解产物或非降解塑料原料进行原位与塑料的热/催化降解进行。
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18.发明授权
公开(公告)号：US5583276A
公开(公告)日：1996-12-10
申请号：US442549
申请日：1995-05-16
CPC分类号： C01B39/12 , B01J29/04 , C01B39/48 , C07C2/58 , C07C2529/70
摘要： A process for converting at least one olefin and at least one isoparaffin to a diesel fuel blending component comprising the steps of contacting the olefin and the isoparaffin with a catalyst comprising MCM-58 to provide a diesel fuel. Process conditions can be varied to favor the formation of gasoline, distillate, lube range products or mixtures thereof.
摘要翻译： 一种将至少一种烯烃和至少一种异链烷烃转化为柴油燃料共混组分的方法，包括使烯烃和异链烷烃与包含MCM-58的催化剂接触以提供柴油燃料的步骤。 工艺条件可以变化以有利于形成汽油，馏出物，润滑剂产品或其混合物。
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公开(公告)号：US5552357A
公开(公告)日：1996-09-03
申请号：US294801
申请日：1994-08-25
IPC分类号： B01J29/40 , B01J31/02 , B01J31/12 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/27 , C07C5/41 , C07C6/12 , C10G45/64 , B01J29/06
CPC分类号： C10G45/64 , B01J29/40 , B01J31/123 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/2708 , C07C5/41 , C07C6/123 , C07C6/126 , B01J2229/12 , B01J2229/26 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2529/06 , C07C2529/064 , Y02P20/52
摘要： A process for shape selective hydrocarbon conversion involves contacting a hydrocarbon feedstream under conversion conditions with a catalytic molecular sieve which has been modified by treatment with an amino silane polymer while molecular sieve acid sites are protected. When the process is toluene disproportionation, a toluene feedstream may also contain a second silicon source which is a high p-xylene selectivating agent. The invention also includes the modification method and the shape selective catalyst which results from the modification.
摘要翻译： 用于形状选择性烃转化的方法包括在转化条件下使烃进料流与催化分子筛接触，催化分子筛在分子筛酸性位点受到保护时已用氨基硅烷聚合物进行改性。 当该方法是甲苯歧化反应时，甲苯进料流还可含有作为高对二甲苯选择性试剂的第二硅源。 本发明还包括由改性产生的改性方法和形状选择性催化剂。
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公开(公告)号：US5349114A
公开(公告)日：1994-09-20
申请号：US42431
申请日：1993-04-05
CPC分类号： C07C6/123 , B01J29/40 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/2708 , B01J2229/12 , B01J2229/26 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2529/42
摘要： A process for shape selective hydrocarbon conversion involves contacting a hydrocarbon feedsteam under conversion conditions with a modified catalytic molecular sieve which has been modified by being pre-selectivated with a first silicon source, then steamed. The feedstream may also contain a second silicon source which is a high efficiency para-xylene selectivating agent. The method for modifying the molecular sieve is also described.
摘要翻译： 形状选择性烃转化的方法包括使转化条件下的烃进料流与改性的催化分子筛接触，所述催化分子筛已经通过用第一硅源预先选择然后被蒸煮而被修饰。 进料流还可以含有作为高效对二甲苯选择剂的第二硅源。 还描述了改性分子筛的方法。
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