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11.发明申请Multi-metal reduction catalysts and methods of producing reduction catalysts 审中-公开多金属还原催化剂和还原催化剂的制备方法公开(公告)号：US20090088317A1
公开(公告)日：2009-04-02
申请号：US11904794
申请日：2007-09-28
申请人： John G. Frye, JR. , Johnathan E. Holladay , Danielle S. Muzatko , James F. White , Alan H. Zacher
发明人： John G. Frye, JR. , Johnathan E. Holladay , Danielle S. Muzatko , James F. White , Alan H. Zacher
IPC分类号： B01J27/224 , B01J23/10 , B01J23/06 , B01J23/20 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/36 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/50 , B01J23/52 , B01J23/56 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J21/08 , B01J27/22
CPC分类号： B01J23/626 , B01J23/462 , B01J23/464 , B01J23/466 , B01J23/48 , B01J23/60 , B01J23/62 , B01J23/628 , B01J23/6447 , B01J23/656 , B01J23/80 , B01J23/85 , B01J23/889 , B01J23/89 , B01J23/8906 , B01J23/8926 , B01J23/8986 , B01J27/045 , B01J27/0576 , B01J37/18 , C07C29/60 , C07C31/205
摘要： A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.
摘要翻译： 一种具有包含Co，Os，Fe，Re，Rh和Ru中的一种的第一金属组分的还原催化剂。 催化剂中第一种金属组分以重量百分比为0.5％至20％存在。 不同于催化剂中存在的第一金属组分的第二金属组分，其中第二金属组分选自Fe，Mn，Ru，Os，Rh，Ir，Ni，Pd，Pt，Ag，Au，Zn， Co，Re，Cu，Pb，Cr，W，Mo，Sn，Nb，Cd，Te，V，Bi，Ga和Na。 包含Ni和Co中的一种或两种以及选自Mn，Fe，Ag，Au，Mo和Rh中的一种或多种元素的氢化催化剂。
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12.发明申请公开(公告)号：US20090264686A1
公开(公告)日：2009-10-22
申请号：US12082997
申请日：2008-04-16
申请人： Johnathan E. Holladay , James F. White , Thomas H. Peterson , John G. Frye, JR. , Danielle S. Muzatko , Simon R. Bare , James G. Vassilakis , Richard R. Rosin
发明人： Johnathan E. Holladay , James F. White , Thomas H. Peterson , John G. Frye, JR. , Danielle S. Muzatko , Simon R. Bare , James G. Vassilakis , Richard R. Rosin
IPC分类号： B01J23/44 , C07C29/60 , B01J23/755 , B01J23/75
CPC分类号： B01J21/18 , B01J23/8896 , B01J23/8986 , B01J37/18
摘要： Hydrogenolysis processes are provided that can include providing a hydrogenolysis reactor having a catalyst therein. The catalyst can be exposed to a reducing agent in the absence of polyhydric alcohol compound while maintaining a temperature of the catalyst above 290° C. Hydrogenolysis processes can also include providing a passivated catalyst to within a reactor and exposing the catalyst to a reducing atmosphere while maintaining the catalyst at a temperature less than 210° C.Hydrogenolysis catalyst preparation methods are provided that can include exposing the catalyst to a first reducing atmosphere while maintaining the catalyst at a first temperature to reduce at least a portion of the catalyst. The method can also include passivating at least the portion of the catalyst and depassivating the portion of the catalyst in the presence of a second reducing atmosphere while maintaining the portion of the catalyst at a second temperature less than the first temperature.
摘要翻译： 提供氢解方法，其可以包括提供其中具有催化剂的氢解反应器。 催化剂可以在不存在多元醇化合物的情况下暴露于还原剂，同时保持催化剂的温度高于290℃。氢解方法还可以包括在反应器内提供钝化的催化剂并将催化剂暴露于还原气氛，同时 将催化剂保持在低于210℃的温度。提供氢解催化剂制备方法，其可以包括将催化剂暴露于第一还原气氛，同时将催化剂保持在第一温度以减少至少一部分催化剂。 该方法还可以包括钝化至少一部分催化剂，并且在第二还原气氛存在的情况下使催化剂的一部分钝化，同时保持催化剂的部分在低于第一温度的第二温度。
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公开(公告)号：US07687661B2
公开(公告)日：2010-03-30
申请号：US11377096
申请日：2006-03-15
申请人： Michael A. Lilga , James F. White , Johnathan E. Holladay , Alan H. Zacher , Danielle S. Muzatko , Rick J. Orth
发明人： Michael A. Lilga , James F. White , Johnathan E. Holladay , Alan H. Zacher , Danielle S. Muzatko , Rick J. Orth
IPC分类号： C07C67/30
CPC分类号： C07C51/377 , C07C51/41 , C07C57/04
摘要： A process is disclosed for conversion of salts of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., α,β-unsaturated carbonyl compounds and/or salts of α,β-unsaturated carbonyl compounds. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译： 公开了用于转化形成有用的转化产物（例如α，b' - 不饱和羰基化合物和/或α，β-不饱和羰基化合物的盐的α-羟基羰基化合物的盐的方法。 转化产物可用作例如原料和/或最终用途的化学品。
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公开(公告)号：US20090264687A1
公开(公告)日：2009-10-22
申请号：US12104394
申请日：2008-04-16
CPC分类号： C07C29/132 , C07C29/60 , C07C31/205
摘要： Hydrogenolysis systems are provided that can include a reactor housing an Ru-comprising hydrogenolysis catalyst and wherein the contents of the reactor is maintained at a neutral or acidic pH. Reactant reservoirs within the system can include a polyhydric alcohol compound and a base, wherein a weight ratio of the base to the compound is less than 0.05. Systems also include the product reservoir comprising a hydrogenolyzed polyhydric alcohol compound and salts of organic acids, and wherein the moles of base are substantially equivalent to the moles of salts or organic acids. Processes are provided that can include an Ru-comprising catalyst within a mixture having a neutral or acidic pH. A weight ratio of the base to the compound can be between 0.01 and 0.05 during exposing.
摘要翻译： 提供了氢解系统，其可以包括容纳含Ru的氢解催化剂的反应器，并且其中反应器的内容物保持在中性或酸性pH。 系统内的反应物储存器可以包括多元醇化合物和碱，其中碱与化合物的重量比小于0.05。 系统还包括包含氢解的多元醇化合物和有机酸的盐的产物储存器，其中碱的摩尔数基本上等于盐或有机酸的摩尔数。 提供了可以在具有中性或酸性pH的混合物中包含含Ru的催化剂的方法。 在曝光期间，碱与化合物的重量比可以在0.01和0.05之间。
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公开(公告)号：US07872158B2
公开(公告)日：2011-01-18
申请号：US11895414
申请日：2007-08-24
CPC分类号： B01J27/186 , B01J8/025 , B01J23/96 , B01J27/1856 , B01J27/285 , B01J37/03 , B01J38/12 , B01J2208/00212 , B01J2208/00256 , B01J2219/00247 , C07C45/52 , Y02P20/584 , C07C47/22 , C07C49/17
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. The reactant composition can include a multihydric alcohol compound and the product composition can include a carbonyl compound. The catalyst composition can include a metal effective to facilitate catalyst activation. Processes disclosed also include supplementing a dehydration catalyst with a promoter, and activating the supplemented catalyst in the presence of oxygen. Processes also include providing a supplemented dehydration catalyst to within a reactor, and exposing a multihydric alcohol compound to the dehydration catalyst, with the exposing forming coke within the reactor. Oxygen can be provided to the reactor to remove at least a portion of the coke.
摘要翻译： 提供化学生产方法，其可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物。 反应物组合物可以包括多元醇化合物，并且产物组合物可以包括羰基化合物。 催化剂组合物可以包括有效促进催化剂活化的金属。 所公开的方法还包括用助催化剂补充脱水催化剂，并在氧的存在下活化补充的催化剂。 方法还包括向反应器内部提供补充的脱水催化剂，并将多元醇化合物暴露于脱水催化剂中，同时在反应器内形成曝光的焦炭。 可以将氧气提供给反应器以除去至少一部分焦炭。
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公开(公告)号：US20090054693A1
公开(公告)日：2009-02-26
申请号：US11895362
申请日：2007-08-24
CPC分类号： C07C45/52 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/12 , B01J27/125 , B01J27/16 , B01J27/185 , B01J27/186 , C07C49/17 , C07C47/22
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. Catalyst compositions are also provided that can include metal phosphate compositions, metal phosphorous compositions, and/or solid support compositions with the solid support compositions including one or more of F—Al2O3, ZrO2—CO2, SiO2—Al2O3—CO2, SiO2 Al2O3, Alundum, and Silica such as Ludox AS-30
摘要翻译： 提供化学生产方法，其可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物。 还提供催化剂组合物，其可以包括金属磷酸盐组合物，金属磷组合物和/或固体支持组合物，其中固体支持组合物包括F-Al 2 O 3，ZrO 2 -CO 2，SiO 2 -Al 2 O 3 -CO 2，SiO 2 Al 2 O 3，Alundum中的一种或多种 ，和二氧化硅如Ludox AS-30
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公开(公告)号：US07872159B2
公开(公告)日：2011-01-18
申请号：US11895362
申请日：2007-08-24
CPC分类号： C07C45/52 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/12 , B01J27/125 , B01J27/16 , B01J27/185 , B01J27/186 , C07C49/17 , C07C47/22
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. Catalyst compositions are also provided that can include metal phosphate compositions, metal phosphorous compositions, and/or solid support compositions with the solid support compositions including one or more of F—Al2O3, ZrO2—CO2, SiO2—Al2O3—CO2, SiO2 Al2O3, Alundum, and Silica such as Ludox AS-30.
摘要翻译： 提供化学生产方法，其可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物。 还提供催化剂组合物，其可以包括金属磷酸盐组合物，金属磷组合物和/或固体支持组合物，其中固体支持组合物包括F-Al 2 O 3，ZrO 2 -CO 2，SiO 2 -Al 2 O 3 -CO 2，SiO 2 Al 2 O 3，Alundum中的一种或多种 ，和二氧化硅如Ludox AS-30。
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公开(公告)号：US20090054695A1
公开(公告)日：2009-02-26
申请号：US11895414
申请日：2007-08-24
IPC分类号： C07C45/29 , B01J21/00 , B01J27/053 , B01J8/00
CPC分类号： B01J27/186 , B01J8/025 , B01J23/96 , B01J27/1856 , B01J27/285 , B01J37/03 , B01J38/12 , B01J2208/00212 , B01J2208/00256 , B01J2219/00247 , C07C45/52 , Y02P20/584 , C07C47/22 , C07C49/17
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. The reactant composition can include a multihydric alcohol compound and the product composition can include a carbonyl compound. The catalyst composition can include a metal effective to facilitate catalyst activation. Processes disclosed also include supplementing a dehydration catalyst with a promoter, and activating the supplemented catalyst in the presence of oxygen. Processes also include providing a supplemented dehydration catalyst to within a reactor, and exposing a multihydric alcohol compound to the dehydration catalyst, with the exposing forming coke within the reactor. Oxygen can be provided to the reactor to remove at least a portion of the coke.
摘要翻译： 提供化学生产方法，其可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物。 反应物组合物可以包括多元醇化合物，并且产物组合物可以包括羰基化合物。 催化剂组合物可以包括有效促进催化剂活化的金属。 所公开的方法还包括用助催化剂补充脱水催化剂，并在氧的存在下活化补充的催化剂。 方法还包括在反应器内提供补充的脱水催化剂，并将多元醇化合物暴露于脱水催化剂中，同时在反应器内形成曝光的焦炭。 可以将氧气提供给反应器以除去至少一部分焦炭。
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公开(公告)号：US20090054538A1
公开(公告)日：2009-02-26
申请号：US11895592
申请日：2007-08-24
申请人： Thomas H. Peterson , Alan H. Zacher , Michel J. Gray , James F. White , Johnathon E. Holladay , Todd A. Werpy
发明人： Thomas H. Peterson , Alan H. Zacher , Michel J. Gray , James F. White , Johnathon E. Holladay , Todd A. Werpy
IPC分类号： C07C27/22
CPC分类号： B01J27/188 , B01J8/025 , B01J23/20 , B01J23/24 , B01J23/34 , B01J23/8474 , B01J27/195 , B01J37/0236 , B01J2208/00212 , B01J2208/00256 , C07C45/52 , C07C47/22
摘要： Chemical production processes are provided than can include exposing a reactant composition to a catalyst composition to form a product composition, with the reactant composition including a multihydric alcohol compound and product composition including a carbonyl compound. The catalyst composition can include one or more elements of groups 5 and 6 of the periodic table of elements. Catalyst compositions are provided that can include one or more of niobia, hydrated niobia, tungstic acid, phosphotungstic acid, and phosphomolybdic acid.
摘要翻译： 提供化学生产方法可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物，反应物组合物包含多元醇化合物和包含羰基化合物的产物组合物。 催化剂组合物可以包括元素周期表第5和6族的一个或多个元素。 提供的催化剂组合物可以包括铌，氧化铌，钨酸，磷钨酸和磷钼酸中的一种或多种。
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20.发明授权Multihydric compound dehydration systems, catalyst compositions, and methods 失效多羟基化合物脱水体系，催化剂组合物和方法公开(公告)号：US08530703B2
公开(公告)日：2013-09-10
申请号：US12973518
申请日：2010-12-20
CPC分类号： C07C45/00 , B01J8/001 , B01J21/08 , B01J27/18 , B01J27/1806 , B01J27/1853 , B01J27/285 , B01J38/02 , B01J38/04 , B01J38/06 , B01J38/12 , C07C45/52 , Y02P20/584 , C07C47/22
摘要： The present disclosure relates to facilities, systems, methods and/or catalysts for use in chemical production. In particular, the disclosure provides innovations relating to dehydration of multihydric compounds such as glycerol to form acrolein. Some of these innovations include continuous reaction systems as well as system parameters that allow for long term production.
摘要翻译： 本公开涉及用于化学生产的设备，系统，方法和/或催化剂。 特别地，本公开提供了与多羟基化合物如甘油的脱水相关的创新以形成丙烯醛。 其中一些创新包括连续反应系统以及允许长期生产的系统参数。
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