公开(公告)号：US10046974B2

公开(公告)日：2018-08-14

申请号：US14765471

申请日：2014-02-05

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Robert Bayer ,  Regina Vogelsang ,  Robert Schlosser ,  Franky Ruslim ,  Pawel Czajka

IPC分类号： C01B39/12 ,  B01J29/86 ,  C01B39/48 ,  C01B37/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  C01B39/46

摘要： A process for preparing an aluminum-free boron containing zeolitic material comprising the framework structure MWW (BMWW), comprising (a) hydrothermally synthesizing the BMWW from a synthesis mixture containing water, a silicon source, a boron source, and an MWW template compound obtaining the BMWW in its mother liquor, the mother liquor having a pH above 9; (b) adjusting the pH of the mother liquor, obtained in (a) and containing the BMWW, to a value in the range of from 6 to 9; (c) separating the BMWW from the pH-adjusted mother liquor obtained in (b) by filtration in a filtration device.

公开(公告)号：US10005074B2

公开(公告)日：2018-06-26

申请号：US15465716

申请日：2017-03-22

申请人： ExxonMobil Research and Engineering Company

发明人： Allen Wayne Burton ,  Karl G. Strohmaier ,  Hilda B. Vroman ,  Yifeng Yun ,  Xiaodong Zou ,  Wei Wan ,  Tom J. Willhammar

IPC分类号： C01B39/48 ,  B01J29/70 ,  C01B37/00 ,  C07C7/13 ,  C01B39/12

CPC分类号： B01J29/70 ,  C01B37/007 ,  C01B39/12 ,  C01B39/48 ,  C07C7/13 ,  C07C2531/02 ,  C07C2601/16

摘要： A molecular sieve material, EMM-25, having in its calcined form an X-ray diffraction pattern including the following peaks: d-spacing (Å)Relative Intensity [100 × I/I(o)]% 11.74-11.34 60-100 9.50-9.1030-80 8.68-8.2810-40 5.64-5.4420-60 4.52-4.4210-50 4.28-4.1810-40 3.96-3.8640-80 3.69-3.5930-70

公开(公告)号：US09987624B2

公开(公告)日：2018-06-05

申请号：US15033402

申请日：2014-11-05

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Georg Uhl ,  Joaquim H. Teles ,  Nicolas Vautravers ,  Dominic Riedel

IPC分类号： C01B39/06 ,  C01B39/48 ,  B01J29/70 ,  C01B39/12 ,  C07C45/58 ,  B01J35/00 ,  B01J35/10 ,  B01J37/08 ,  B01J37/30 ,  C01B39/02 ,  C01B39/46

CPC分类号： B01J29/7088 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/026 ,  C01B39/06 ,  C01B39/12 ,  C01B39/46 ,  C01B39/48 ,  C07C45/58 ,  C07C2601/10 ,  C07C47/225

摘要： A process for preparing a tin-containing zeolitic material having an MWW-type framework structure comprising providing a zeolitic material having an MWW-type framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, and incorporating tin into the zeolitic material via solid-state ion exchange.

公开(公告)号：US09957166B2

公开(公告)日：2018-05-01

申请号：US15044041

申请日：2016-02-15

申请人： CALIFORNIA INSTITUTE OF TECHNOLOGY

发明人： Raymond Archer ,  Mark E. Davis

IPC分类号： C01B39/04 ,  B01J29/70 ,  C01B39/48 ,  B01J29/87 ,  B01J29/86 ,  B01J29/04 ,  B01J29/89 ,  B01J29/88 ,  C01B37/00 ,  C01B37/02 ,  C01B39/08 ,  C01B39/12 ,  B01J20/18 ,  B01J20/30 ,  B01J37/00

CPC分类号： C01B39/48 ,  B01J20/18 ,  B01J20/3057 ,  B01J29/047 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J37/0018 ,  C01B37/005 ,  C01B37/007 ,  C01B37/02 ,  C01B39/04 ,  C01B39/08 ,  C01B39/12

摘要： Method for preparing molecular sieves and molecular sieves obtained thereby are described. The method includes preparing a reaction mixture, comprising a structure directing agent, at least one source of at least one oxide of a tetravalent element, optionally, one or more sources of one or more oxides selected from the group consisting of oxides of trivalent elements, pentavalent elements, and mixtures thereof, optionally, at least one source of an element selected from Groups 1 and 2 of the Periodic Table; and optionally, hydroxide ions or fluoride ions, and maintaining the reaction mixture under conditions sufficient to form crystals of the molecular sieve. In the method, various imidazolium cations are used as the structure directing element.

公开(公告)号：US09878311B2

公开(公告)日：2018-01-30

申请号：US14862893

申请日：2015-09-23

申请人： BASF SE

发明人： Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Jeff Yang ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Stefan Dumser

IPC分类号： B01J29/04 ,  C01B39/12 ,  B01J29/89 ,  B01J29/70 ,  B01J29/86 ,  B01J35/00 ,  C01B39/02 ,  B01J35/02 ,  B01J37/00 ,  B01J37/06 ,  B01J37/10 ,  C01B39/48

CPC分类号： B01J29/04 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  B01J35/026 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/06 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/30 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/12 ,  C01B39/48

摘要： The present invention relates to a process for process for the preparation of a zeolitic material which process comprises (i) providing a boron-containing zeolitic material and (ii) deboronating the boron-containing zeolitic material by treating the boron-containing zeolitic material with a liquid solvent system thereby obtaining a deboronated zeolitic material, which liquid solvent system does not contain an inorganic or organic acid, or a salt thereof.

公开(公告)号：US09296715B2

公开(公告)日：2016-03-29

申请号：US14143838

申请日：2013-12-30

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Joaquim Henrique Teles ,  Bianca Seelig ,  Philip Kampe ,  Markus Weber ,  Robert Bayer ,  Karsten Seidel ,  Peter Resch

IPC分类号： C07D301/12 ,  C01B39/12 ,  B01J29/70 ,  B01J29/04 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  C01B37/00 ,  C01B39/02 ,  C01B39/06 ,  B01J29/89

CPC分类号： C07D301/12 ,  B01J29/041 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/18 ,  B01J2229/37 ,  B01J2229/42 ,  C01B37/005 ,  C01B39/026 ,  C01B39/065 ,  C01B39/12

摘要： The present invention relates to a micropowder, wherein the particles of the micropowder have a Dv10 value of at least 2 micrometer and the micropowder comprises mesopores which have an average pore diameter in the range of from 2 to 50 nm and comprise, based on the weight of the micropowder, at least 95 weight-% of a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc.

公开(公告)号：US09206052B2

公开(公告)日：2015-12-08

申请号：US14028015

申请日：2013-09-16

申请人： Saleh Ali Elomari

发明人： Saleh Ali Elomari

IPC分类号： C01B39/48 ,  C01B39/12 ,  B01J29/86 ,  B01J29/70

CPC分类号： C01B39/48 ,  B01J29/70 ,  B01J29/86 ,  C01B39/12

摘要： A method for making zeolite SSZ-35 having the framework structure STF is disclosed using a N,N-diethyl-2,3-dimethylpiperidinium cation or a N,N-dimethyl-2-isopropylpiperidinium cation as a structure directing agent.

摘要翻译： 公开了使用N，N-二乙基-2,3-二甲基哌啶阳离子或N，N-二甲基-2-异丙基哌啶鎓阳离子作为结构导向剂的制备具有骨架结构STF的沸石SSZ-35的方法。

公开(公告)号：US06916459B2

公开(公告)日：2005-07-12

申请号：US10412624

申请日：2003-04-11

申请人： Avelino Corma Canós ,  Maria Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  Maria Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

IPC分类号： B01D53/86 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J35/10 ,  C01B39/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07B61/00 ,  C07C2/66 ,  C07C45/29 ,  C07C45/33 ,  C07C45/46 ,  C10G11/02 ,  C10G11/05 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16

CPC分类号： C10G47/16 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  C01B39/023 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C45/29 ,  C07C45/294 ,  C07C45/33 ,  C07C45/46 ,  C10G11/05 ,  C10G29/205 ,  C10G45/64 ,  Y02C20/30 ,  Y02P20/52 ,  C07C15/085

摘要： This invention refers to a new zeolitic material included under the ITQ-16 denomination, to the method for obtaining them and their use as catalysts.This material, ITQ-16 zeolite, is characterized by having different ratios of the different polymorphs A, B and C described as possible intergrowths in Beta zeolite and which, therefore, show different X-ray diffraction patterns to that described for Beta zeolite, showing the X-ray diffraction pattern for ITQ-16, as it is synthesised, diffraction peaks at 2θ angles of 6.9°, 7.4°, and 9.6°, simultaneously.ITQ-16 zeolite in its calcinated form has the following empiric formula: x(M1/nXO2):tTO2:gGeO2:(1−g)SiO2 where T is one or various elements with +4 oxidation status, different of Ge and Si; X is one or various elements with +3 oxidation status and M can be H+ or one or various inorganic cations with charge +n, t is comprised between 0 and 0.1, g is comprised between 0.001 and 0.33 and x is comprised between 0 and 0.2.

摘要翻译： 本发明涉及包含在ITQ-16面额内的新型沸石材料，其获得方法及其作为催化剂的用途。 该材料，ITQ-16沸石的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长，因此与β沸石所述的X射线衍射图不同，显示出 合成了ITQ-16的X射线衍射图，同时在2θ角为6.9°，7.4°和9.6°的衍射峰。 其煅烧形式的ITQ-16沸石具有以下经验公式：<？in-line-formula description =“In-line Formulas”end =“lead”？> x（M 1 / n XO 2→2→1：gGeO 2：（1-g）SiO 2-β-in-in-line-2 公式描述=“在线公式”end =“tail”？>其中T是具有+4氧化状态，Ge和Si不同的一种或多种元素; X是具有+3氧化状态的一种或各种元素，M可以是H + +或一种或多种带电荷+ n的无机阳离子，t在0和0.1之间，g在0.001和0.33之间 并且x在0和0.2之间。

公开(公告)号：US6080382A

公开(公告)日：2000-06-27

申请号：US992520

申请日：1997-12-17

申请人： Gregory S. Lee ,  Stacey I. Zones

发明人： Gregory S. Lee ,  Stacey I. Zones

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J29/04 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C5/22 ,  C07C5/27 ,  C07C6/12 ,  C10G3/00 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  C10G50/00 ,  C10G65/04 ,  C01B39/06

CPC分类号： C10G50/00 ,  B01D53/8628 ,  B01D53/9418 ,  B01J29/04 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C5/226 ,  C07C5/2724 ,  C07C6/126 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  B01D2255/1021 ,  B01D2255/202 ,  B01D2255/204 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/50 ,  C07C2529/70 ,  C07C2529/74 ,  C10G2400/10 ,  Y02P30/20

摘要： The present invention relates to new crystalline zeolite SSZ-48 prepared using a decahydroquinolinium cation templating agent.

摘要翻译： 本发明涉及使用十氢喹啉阳离子模板剂制备的新的结晶沸石SSZ-48。

公开(公告)号：US5693215A

公开(公告)日：1997-12-02

申请号：US739903

申请日：1996-10-30

申请人： Stacey I. Zones ,  Dennis L. Holtermann ,  Lawrence W. Jossens ,  Donald S. Santilli ,  Andrew Rainis ,  James N. Ziemer

发明人： Stacey I. Zones ,  Dennis L. Holtermann ,  Lawrence W. Jossens ,  Donald S. Santilli ,  Andrew Rainis ,  James N. Ziemer

IPC分类号： B01J29/04 ,  B01J29/86 ,  C01B39/12 ,  C07C2/12 ,  C07C2/66 ,  C07C6/12 ,  C10G35/06 ,  C10G45/64 ,  C10G47/16 ,  C10G73/02 ,  C10G11/05 ,  C10G25/00

CPC分类号： C10G47/16 ,  B01J29/04 ,  B01J29/86 ,  C01B35/1009 ,  C01B39/12 ,  C07C2/12 ,  C07C2/66 ,  C07C6/126 ,  C10G35/065 ,  C10G45/64 ,  C07C2529/86

摘要： A crystalline low-aluminum boron beta zeolite is used for dewaxing hydrocarbonaceous feeds.

摘要翻译： 一种结晶低铝硼沸石用于脱蜡含烃原料。