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公开(公告)号：US08858891B2
公开(公告)日：2014-10-14
申请号：US14046216
申请日：2013-10-04
Applicant: BASF Corporation
Inventor： Chung-Zong Wan , Xiaolai Zheng , Susanne Stiebels , Claudia Wendt , Torsten Neubauer , R. Samuel Boorse
Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
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22.发明申请Diesel Oxidation Catalyst with Layered Structure Containing Ceria Composition as Palladium Support Material for Enhanced HC and CO Gas Conversion 有权含有二氧化铈组合物的层状结构的柴油氧化催化剂作为用于增强HC和CO气体转化的钯载体材料公开(公告)号：US20130084222A1
公开(公告)日：2013-04-04
申请号：US13624524
申请日：2012-09-21
Applicant: BASF SE , BASF Corporation
Inventor： Gerd Grubert , Torsten Neubauer , Alfred Punke , Marcus Hilgendorff , Torsten Müller-Stach , Olga Gerlach , Xinyi Wei , Jeffrey Hoke , Shiang Sung , Stanley Roth
CPC classification number: B01J29/04 , B01D53/944 , B01D53/9477 , B01D2255/1021 , B01D2255/1023 , B01D2255/9025 , B01D2258/012 , B01J23/63 , B01J29/7007 , B01J35/023 , B01J35/04 , B01J37/0036 , B01J37/0244 , B01J37/0246 , B01J2523/00 , B01J2523/3706 , B01J2523/3712 , B01J2523/3718 , B01J2523/48 , B01J2523/49 , B01J2523/31 , B01J2523/824 , B01J2523/828
Abstract: The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.
Abstract translation: 本发明涉及层状柴油氧化催化剂（DOC），其包括：a）载体基材; b）一种柴油氧化催化材料，其包含：b1）位于所述载体基底上的第一层，所述第一层包含浸渍在载体材料上的钯，所述载体材料包含基于载体材料总重量至少45重量％的二氧化铈 ，并且任选地包含铂; b2）位于所述第一层上的第二层，所述第二层包含钯和铂，各自浸渍在包含金属氧化物的载体材料上; 其中第一层的铂与钯的重量比低于第二层的铂与钯的重量比。
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公开(公告)号：US10369548B2
公开(公告)日：2019-08-06
申请号：US15124146
申请日：2015-03-11
Applicant: BASF SE , BASF Corporation
Inventor： Gerd Grubert , Alfred H. Punke , Torsten Neubauer , Marcus Hilgendorff , Chung-Zong Wan , Yuejin Li , Matthew Caudle
IPC: B01D53/94 , B01J37/02 , F01N3/28 , B01J23/72 , F01N3/035 , B01J35/00 , B01J23/42 , B01J23/89 , B01J35/04 , B01J21/12 , B01J23/44 , B01J27/224 , B01J35/10 , F01N13/10 , B01J35/02 , F01N3/08 , F01N3/10 , F01N3/20
Abstract: A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H2S emissions during normal engine operations and regeneration events.
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公开(公告)号：US10226754B2
公开(公告)日：2019-03-12
申请号：US15555142
申请日：2016-03-03
Applicant: BASF Corporation
Inventor： Gerd Grubert , Torsten Neubauer , Alfred Punke , Marcus Hilgendorff , Marko Buchholz , Matthew Caudle
IPC: B01D53/94 , B01J23/10 , B01J23/46 , B01J35/00 , B01J37/02 , B01J37/08 , B01J37/03 , B01J21/04 , B01J23/63 , B01J35/04 , B01J37/00 , F01N3/08 , F01N3/20
Abstract: A lean NOx trap composition for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO), and the trapping and reduction of nitrogen oxides (NOx) is disclosed. The lean NOx trap composition can have a washcoat layer on a carrier substrate including a first support material comprising greater than 50% by weight of a reducible metal oxide; 10 to 30% by weight of alkaline earth metal supported on a second support material comprising a refractory metal oxide and 50% or less by weight of a reducible metal oxide and; and a platinum group metal component supported on at least one of the first support material and/or the second support material. A portion of the first support material may further include 0.5% to 10% by weight of an alkaline earth metal.
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Patent Agency Ranking
公开(公告)号：US10124292B2
公开(公告)日：2018-11-13
申请号：US15590535
申请日：2017-05-09
Applicant: BASF Corporation
Inventor： Chung-Zong Wan , Xiaolai Zheng , Susanne Stiebels , Claudia Zabel , Torsten Neubauer , R. Samuel Boorse
IPC: F01N3/10 , B01D53/94 , F01N3/035 , F01N3/08 , F01N3/20 , F01N13/02 , B01D53/58 , B01D53/92 , F01N3/02 , F01N3/021
Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
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公开(公告)号：US20170241313A1
公开(公告)日：2017-08-24
申请号：US15590535
申请日：2017-05-09
Applicant: BASF Corporation
Inventor： Chung-Zong Wan , Xiaolai Zheng , Susanne Stiebels , Claudia Zabel , Torsten Neubauer , R. Samuel Boorse
CPC classification number: B01D53/9431 , B01D53/58 , B01D53/92 , B01D53/9418 , B01D53/9422 , B01D53/9472 , B01D53/9477 , B01D2251/2062 , B01D2255/102 , B01D2255/2042 , B01D2255/2045 , B01D2255/206 , B01D2255/2063 , B01D2255/2066 , B01D2255/2068 , B01D2255/20753 , B01D2255/20761 , B01D2255/2092 , B01D2255/50 , B01D2255/9022 , B01D2255/91 , B01D2255/9155 , B01D2255/9205 , B01D2258/012 , F01N3/02 , F01N3/021 , F01N3/035 , F01N3/0807 , F01N3/0814 , F01N3/0821 , F01N3/0842 , F01N3/10 , F01N3/103 , F01N3/206 , F01N3/2066 , F01N3/2073 , F01N13/02 , F01N2510/063 , F01N2510/0682 , Y02T10/24
Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
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公开(公告)号：US20170021338A1
公开(公告)日：2017-01-26
申请号：US15124146
申请日：2015-03-11
Applicant: BASF SE , BASF Corporation
Inventor： Gerd Grubert , Alfred H. Punke , Torsten Neubauer , Marcus Hilgendorff , Chung-Zong Wan , Yuejin Li , Matthew Tyler Caudle
IPC: B01J23/72 , B01J23/42 , B01J23/44 , B01J21/12 , F01N13/10 , B01J35/00 , B01J35/04 , B01J35/10 , B01J37/02 , F01N3/035 , B01D53/94 , B01J27/224
CPC classification number: B01J23/72 , B01D53/9431 , B01D53/944 , B01D53/9459 , B01D53/9468 , B01D2255/1021 , B01D2255/1023 , B01D2255/2073 , B01D2255/20738 , B01D2255/20753 , B01D2255/20761 , B01D2255/9032 , B01D2255/9155 , B01D2255/9202 , B01D2255/9207 , B01D2257/304 , B01D2258/012 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/8926 , B01J27/224 , B01J35/0006 , B01J35/023 , B01J35/04 , B01J35/10 , B01J35/1009 , B01J35/1076 , B01J37/0219 , B01J37/0234 , B01J37/0244 , B01J37/0248 , F01N3/035 , F01N3/0814 , F01N3/0842 , F01N3/103 , F01N3/2066 , F01N13/10 , F01N2570/10 , Y02A50/2341
Abstract: A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H2S emissions during normal engine operations and regeneration events.
Abstract translation: 特别是用于柴油发动机排气处理的催化烟灰过滤器包括确保烟灰颗粒过滤的辅助设计，有助于一氧化碳（CO）的氧化，并在正常的发动机操作和再生事件期间产生低的H2S排放。
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公开(公告)号：US20150298098A1
公开(公告)日：2015-10-22
申请号：US14681552
申请日：2015-04-08
Applicant: BASF Corporation
Inventor： Gary A. Gramiccioni , Andreas Richard Munding , Kenneth E. Voss , Torsten Neubauer , Stanley A. Roth
CPC classification number: B01J23/464 , B01D53/9418 , B01D53/944 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/20715 , B01D2255/2092 , B01D2255/50 , B01D2255/9022 , B01D2255/9032 , B01D2255/908 , B01D2255/9202 , B01J23/42 , B01J23/44 , B01J29/7415 , B01J35/0006 , B01J35/002 , B01J35/04 , B01J37/0219 , B01J37/0244 , B01J37/0246 , B01J2229/37 , B05D1/18 , B05D3/0493 , B05D7/22 , Y02T10/22
Abstract: Provided herein are zoned catalysts that utilize components efficiently in that relatively short zones are provided to achieve specific functionalities to convert and/or trap one or more components in the exhaust stream. Highly controlled zoned are formed from one end of a monolithic carrier. The zones have a flat profile such that the zoned catalytic material within each passage of the substrate is at a substantially uniform distance from one end of the carrier. Methods of making and using the same are also provided.
Abstract translation: 本文提供了分区催化剂，其有效地利用组分，因为提供相对短的区域以实现转化和/或捕集排气流中的一种或多种组分的特定功能。 高度受控的分区由单片载体的一端形成。 这些区域具有平坦的轮廓，使得在基底的每个通道内的分区的催化材料距离载体的一端基本上均匀的距离。 还提供了制备和使用它们的方法。
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29.发明申请Preparation of Diesel Oxidation Catalyst Via Deposition of Colloidal Nanoparticles 有权通过沉积胶体纳米颗粒制备柴油氧化催化剂公开(公告)号：US20140044627A1
公开(公告)日：2014-02-13
申请号：US14058559
申请日：2013-10-21
Applicant: BASF Corporation
Inventor： Attilio Siani , Torsten W. Müller-Stach , Torsten Neubauer , Xinyi Wei
CPC classification number: B01J23/44 , B01D53/94 , B01D53/944 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/104 , B01D2255/106 , B01J21/04 , B01J23/38 , B01J23/42 , B01J23/48 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J37/0203 , B01J37/04 , B01J37/16
Abstract: The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.
Abstract translation: 本发明涉及一种制备催化剂的方法，至少包括以下步骤：向金属前体的水溶液中加入保护剂，得到混合物（M1），向混合物（M1）中加入还原剂，得到 混合物（M2），向混合物（M2）中加入载体材料以得到混合物（M3），调节混合物（M3）的pH值，并分离混合物（M3）的固相和液相。 此外，本发明涉及催化剂及其作为柴油氧化催化剂的用途。
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