公开(公告)号：US4678766A

公开(公告)日：1987-07-07

申请号：US704694

申请日：1985-02-22

申请人： Edward J. Rosinski

发明人： Edward J. Rosinski

IPC分类号： B01J29/90 ,  C10G45/64 ,  B01J29/38

CPC分类号： C10G45/64 ,  B01J29/90 ,  Y10S423/22 ,  Y10S423/23 ,  Y10S423/25 ,  Y10S423/27 ,  Y10S423/33

摘要： A method is provided for enhancing the shape selectivity of a crystalline zeolite having a silica-to-alumina mol ratio greater than 10. The method consists of treating the zeolite with an ammonium fluoride solution at moderately elevated temperature, in the absence or in the presence of a matrix. The products are useful as shape-selective sorbents, and also as shape-selective catalysts for organic reactions including catalytic dewaxing.

摘要翻译： 提供了一种提高二氧化硅 - 氧化铝摩尔比大于10的结晶沸石的形状选择性的方法。该方法包括在不存在或存在下在适度升高的温度下用氟化铵溶液处理沸石 的矩阵。 该产品可用作形状选择性吸附剂，以及用作有机反应（包括催化脱蜡）的形状选择性催化剂。

公开(公告)号：US4430198A

公开(公告)日：1984-02-07

申请号：US425846

申请日：1982-09-28

申请人： Roland H. Heck ,  Edward J. Rosinski ,  Stuart S. Shih

发明人： Roland H. Heck ,  Edward J. Rosinski ,  Stuart S. Shih

IPC分类号： B01J27/08 ,  C10G45/08 ,  C10G45/06

CPC分类号： C10G45/08 ,  B01J27/08

摘要： An improved hydrotreating catalyst, and a process for using thereof, comprises a conventional Group VIA and Group VIIIA metal metal oxide or metal sulfide, deposited on an inorganic refractory support and about 0.1% by weight to about 7% by weight of the catalyst of a promoter comprising a halogenated metal selected from the Group consisting of halogenated metals of Group IB, IIB, IIIB, titanium and tin. The presence of the promoter results in greater degree of desulfurization and in CCR reduction of hydrocarbon feedstocks, especially highly aromatic petroleum residua and synthetically-derived hydrocarbons, e.g., coal liquids.

摘要翻译： 改进的加氢处理催化剂及其使用方法包括沉积在无机耐火载体上的常规的VIA族和VIIIA族金属氧化物或金属硫化物，和约0.1重量％至约7重量％的催化剂 促进剂，其包含选自组IB，IIB，IIIB，钛和锡的卤化金属的卤代金属。 促进剂的存在导致更大程度的脱硫和在烃原料，特别是高度芳族的石油残渣和合成衍生的烃例如煤液中的CCR还原。

公开(公告)号：US4309280A

公开(公告)日：1982-01-05

申请号：US170220

申请日：1980-07-18

申请人： Edward J. Rosinski ,  Albert B. Schwartz

发明人： Edward J. Rosinski ,  Albert B. Schwartz

IPC分类号： C10G11/02 ,  B01J29/08 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/80 ,  C10G11/00 ,  C10G11/04 ,  C10G11/05

CPC分类号： C10G11/05 ,  B01J29/40 ,  B01J29/80 ,  C10G11/04 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/084 ,  B01J29/65 ,  B01J29/70

摘要： A process is provided for increasing gasoline octane number and/or total gasoline yield in catalytic cracking units by the addition of a very small amount of finely divided shape selective additive promoter, which additive promoter is not intimately combined with a substantial amount of another solid prior to contact with the cracking catalyst. The additive promoter, in one embodiment, is a crystalline aluminosilicate zeolite having a silica to alumina mole ratio greater than about 12 and a constraint index within the approximate range of 1 to 12.

摘要翻译： 提供了一种通过加入非常少量的精细分散的形状选择性添加剂促进剂来提高催化裂化装置中汽油辛烷值和/或总汽油产率的方法，该添加剂促进剂不与先前的大量另外的固体紧密结合 与裂化催化剂接触。 在一个实施方案中，添加剂促进剂是具有大于约12的二氧化硅/氧化铝摩尔比和大约1至12范围内的约束指数的结晶硅铝酸盐沸石。

公开(公告)号：US4954243A

公开(公告)日：1990-09-04

申请号：US456037

申请日：1989-12-22

申请人： Guenter H. Kuehl ,  Edward J. Rosinski

发明人： Guenter H. Kuehl ,  Edward J. Rosinski

IPC分类号： B01J29/40 ,  C10G11/05

CPC分类号： B01J29/40 ,  C10G11/05 ,  B01J2229/16 ,  B01J2229/26 ,  B01J2229/42

摘要： A zeolite, its method of preparation and use is disclosed. The zeolite is characterized by a silica to alumina mole ratio greater than 12 and a Constraint Index of 1 to 12. The zeolite undergoes controlled alumina extraction by treatment with, e.g., strong mineral acid or chelating agent. Removal of aluminum increases the acid activity of the zeolite.

摘要翻译： 公开了一种沸石及其制备方法。 沸石的特征在于二氧化硅与氧化铝的摩尔比大于12，约束指数为1至12.沸石通过用例如强无机酸或螯合剂的处理进行受控的氧化铝提取。 去除铝增加了沸石的酸活性。

公开(公告)号：US4552648A

公开(公告)日：1985-11-12

申请号：US577941

申请日：1984-02-08

申请人： Edward J. Rosinski ,  Albert B. Schwartz ,  Francis G. Dwyer

发明人： Edward J. Rosinski ,  Albert B. Schwartz ,  Francis G. Dwyer

IPC分类号： B01J29/08 ,  B01J29/40 ,  B01J29/80 ,  C10G11/05

CPC分类号： B01J29/80 ,  B01J29/40 ,  C10G11/05 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/08 ,  B01J29/084

摘要： A process for catalytically cracking a hydrocarbon feed in a reaction zone under catalytic cracking conditions in the absence of added hydrogen with a catalyst comprising a conventional cracking catalyst. The improvement comprises adding to the conventional cracking catalyst a thermally treated zeolite having a mole ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of about 10:1 to 100:1 and a constraint index of about 1 to 12. Thermal treatment reduces the additive zeolite's alpha activity to about 1 to 10 prior to use.

摘要翻译： 在催化裂化条件下，在没有加入氢气的情况下，用含有常规裂化催化剂的催化剂，在反应区中催化裂化烃原料的方法。 改进包括向常规裂化催化剂中加入具有约10:1至100:1摩尔比的SiO 2 :Al 2 O 3的热处理沸石，约1至12的约束指数。热处理将添加沸石的α活性降低至约 使用前1至10。

公开(公告)号：US4243828A

公开(公告)日：1981-01-06

申请号：US912649

申请日：1978-06-05

申请人： George T. Kerr ,  Charles J. Plank ,  Edward J. Rosinski

发明人： George T. Kerr ,  Charles J. Plank ,  Edward J. Rosinski

IPC分类号： B01J20/18 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70 ,  C07C2/66 ,  C07C2/86 ,  C07C15/16 ,  C07C29/10 ,  C07C29/32 ,  C07C29/38 ,  C07C37/055 ,  C07C37/11 ,  C07C37/14 ,  C07C37/16 ,  C07C37/20 ,  C07C2/68 ,  C07C37/12

CPC分类号： B01J29/7007 ,  B01J20/186 ,  B01J29/087 ,  B01J29/088 ,  B01J29/18 ,  B01J29/40 ,  C01B33/2869 ,  C07C2/66 ,  C07C2/865 ,  C07C2/867 ,  C07C29/106 ,  C07C29/32 ,  C07C29/38 ,  C07C29/44 ,  C07C37/055 ,  C07C37/115 ,  C07C37/14 ,  C07C41/06 ,  C07C67/04 ,  B01J2229/16 ,  C07C2101/14 ,  C07C2529/06 ,  C07C2529/08 ,  Y02P20/52

摘要： Conversion, e.g. dehydration of aliphatic organic oxygenates having up to about 6 carbon atoms by contact with a crystalline aluminosilicate zeolite, preferably ZSM-5, having a silica to alumina ratio substantially greater than 10, at a temperature of about 70.degree. to 1400.degree. F., depending upon the exact nature of the reactant and product.

摘要翻译： 转换，例如 在大约70°至1400°F的温度下，通过与晶体硅铝酸盐沸石（优选ZSM-5）接触而具有高达约6个碳原子的脂肪族有机含氧化合物脱水，其中二氧化硅与氧化铝的比例基本上大于10。 根据反应物和产品的确切性质。

公开(公告)号：US4157293A

公开(公告)日：1979-06-05

申请号：US934234

申请日：1978-08-16

申请人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

发明人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

IPC分类号： B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  C07C2/00 ,  B01J29/28 ,  C07C15/02

CPC分类号： B01J29/46 ,  B01J29/40 ,  B01J29/405 ,  B01J29/44 ,  C07C2/00 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40

摘要： A process for converting hydrocarbons with stabilized crystalline aluminosilicate catalysts. The catalysts contain zinc, and are stabilized by adding thereto another metal of Group IB or Group VIII (e.g. copper or nickel). Germanium, rhenium and the rare earth metals may also be added.

摘要翻译： 用稳定的结晶硅铝酸盐催化剂转化烃的方法。 催化剂含有锌，并通过加入另一种IB或VIII族金属（如铜或镍）来稳定。 还可以加入锗，铼和稀土金属。

公开(公告)号：US4082695A

公开(公告)日：1978-04-04

申请号：US707790

申请日：1976-07-22

申请人： Edward J. Rosinski ,  Thomas R. Stein ,  Ronald H. Fischer

发明人： Edward J. Rosinski ,  Thomas R. Stein ,  Ronald H. Fischer

IPC分类号： B01J23/85 ,  B01J35/10 ,  C10G45/08 ,  B01J21/04 ,  B01J23/84 ,  B01J23/88

CPC分类号： C10G45/08 ,  B01J23/85 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1085

摘要： The disclosure concerns the demetalation and desulfurization of metal and sulfur containing petroleum oils, preferably those containing residua hydrocarbon components, through the use of a catalyst comprising a hydrogenating component composited on a refractory base, preferably an alumina, whose pores are substantially distributed over a narrow 100A to 200A diameter range, but also having at least about 5% of its pores of a diameter greater than 500A.

公开(公告)号：US4066531A

公开(公告)日：1978-01-03

申请号：US616964

申请日：1975-09-26

申请人： Hartley Owen ,  Paul B. Venuto ,  Edward J. Rosinski

发明人： Hartley Owen ,  Paul B. Venuto ,  Edward J. Rosinski

IPC分类号： C10G11/18 ,  C10G11/02

CPC分类号： C10G11/18 ,  C10G2400/20 ,  C10G2400/30

摘要： Liquid product rich in benzene, toluene and xylene and having a substantially lower mid-boiling point than heavy reformate feedstock or similar feedstock, such as, for example, from pyrolysis gasoline, of a class having an initial boiling point between about 230.degree. F and about 250.degree. F and an end point between about 350.degree. F and about 430.degree. F, and gaseous product rich in light olefins and isoparaffins which is good alkylation plant feed are produced by contacting said heavy reformate feedstock or said similar feedstock with a porous acid-active zeolite catalyst having a fluid activity index of at least about 18 in a fluidized catalyst system absent added hydrogen at a temperature of from about 800.degree. F to about 1200.degree. F, a catalyst/oil (i.e. heavy reformate or similar feedstock) weight ratio of from about 0.5 to about 40 and a catalyst residence time of from about 0.1 second to about 20 seconds.

公开(公告)号：US3974062A

公开(公告)日：1976-08-10

申请号：US515757

申请日：1974-10-17

申请人： Hartley Owen ,  Edward J. Rosinski ,  Paul B. Venuto

发明人： Hartley Owen ,  Edward J. Rosinski ,  Paul B. Venuto

IPC分类号： B01J8/24 ,  C10G11/18 ,  C10G11/02

CPC分类号： C10G11/18 ,  B01J8/24

摘要： A refinery process is described for converting desalted full range crude oils and syncrudes derived from coal, shale and tar sands. The process involves mixing and reacting the full range heavy oil feed with a low molecular weight carbon-hydrogen fragment contributor such as methanol or C.sub.2 -C.sub.5 olefins in the presence of a fluid zeolite cracking catalyst comprising mordenite.

摘要翻译： 描述了一种炼油方法，用于转化脱盐的全系原油和源自煤，页岩和焦油砂的合成油。 该方法包括在包含丝光沸石的流体沸石裂化催化剂存在下，使全范围重油进料与低分子量碳氢原子片段贡献者如甲醇或C 2 -C 5烯烃混合和反应。