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39 条记录 (耗时 0.029 秒)

    Two stage process for the production of molded articles
    21.
    发明授权
    Two stage process for the production of molded articles 失效
    用于生产模制品的两阶段工艺

    公开(公告)号：US4788224A

    公开(公告)日：1988-11-29

    申请号：US131959

    申请日：1987-12-11

    申请人： Hanns P. Muller ,  Walter Uerdingen ,  Heinrich Heine

    发明人： Hanns P. Muller ,  Walter Uerdingen ,  Heinrich Heine

    IPC分类号： B29C45/00 ,  C08G18/00 ,  C08G18/04 ,  C08G18/08 ,  C08G18/10 ,  C08G18/16 ,  C08G18/18 ,  C08G18/30 ,  C08G18/58 ,  C08G18/63 ,  C08G18/14

    CPC分类号： C08G18/637 ,  C08G18/003 ,  C08G18/04 ,  C08G18/089 ,  C08G18/1875 ,  C08G2101/00 ,  C08G2105/02 ,  C08G2150/20

    摘要： Molded articles are produced in a two-stage process. In the first stage, an organic polyisocyanate is reacted with an organic compound containing at least two epoxide groups (NCO: epoxide equivalent ratio of 1.2:1 to 500:1) in the presence of a tertiary amine catalyst. This reaction is stopped when no more than 65% of the isocyanate groups have reacted by adding an alkylating sulfonic acid alkyl ester of methyl iodide and/or of dimethyl sulfate in an amount equivalent to the amount of tertiary amine catalyst present. A latent catalyst capable of being activated by heat is subsequently added to the intermediate product and the resultant mixture is heated in a mold to complete the crosslinking of the intermediate product and to form the molded article.

    摘要翻译： 模制品在两阶段工艺中生产。 在第一阶段中，在叔胺催化剂的存在下，有机多异氰酸酯与含有至少两个环氧基团的有机化合物（NCO：环氧当量比为1.2:1至500:1）反应。 当不超过65％的异氰酸酯基团通过加入等量于叔胺催化剂存在量的甲基碘和/或硫酸二甲酯的烷基化磺酸烷基酯反应时，停止该反应。 随后将能够被热活化的潜催化剂加入到中间产物中，并将所得混合物在模具中加热以完成中间产物的交联并形成模塑制品。

    Low-molecular weight acrylate resins and a process for their production
    27.
    发明授权
    Low-molecular weight acrylate resins and a process for their production 失效
    低分子量丙烯酸酯树脂及其制备方法

    公开(公告)号：US4137389A

    公开(公告)日：1979-01-30

    申请号：US871248

    申请日：1978-01-23

    申请人： Frank Wingler ,  Josef Pedain ,  Walter Uerdingen

    发明人： Frank Wingler ,  Josef Pedain ,  Walter Uerdingen

    IPC分类号： C08F2/02 ,  C08F220/12 ,  C08J3/09 ,  C08F2/00 ,  C08F4/38 ,  C08F16/12

    CPC分类号： C08J3/095 ,  C08F2/02 ,  C08F220/12 ,  C08K5/06 ,  C08J2333/06

    摘要： A process for the production of a crosslinkable low-molecular weight acrylic resin containing hydroxyl-groups and having a low-molecular consistency factor by the radical bulk copolymerization of(A) 0 to 30 parts by weight of a hydroxyalkyl ester of acrylic acid or methacrylic acid or mixtures thereof;(B) 0 to 60 parts by wt. of styrene or a substituted styrene or methyl methacrylate or mixtures thereof;(C) 10 to 90 parts by weight of an acrylic acid ester or of a methacrylic acid ester with 2 to 12 carbon atoms in the alcohol radical or mixtures thereof;(D) 0 to 30 parts by weight of an .alpha.,.beta.-monoolefinically saturated mono- or di-carboxylic acid with 3 to 5 carbon atoms or of a maleic acid semiester or mixtures thereof or reaction products thereof with a monoglycidyl compound, in the presence of 10 to 70 parts by weight of a monoallyl ether of an at least trihydric alcohol,The sum of the parts by weight of all the monomers A - E amounting to 100,Wherein the indicated quantity of monomer E is initially introduced and, at temperatures above 100.degree. C, monomers A to D together with 0.5 to 6% by weight, based on A to D, of an initiator with a half-life period at 100 to 160.degree. C of 0.01 to 100 minutes, are introduced over a period of 1 to 6 hours and polymerized, at least 98% by weight of the monomers A to D and from 36 to 95% by weight of monomer E being converted. Acrylate resins of this type are eminently suitable for the production of readily processible binder mixtures which although low in viscosity, have a very high solids content.

    摘要翻译： 一种通过（A）0-30重量份的丙烯酸或甲基丙烯酸羟烷基酯的自由基本体共聚生产含羟基并具有低分子稠度因子的可交联的低分子量丙烯酸树脂的方法 酸或其混合物; （B）0〜60重量份。 的苯乙烯或取代的苯乙烯或甲基丙烯酸甲酯或其混合物; （C）10至90重量份的丙烯酸酯或醇基中具有2至12个碳原子的甲基丙烯酸酯或其混合物; （D）0至30重量份具有3至5个碳原子的α，β-单烯烃饱和的单羧酸或二羧酸或马来酸半酯或其混合物或其与单缩水甘油基化合物的反应产物，在 存在10至70重量份的至少三元醇的单烯丙基醚，所有单体A-E的重量份数为100，由于初始引入了单体E的指示数量，并且在 温度高于100℃，单体A至D和基于A至D的0.5至6重量％的引发剂，其在100至160℃下的半衰期为0.01至100分钟的引发剂通过 时间为1至6小时并聚合，至少98重量％的单体A至D和36至95重量％的单体E被转化。 这种类型的丙烯酸酯树脂非常适用于生产易于加工的粘合剂混合物，尽管粘度低，但固体含量非常高。

    Process for the preparation of polyisocyanates containing urethane and biuret groups
    28.
    发明授权
    Process for the preparation of polyisocyanates containing urethane and biuret groups 失效
    制备含氨基甲酸酯和缩二脲基团的多异氰酸酯的方法

    公开(公告)号：US4124569A

    公开(公告)日：1978-11-07

    申请号：US832318

    申请日：1977-09-12

    申请人： Manfred Bock ,  Josef Pedain ,  Walter Uerdingen ,  Manfred Schonfelder

    发明人： Manfred Bock ,  Josef Pedain ,  Walter Uerdingen ,  Manfred Schonfelder

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C273/18 ,  C07C275/48 ,  C07C275/62 ,  C08G18/78 ,  C08G18/80 ,  C08G18/79

    CPC分类号： C07C273/1863 ,  C07C273/1872 ,  C08G18/7831 ,  C08G18/8041 ,  C08G18/8058

    摘要： The present invention is concerned with a process for producing biuret polyisocyanates and the polyisocyanates so produced. These isocyanates are produced by the reaction of at least about a four fold molar excess of a diisocyanate having aliphatically bound isocyanate groups with amino alcohols having a particular structure at a temperature between about 90 and 200.degree. C. The amino alcohols contain at least three carbon atoms, have their hydroxyl and amino groups separated by at least two carbon atoms, and may contain urea, urethane, ether or amino bonds. The present invention is also concerned with a process for producing two component and one component moisture curing lacquers using the biuret polyisocyanates of the present invention and the lacquers so produced.

    摘要翻译： 本发明涉及制备缩二脲多异氰酸酯的方法和如此制备的多异氰酸酯。 这些异氰酸酯是通过至少约四倍摩尔过量的具有脂肪族结合的异氰酸酯基团的二异氰酸酯与具有特定结构的氨基醇在约90-200℃之间的温度下进行的反应来制备的。氨基醇含有至少三个碳 原子，其羟基和氨基被至少两个碳原子分开，并且可以含有脲，氨基甲酸酯，醚或氨基键。 本发明还涉及使用本发明的缩二脲多异氰酸酯和如此制备的漆制备两组分和一种组分的湿固化漆的方法。