Method for preparing a composition comprising perfluoropolyether having a carboxyl group at one terminal
    57.
    发明授权
    Method for preparing a composition comprising perfluoropolyether having a carboxyl group at one terminal 有权
    制备包含一端具有羧基的全氟聚醚的组合物的方法

    公开(公告)号:US09217059B2

    公开(公告)日:2015-12-22

    申请号:US14615171

    申请日:2015-02-05

    摘要: An object of the present invention is to provide a method for efficiently and highly selectively preparing a composition comprising a perfluoropolyether having a carboxyl group at one terminal at a higher ratio. The present invention provides a method for increasing a ratio of a perfluoropolyether having a carboxyl group at one terminal, relative to a total amount of the perfluoropolyether having a carboxyl group at one terminal and a perfluoropolyether having carboxyl groups at both terminals in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a carboxyl group at one terminal at a higher ratio. Further, present invention provides for increasing a ratio of a perfluoropolyether having a carboxyl group at one terminal, relative to a total amount of the perfluoropolyether having a carboxyl group at one terminal, a perfluoropolyether having carboxyl groups at both terminals and a perfluoropolyether having no carboxyl group at any terminal perfluoropolyether, in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a carboxyl group at one terminal at a higher ratio.

    摘要翻译: 本发明的目的是提供一种高效选择性地制备包含在一个末端具有较高比例的具有羧基的全氟聚醚的组合物的方法。 本发明提供一种提高一端具有羧基的全氟聚醚的比例相对于在一末端具有羧基的全氟聚醚的总量和在两末端具有羧基的全氟聚醚的比例的方法, 全氟聚醚,其中所述方法包括使组合物进行色谱,其中移动相是特定温度和比压的超临界或亚临界状态二氧化碳,并且固定相是硅胶,从而收集含有全氟聚醚的级分 在一个末端具有较高比例的羧基。 此外,本发明提供了增加一端具有羧基的全氟聚醚的比例,相对于一端具有羧基的全氟聚醚的总量,两末端具有羧基的全氟聚醚和不具有羧基的全氟聚醚 在包含这些全氟聚醚的组合物中的任何末端全氟聚醚组,其中该方法包括使组合物进行色谱,其中移动相是特定温度和比压的超临界或亚临界状态二氧化碳,以及固定相 是硅胶,从而在一个末端以更高的比例收集含有具有羧基的全氟聚醚的级分。

    METHOD FOR PREPARING A COMPOSITION COMPRISING PERFLUOROPOLYETHER HAVING A CARBOXYL GROUP AT ONE TERMINAL
    58.
    发明申请
    METHOD FOR PREPARING A COMPOSITION COMPRISING PERFLUOROPOLYETHER HAVING A CARBOXYL GROUP AT ONE TERMINAL 有权
    在一个端子上制备含有羧基的全氟代乙烯基醚的组合物的方法

    公开(公告)号:US20150218311A1

    公开(公告)日:2015-08-06

    申请号:US14615171

    申请日:2015-02-05

    IPC分类号: C08G65/00

    摘要: An object of the present invention is to provide a method for efficiently and highly selectively preparing a composition comprising a perfluoropolyether having a carboxyl group at one terminal at a higher ratio. The present invention provides a method for increasing a ratio of a perfluoropolyether having a carboxyl group at one terminal, relative to a total amount of the perfluoropolyether having a carboxyl group at one terminal and a perfluoropolyether having carboxyl groups at both terminals in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a carboxyl group at one terminal at a higher ratio. Further, present invention provides for increasing a ratio of a perfluoropolyether having a carboxyl group at one terminal, relative to a total amount of the perfluoropolyether having a carboxyl group at one terminal, a perfluoropolyether having carboxyl groups at both terminals and a perfluoropolyether having no carboxyl group at any terminal perfluoropolyether, in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a carboxyl group at one terminal at a higher ratio.

    摘要翻译: 本发明的目的是提供一种高效选择性地制备包含在一个末端具有较高比例的具有羧基的全氟聚醚的组合物的方法。 本发明提供一种提高一端具有羧基的全氟聚醚的比例相对于在一末端具有羧基的全氟聚醚的总量和在两末端具有羧基的全氟聚醚的比例的方法, 全氟聚醚,其中所述方法包括使组合物进行色谱,其中移动相是特定温度和比压的超临界或亚临界状态二氧化碳,并且固定相是硅胶,从而收集含有全氟聚醚的级分 在一个末端具有较高比例的羧基。 此外,本发明提供了增加一端具有羧基的全氟聚醚的比例,相对于一端具有羧基的全氟聚醚的总量,两末端具有羧基的全氟聚醚和不具有羧基的全氟聚醚 在包含这些全氟聚醚的组合物中的任何末端全氟聚醚组,其中该方法包括使组合物进行色谱,其中移动相是特定温度和比压的超临界或亚临界状态二氧化碳,以及固定相 是硅胶,从而在一个末端以更高的比例收集含有具有羧基的全氟聚醚的级分。

    Process for Production of Poly(Arylene Sulfide)
    59.
    发明申请
    Process for Production of Poly(Arylene Sulfide) 审中-公开
    聚(亚硫酰基)生产工艺

    公开(公告)号:US20150175748A1

    公开(公告)日:2015-06-25

    申请号:US14135219

    申请日:2013-12-19

    IPC分类号: C08G75/14

    摘要: A process for producing a poly(arylene sulfide) polymer comprising (a) polymerizing reactants in a reaction vessel to produce a poly(arylene sulfide) reaction mixture, (b) processing the poly(arylene sulfide) reaction mixture to obtain a poly(arylene sulfide) polymer and a by-product slurry, (c) removing (e.g., evaporating) at least a portion of the by-product slurry to yield salt solids particulates, wherein at least a portion of the evaporating is carried out while simultaneously sizing the salt solids particulates to a desired size.

    摘要翻译: 一种制备聚(亚芳基硫醚)聚合物的方法,包括(a)在反应容器中聚合反应物以产生聚(亚芳基硫醚)反应混合物,(b)加工聚(亚芳基硫醚)反应混合物以获得聚(亚芳基硫醚) 硫化物)聚合物和副产物浆料,(c)除去(例如,蒸发)至少一部分副产物浆料以产生盐固体颗粒,其中至少部分蒸发进行同时施胶 盐固体颗粒至所需尺寸。