公开(公告)号：US07045579B2

公开(公告)日：2006-05-16

申请号：US10383600

申请日：2003-03-07

Applicant: Keimpe Jan Van Den Berg ,  Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Marcel Johannes Antonius Mensink ,  Kenny Abdoel Nassier Raghosing ,  Edith Hulsbos

Inventor： Keimpe Jan Van Den Berg ,  Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Marcel Johannes Antonius Mensink ,  Kenny Abdoel Nassier Raghosing ,  Edith Hulsbos

IPC: C09D129/14 ,  C09D201/06 ,  C09D175/04 ,  C08K5/37

CPC classification number: C09D175/04 ,  C07C237/08 ,  C07C271/16 ,  C08G18/0866 ,  C08G18/12 ,  C08G18/283 ,  C08G18/3819 ,  C08G18/4036 ,  C08G18/423 ,  C08G18/8108 ,  C08G18/834 ,  C08K5/37 ,  C08K5/372 ,  C08L31/02 ,  C08L75/04 ,  C09D129/14 ,  C09D175/10 ,  Y10T428/28 ,  C08G18/3876 ,  C08G18/3271 ,  C08L57/04 ,  C08L2666/20 ,  C08L2666/04 ,  C08L75/10

Abstract: The invention relates to a coating composition comprising an acetal-functional binder and a thiol-functional cross-linker, wherein the acetal-functional binder is represented by the following formula wherein P is a binder backbone, K is a divalent and/or trivalent organic moiety having 1 to 30 carbon atoms and having one or two links to the binder backbone, A is selected from oxygen, sulphur, and NRVII, wherein RVII is hydrogen or an alkyl group with 1 to 4 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 10, and R and R′ may be the same or different and represent alkyl groups with 1 to 4 carbon atoms. In a further aspect, the invention relates to acetal-functional binders, acetal-functional monomers, a process for the preparation of said monomers, coating compositions comprising said acetal-functional binders, and to a process for the preparation of a coating composition comprising an acetal-functional polyurethane dispersion and a thiol-functional cross-linker.

Abstract translation: 本发明涉及包含缩醛官能粘合剂和硫醇官能交联剂的涂料组合物，其中缩醛官能粘合剂由下式表示：其中P是粘合剂主链，K是二价和/或三价有机物 具有1至30个碳原子并且具有一个或两个连接到粘合剂主链的部分，A选自氧，硫和NR VII，其中R VII是氢或 具有1至4个碳原子的烷基，m为1至50的整数，n为1至10的整数，R和R'可以相同或不同，表示具有1至4个碳原子的烷基。 在另一方面，本发明涉及缩醛官能的粘合剂，缩醛官能单体，制备所述单体的方法，包含所述缩醛官能粘合剂的涂料组合物，以及制备涂料组合物的方法，所述涂料组合物包含 缩醛官能聚氨酯分散体和硫醇功能交联剂。

公开(公告)号：US20050240042A1

公开(公告)日：2005-10-27

申请号：US10518098

申请日：2003-07-09

Applicant: Michael Hartung ,  Ulrich Heimann ,  Karl-Heinz Grosse-Brinkhaus ,  Hardy Reuter

Inventor： Michael Hartung ,  Ulrich Heimann ,  Karl-Heinz Grosse-Brinkhaus ,  Hardy Reuter

IPC: C09D201/00 ,  C09D5/08 ,  C09D5/44 ,  C09D7/06 ,  C09D7/12 ,  C09D175/04 ,  C09D201/06 ,  C07F9/70

CPC classification number: C09D5/086 ,  C09D5/4492 ,  C09D7/47

Abstract: Electrocoat materials comprising bismuth compounds, further comprising (A) at least one self-crosslinking and/or externally crosslinking binder containing (potentially) cationic or anionic groups and reactive functional groups which (i) with themselves or with complementary reactive functional groups in the self-crosslinking binder, or (ii) in the case of the externally crosslinking binder, with complementary reactive functional groups present in crosslinking agents (B) are able to undergo thermal crosslinking reactions, (B) if desired, at least one crosslinking agent comprising the complementary reactive functional groups, and (C) bismuth subsalicylate of empirical formula C7H5O4Bi.

Abstract translation: 包含铋化合物的电涂层材料还包含（A）至少一种含（潜在）阳离子或阴离子基团和反应性官能团的自交联和/或外部交联的粘合剂，（i）其自身或在自身中具有互补的反应性官能团 - 交联粘合剂，或（ii）在外部交联粘合剂的情况下，存在于交联剂（B）中的互补的反应性官能团能够进行热交联反应，（B）如果需要，至少一种包含 互补的反应性官能团，和（C）经验式C 7 H 5 O 4 Bi的亚硫酸铋。

公开(公告)号：US06914087B2

公开(公告)日：2005-07-05

申请号：US09926632

申请日：2001-03-29

Applicant: Katsuhiko Okada ,  Tetsuro Agawa ,  Kouji Shinohara ,  Yoshitaka Konishi

Inventor： Katsuhiko Okada ,  Tetsuro Agawa ,  Kouji Shinohara ,  Yoshitaka Konishi

IPC: B05D7/24 ,  C09D5/03 ,  C09D7/12 ,  C09D201/02 ,  C09D201/06 ,  B05D1/36 ,  C08L63/00

CPC classification number: C09D5/03

Abstract: A powder coating is provided which does not require a long complicated production process, can be produced easily and with no danger of gelling occurring during production, and which forms a paint film with superior smoothness and with no film defects such as bubbles or pinholes. A powder coating raw materials solution comprising as essential constituents a room temperature solid main constituent resin (A) with a curable reactive group, a room temperature solid curing agent (B) which reacts with the curable reactive group of the main constituent resin (A), and an organic solvent (C), is spray dried at a temperature at which the main constituent resin (A) and the curing agent (B) undergo no substantial curing reaction.

Abstract translation: 提供粉末涂料，其不需要长的复杂生产工艺，可以容易地制备，并且在生产过程中不会发生胶凝的危险，并且形成具有优异平滑度和没有膜缺陷如气泡或针孔的漆膜。 一种粉末涂料原料溶液，其包含具有可固化反应性基团的室温固体主要构成树脂（A）和与主要构成树脂（A）的可固化反应性基团反应的室温固体固化剂（B）作为必要组分） 和有机溶剂（C）在主要构成树脂（A）和固化剂（B）不发生实质固化反应的温度下进行喷雾干燥。

公开(公告)号：US06894084B2

公开(公告)日：2005-05-17

申请号：US09781682

申请日：2001-02-12

Applicant: Robert F. Kovar ,  Nese Orbey ,  Stanley Wentworth

Inventor： Robert F. Kovar ,  Nese Orbey ,  Stanley Wentworth

IPC: C08F2/46 ,  C08F2/44 ,  C08F2/48 ,  C08F24/00 ,  C08F290/06 ,  C08F299/02 ,  C08G18/30 ,  C08G18/67 ,  C09D4/00 ,  C09D4/02 ,  C09D4/06 ,  C09D5/00 ,  C09D167/07 ,  C09D175/04 ,  C09D175/06 ,  C09D175/16 ,  C09D183/04 ,  C09D201/06 ,  C08F2/50 ,  C08F4/44

CPC classification number: C09D175/16 ,  C08G18/671 ,  C08G18/6715 ,  C08G18/765 ,  C08G18/8175 ,  C09D4/06 ,  C09D167/07 ,  C08F290/067

Abstract: The present invention provides radiation curable resin compositions that contain no or essentially no volatile organic components (VOCs), and to methods of using these compositions. The radiation curable resin compositions find particular use as coating compositions. In particular, the radiation curable resin compositions of this invention comprise a vinyl dioxolane end-capped oligomer blended with a photoinitiator.

Abstract translation: 本发明提供了不含或基本上不含挥发性有机成分（VOC）的辐射固化树脂组合物，以及使用这些组合物的方法。 辐射固化树脂组合物特别用作涂料组合物。 特别地，本发明的可辐射固化树脂组合物包含与光引发剂共混的乙烯基二氧戊环封端的低聚物。

公开(公告)号：US20050082169A1

公开(公告)日：2005-04-21

申请号：US10963717

申请日：2004-10-14

Applicant: Hideaki Katsuta ,  Shingo Sato ,  Yoshizumi Matsuno

Inventor： Hideaki Katsuta ,  Shingo Sato ,  Yoshizumi Matsuno

IPC: B05D1/36 ,  B05D7/24 ,  C08L53/00 ,  C09D5/02 ,  C09D7/12 ,  C09D123/00 ,  C09D153/00 ,  C09D175/04 ,  C09D201/06 ,  C25D13/00

CPC classification number: C08L53/00 ,  C09D153/00 ,  C08L2666/02 ,  C08L2666/04

Abstract: An automobile body-used light-colored water based coating composition containing a water dispersion (A1) prepared by water-dispersing a block copolymer resin (A) comprising a copolymer (a1) obtained by copolymerizing a monomer component containing an olefin monomer and a copolymer (a2) obtained by copolymerizing a monomer component containing a carboxyl group or carboxylic anhydride group-containing vinyl monomer, a hydroxyl group-containing resin (B), a curing agent (C) and a color pigment, a resulting coating film having a lightness L* value in accordance with a L*a*b* color system as defined in JIS Z 8729 in the range of 80 or more.

Abstract translation: 一种汽车车身使用的浅色水基涂料组合物，其含有通过水分散嵌段共聚物树脂（A）制备的水分散体（A 1），所述嵌段共聚物树脂（A）包含共聚物（a 1 < 通过使含有烯烃单体的单体组分和通过共聚含有含羧基或含羧酸酐基的乙烯基单体的单体组分和羟基基团共聚而获得的共聚物（α2 S） 含有树脂（B），固化剂（C）和着色颜料的涂膜，所得到的涂膜具有根据JIS Z 8729中定义的L * a * b *颜色系统的亮度L *值，其范围为80 或者更多。

公开(公告)号：US06160058A

公开(公告)日：2000-12-12

申请号：US184196

申请日：1998-11-02

Applicant: Walter H. Ohrbom ,  Gregory G. Menovcik ,  Donald L. St. Aubin ,  John E. Boisseau ,  John W. Rehfuss

Inventor： Walter H. Ohrbom ,  Gregory G. Menovcik ,  Donald L. St. Aubin ,  John E. Boisseau ,  John W. Rehfuss

IPC: C07D251/34 ,  C08F8/30 ,  C08G12/40 ,  C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/30 ,  C08G18/38 ,  C08G18/46 ,  C08G18/66 ,  C08G18/80 ,  C08G59/14 ,  C08G71/00 ,  C08G81/02 ,  C08K5/3492 ,  C08L61/20 ,  C09D133/00 ,  C09D133/06 ,  C09D161/20 ,  C09D167/00 ,  C09D167/04 ,  C09D169/00 ,  C09D175/00 ,  C09D175/02 ,  C09D175/04 ,  C09D201/02 ,  C09D201/06 ,  C08G8/28 ,  C08L63/00 ,  C08L67/04

CPC classification number: C09D201/025 ,  C07D251/34 ,  C08F8/30 ,  C08G12/40 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/2865 ,  C08G18/302 ,  C08G18/3829 ,  C08G18/3831 ,  C08G18/3853 ,  C08G18/4615 ,  C08G18/6633 ,  C08G18/8077 ,  C08G59/1438 ,  C08G59/1477 ,  C08G59/1494 ,  C08G71/00 ,  C08G81/021 ,  C08K5/34924 ,  C08L61/20 ,  C09D133/06 ,  C09D133/062 ,  C09D161/20 ,  C09D167/00 ,  C09D167/04 ,  C09D169/00 ,  C09D175/00 ,  C09D175/02 ,  C09D175/04 ,  C09D201/02 ,  C09D201/06 ,  C08L2666/16 ,  C08L2666/14 ,  C08L2666/28 ,  C08L2666/02

Abstract: The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes an acrylic polymer comprising active hydrogen-containing functional groups reactive with the third component(c). Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.

Abstract translation: 本发明提供了包含至少三种组分的可固化涂料组合物。 涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或 具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。 涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的丙烯酸聚合物。 涂料组合物的组分（c）是与前两种组分反应的固化剂。 还公开了使用本发明组合物制备涂层制品。

公开(公告)号：US6087464A

公开(公告)日：2000-07-11

申请号：US621171

申请日：1996-03-21

Applicant: Vijay Swarup ,  Frank N. Jones ,  Albert I. Yezrielev ,  Ramachandran P. Subrayan

Inventor： Vijay Swarup ,  Frank N. Jones ,  Albert I. Yezrielev ,  Ramachandran P. Subrayan

IPC: C08G18/32 ,  C08G18/65 ,  C08G18/66 ,  C08G18/72 ,  C08G18/80 ,  C09D161/32 ,  C09D175/04 ,  C09D201/06 ,  C08G18/42 ,  C08G18/58 ,  C08G18/62

CPC classification number: C09D175/04 ,  C08G18/3215 ,  C08G18/3221 ,  C08G18/6511 ,  C08G18/664 ,  C08G18/728 ,  C08G18/8067 ,  C09D201/06

Abstract: The present invention is directed to a polymeric vehicle, a formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a polyol, an isocyanate compound and a phenolic ester alcohol having at least one aliphatic hydroxyl group and at least one phenolic hydroxyl group.

Abstract translation: 本发明涉及聚合物载体，配制的涂料组合物和由聚合物载体制成的涂料粘合剂，以及制备聚合物载体的方法，其中聚合物载体包含多元醇，异氰酸酯化合物和酚酯醇，至少具有 一个脂族羟基和至少一个酚羟基。

公开(公告)号：US5976706A

公开(公告)日：1999-11-02

申请号：US123065

申请日：1998-07-27

Applicant: Albert Ilya Yezrielev ,  Konstantinos R. Rigopoulos ,  Richard William Ryan ,  Karen K. Kuo ,  George Andrew Knudsen

Inventor： Albert Ilya Yezrielev ,  Konstantinos R. Rigopoulos ,  Richard William Ryan ,  Karen K. Kuo ,  George Andrew Knudsen

IPC: C07C69/44 ,  C08G63/16 ,  C08G63/78 ,  C09D167/02 ,  C09D201/06 ,  B32B27/06 ,  C08F20/00

CPC classification number: C09D201/06 ,  C07C69/44 ,  C08G63/16 ,  C08G63/78 ,  C09D167/02 ,  Y10T428/31794

Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.

Abstract translation: 通过使用一种或多种脂族二羧酸或其酯衍生物酯化一种或多种脂族二羧酸或其酯衍生物来制备具有小于3500cps的低粘度，高含量超过96重量％的非挥发性物质和小于约1.4的窄分子量分布的聚酯二醇 至少1.5摩尔过量的一种或多种脂族二醇直到酸值小于20，并从聚酯二醇反应产物中除去过量的二醇。 在使用酯化催化剂的情况下，在从聚酯二醇反应产物中除去过量的未反应二醇之前，基本上除去了催化剂。 所生产的聚酯二醇可用作（i）可热固树脂组合物中的可固化组分，特别是基本上不含挥发性有机溶剂的组合物，并且还含有交联剂和反应性硬化剂：和/或（ii）可用作涂料，涂料和粘合剂 ，提供具有非常低含量的挥发性有机化合物的涂层。

公开(公告)号：US5976615A

公开(公告)日：1999-11-02

申请号：US890501

申请日：1997-07-09

Applicant: Gregory G. Menovcik ,  John G. Partyka ,  Aimee R. Barach ,  Sanjay Mehta

Inventor： Gregory G. Menovcik ,  John G. Partyka ,  Aimee R. Barach ,  Sanjay Mehta

IPC: B05D1/36 ,  C09D5/00 ,  C09D129/10 ,  C09D133/00 ,  C09D161/20 ,  C09D163/00 ,  C09D201/02 ,  C09D201/06 ,  B05D7/16 ,  B05D7/24

CPC classification number: C09D201/025

Abstract: A curable coating composition is described comprising a carbamate functional material and a crosslinking agent, reactive with the carbamate group. The composition further comprises a third component that is a mixture of catalysts including a phosphorus containing acid or acid derivative and other acid catalysts. Coatings prepared with this coating composition can be cured and coated with additional coating(s), providing good intercoat adhesion to the subsequent coating.

Abstract translation: 描述了可固化涂料组合物，其包含与氨基甲酸酯基团反应的氨基甲酸酯官能材料和交联剂。 组合物还包含第三组分，其是包含含磷酸或酸衍生物和其它酸催化剂的催化剂的混合物。 用该涂料组合物制备的涂料可以固化并涂覆另外的涂层，为随后的涂层提供良好的涂层粘附性。

公开(公告)号：US5972422A

公开(公告)日：1999-10-26

申请号：US71083

申请日：1998-05-01

Applicant: Herbert L. Harmon

Inventor： Herbert L. Harmon

IPC: B05D7/00 ,  B05D5/00 ,  C08G18/38 ,  C08G18/62 ,  C09D133/06 ,  C09D175/00 ,  C09D201/02 ,  C09D201/06 ,  B05D1/38 ,  B05D3/02 ,  B05D7/26 ,  B32B35/00

CPC classification number: C09D133/062 ,  B05D5/005 ,  C09D201/02

Abstract: The invention provides a method for providing a low bake repair to a cured coating, especially a composite coating and low bake repair compositions for use therein. The method of the invention involves the provision of a cured coated surface and the application of a low bake repair coating to at least a portion of the cured coated surface. The low bake repair coating of the invention has (A) a film forming component comprising (a) a first component comprising a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and (b) a second component comprising a compound reactive with said carbamate or urea groups on component (a), and (B) a catalyst comprising a compound selected from the group consisting of Al(ClO.sub.4).sub.2, Zr(ClO.sub.4).sub.2, and Al(NO.sub.3).sub.2. The low bake repair coating is cured at a temperature of less than 200.degree. F. for a time sufficient to cure the low bake repair coating.

Abstract translation: 本发明提供了一种为固化涂层提供低烘烤修复的方法，特别是用于其中的复合涂层和低烘烤修复组合物。 本发明的方法包括提供固化的涂覆表面和将低烘烤修复涂层施加到固化的涂覆表面的至少一部分上。 本发明的低烘烤修复涂层具有（A）成膜组分，其包含（a）第一组分，其包含附有至少一个氨基甲酸酯或脲官能团的化合物或可转化为氨基甲酸酯或脲基的基团，以及 （b）第二组分，其包含与组分（a）上的所述氨基甲酸酯或脲基反应的化合物，和（B）包含选自Al（ClO 4）2，Zr（ClO 4）2和 Al（NO3）2。 低温烘烤修复涂层在低于200°F的温度下固化足够固化低温修复涂层的时间。