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    Transparent Decoratable Multilayer Film
    61.
    发明申请
    Transparent Decoratable Multilayer Film 有权

    公开(公告)号：US20080213552A1

    公开(公告)日：2008-09-04

    申请号：US11816588

    申请日：2006-01-04

    申请人： Harald Hager ,  Michael Beyer ,  Franz-Erich Baumann

    发明人： Harald Hager ,  Michael Beyer ,  Franz-Erich Baumann

    IPC分类号： B32B27/08 ,  B32B7/00

    CPC分类号： B32B27/34 ,  B32B27/08 ,  B32B2250/24 ,  B32B2307/412 ,  B32B2307/75 ,  B32B2519/00 ,  C08L23/0846 ,  C08L23/0869 ,  C08L23/0884 ,  C08L23/0892 ,  C08L77/00 ,  C08L77/10 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/24975 ,  Y10T428/31725 ,  Y10T428/31728 ,  C08L2666/06 ,  C08L2666/04

    摘要： A multilayer film which comprises the following layers: I. an upper layer composed of a polyamide molding composition which is transparent at the selected layer thickness, and II. a lower layer composed of a polyamide molding composition which comprises the following components: a) from 70 to 99% by weight of a polyamide selected from α) polyamides that can be prepared from lactam monomers or from the corresponding ω-aminocarboxylic acids having 6, 7, 8, 9, 10, 11, or 12 carbon atoms, β) polyamides based on diamine and dicarboxylic acids, in each case having from 6 to 18 carbon atoms, γ) polyamide elastomers that can be prepared from oligomeric, difunctional units based on one of the polyamides mentioned under α) and β), and on a difunctional oligoalkylene glycol, δ) copolyamides that can be prepared from the following components: from 50 to 99.9 mol % of a lactam monomer or of the corresponding ω-aminocarboxylic acid having 6, 7, 8, 9, 10, 11, or 12 carbon atoms, or of a substantially equimolar mixture composed of a linear aliphatic diamine and of a linear aliphatic or aromatic dicarboxylic acid in each case having from 6 to 18 carbon atoms, and from 0.1 to 50 mol % of the combination of a diamine and a dicarboxylic acid, where either the diamine or the dicarboxylic acid or both differ from the diamine used, if appropriate, in the other component and, respectively, the dicarboxylic acid used, if appropriate, in the other component, or of another lactam; b) from 1 to 30% by weight of a copolymer which contains units of the following monomers: α) from 20 to 94.5% by weight of one or more α-olefins having from 2 to 12 carbon atoms, β) from 5 to 79.5% by weight of one or more acrylic compounds, γ) from 0 to 50% by weight of an olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline, or oxazinone has good printability and adhesive-bondability and transparency, and can be used, for example, as an overcoating for skis.

    Transparent Moulding Compound
    62.
    发明申请
    Transparent Moulding Compound 审中-公开
    透明模塑料

    公开(公告)号：US20080166529A1

    公开(公告)日：2008-07-10

    申请号：US11816595

    申请日：2006-01-04

    申请人： Harald Hager ,  Franz-Erich Baumann ,  Michael Beyer

    发明人： Harald Hager ,  Franz-Erich Baumann ,  Michael Beyer

    IPC分类号： C08L77/02 ,  B32B3/10

    CPC分类号： C08J5/18 ,  C08G69/08 ,  C08G69/265 ,  C08G69/36 ,  C08J2377/00 ,  C08L77/04 ,  C08L77/06 ,  Y10T428/24802 ,  C08L2666/54

    摘要： A molding composition which comprises the following components: a) a semicrystalline copolyamide and b) an effective amount of a crystallization aid selected from nanoscale fillers and metal salts, metal oxides, or metal hydroxides which can react with the carboxy end groups of the copolyamide, where the copolyamide can be prepared from the following monomer combination: α) from 50 to 99 mol % of a lactam or of a corresponding co-aminocarboxylic acid having 8, 9, 10, 11, or 12 carbon atoms or of a substantially equimolar mixture composed of a diamine and of a dicarboxylic acid, where the diamine has been selected from the group of 1,6-hexamethylenediamine, 1,8-octamethylenediamine, 1,10-decamethylenediamine, and 1,12-dodecamethylenediamine, and the dicarboxylic acid has been selected from the group of sebacic acid and 1,12-dodecanedioic acid, and β) from 1 to 50 mol % of a substantially equimolar mixture composed of a diamine and of a dicarboxylic acid, where either the diamine or the dicarboxylic acid or both differ from the diamine used, if appropriate, under α) and, respectively, the dicarboxylic acid used, if appropriate under α), or of another lactam and, respectively, ω-aminocarboxylic acid, is transparent and has good processability, and gives good results in decoration by means of screen printing.

    摘要翻译： 一种模塑组合物，其包含以下组分：a）半结晶共聚酰胺和b）有效量的结晶助剂，其选自可与共聚酰胺的羧基端基反应的纳米级填料和金属盐，金属氧化物或金属氢氧化物， 其中共聚酰胺可以由以下单体组合制备：α）50-99mol％的内酰胺或相应的具有8,9,10,11或12个碳原子的共 - 氨基羧酸或基本上等摩尔混合物 由二胺和二羧酸组成，其中二胺选自1,6-己二胺，1,8-辛二胺，1,10-癸二胺和1,12-十二亚甲基二胺，二羧酸具有 选自癸二酸和1,12-十二烷二酸，和β）1至50摩尔％的由二胺和二羧酸组成的基本上等摩尔的混合物，其中二胺 或二羧酸或两者均不同于所使用的二胺，如果合适的话，在α下）和分别使用的二羧酸（如果适合的话），或另外的内酰胺和分别为ω-氨基羧酸的透明性和具有 良好的加工性，并通过丝网印刷在装饰上取得了良好的效果。

    Process for producing moldings with an increase in the melt stiffness
    63.
    发明申请
    Process for producing moldings with an increase in the melt stiffness 有权
    具有增加熔体刚度的生产模制品的方法

    公开(公告)号：US20060183869A1

    公开(公告)日：2006-08-17

    申请号：US11354114

    申请日：2006-02-15

    申请人： Andreas Dowe ,  Rainer Goring ,  Martin Himmelmann ,  Sonja Bollmann ,  Franz-Erich Baumann ,  Roland Wursche

    发明人： Andreas Dowe ,  Rainer Goring ,  Martin Himmelmann ,  Sonja Bollmann ,  Franz-Erich Baumann ,  Roland Wursche

    IPC分类号： C08C19/24

    CPC分类号： C08K5/098 ,  C08L69/00 ,  C08L77/02 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L77/00 ,  C08L2666/14

    摘要： A process for producing moldings with condensing-up of a polyamide molding composition whose polyamide component contains, as a result of the method of preparation, at least 5 ppm of phosphorus in the form of an acidic compound by means of a compound having at least two carbonate units, wherein a) from 0.001 to 10% by weight, based on the polyamide, of a salt of a weak acid is added to the polyamide molding composition prior to compounding or during compounding, b) a mixture of the finished composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, effects a significant increase in the melt stiffness combined with moderate processing presssures, which considerably simplifies, in particular, the production of hollow bodies and hollow profiles having large diameters.

    摘要翻译： 一种聚酰胺成型组合物的制造用模制品的制造方法，其聚酰胺成分作为制备方法的结果，含有至少5ppm的酸性化合物形式的磷，该化合物具有至少两个 碳酸酯单元，其中a）基于聚酰胺的0.001至10重量％的弱酸盐在配混之前或在配混期间加入到聚酰胺模塑组合物中，b）成品组合物和 制备具有至少两个碳酸酯单元的化合物，c）如果合适的话，该混合物被储存和/或运输，以及d）随后将该混合物加工以产生模制物，其中仅在该步骤中发生冷凝， 结合中等加工压力的熔体刚度的显着增加，这特别地简化了具有大直径的中空体和中空型材的生产。

    Process for producing moldings with an increase in the melt stiffness
    69.
    发明授权
    Process for producing moldings with an increase in the melt stiffness 有权
    具有增加熔体刚度的生产模制品的方法

    公开(公告)号：US08647551B2

    公开(公告)日：2014-02-11

    申请号：US11354114

    申请日：2006-02-15

    申请人： Andreas Dowe ,  Rainer Goering ,  Martin Himmelmann ,  Sonja Bollmann ,  Franz-Erich Baumann ,  Roland Wursche

    发明人： Andreas Dowe ,  Rainer Goering ,  Martin Himmelmann ,  Sonja Bollmann ,  Franz-Erich Baumann ,  Roland Wursche

    IPC分类号： C08F283/04 ,  C08L77/00 ,  B29C49/00

    CPC分类号： C08K5/098 ,  C08L69/00 ,  C08L77/02 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L77/00 ,  C08L2666/14

    摘要： A process for producing moldings with condensing-up of a polyamide molding composition whose polyamide component contains, as a result of the method of preparation, at least 5 ppm of phosphorus in the form of an acidic compound by means of a compound having at least two carbonate units, wherein a) from 0.001 to 10% by weight, based on the polyamide, of a salt of a weak acid is added to the polyamide molding composition prior to compounding or during compounding, b) a mixture of the finished composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, effects a significant increase in the melt stiffness combined with moderate processing pressures, which considerably simplifies, in particular, the production of hollow bodies and hollow profiles having large diameters.

    摘要翻译： 一种聚酰胺成型组合物的制造用模制品的制造方法，其聚酰胺成分作为制备方法的结果，含有至少5ppm的酸性化合物形式的磷，该化合物具有至少两个 碳酸酯单元，其中a）基于聚酰胺的0.001至10重量％的弱酸盐在配混之前或在配混期间加入到聚酰胺模塑组合物中，b）成品组合物和 制备具有至少两个碳酸酯单元的化合物，c）如果合适的话，该混合物被储存和/或运输，以及d）随后将该混合物加工以产生模制物，其中仅在该步骤中发生冷凝， 结合中等加工压力的熔体刚度的显着增加，这特别地简化了具有大直径的中空体和中空型材的生产。