Polyolefin-substituted amines grafted with poly(aromatic-n-monomers) for
olegaginous compositions
    61.
    发明授权
    Polyolefin-substituted amines grafted with poly(aromatic-n-monomers) for olegaginous compositions 失效
    用聚合(芳族 - n-单体)接枝的聚烯烃取代的胺用于olegaginous组合物

    公开(公告)号:US5871554A

    公开(公告)日:1999-02-16

    申请号:US9615

    申请日:1998-01-20

    Abstract: Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments. The long chain hydrocarbon-substituted reactant can comprise materials such as (i) long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups; (ii) halogenated long chain hydrocarbons; (iii) mixtures of formaldehyde and a long chain hydrocarbyl substituted phenol; and (iv) mixtures of formaldehyde and a reaction product formed by reaction of long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups and an amino-substituted, optionally hydrocarbyl-substituted phenol.

    Abstract translation: 已经发现包含与芳族含N单体如苯胺接枝的聚烯烃取代的胺的新型聚合物在含油组合物(包括燃料和润滑油)中提供具有分散剂和抗氧化性能的油溶性聚合物。 本发明的聚合物在电气应用中更有用。 这些材料通过一种方法形成,该方法包括:(a)使具有至少两个反应性氮部分的胺化合物与至少一种长链烃取代的反应物以足以形成含有N的聚合物加合物的量和条件 反应性胺基,和(b)在聚合条件下使含N聚合物加合物与至少一种含芳族N的单体接触,以使含有N的聚合物链段与含N的聚合物链段接枝。 长链烃取代的反应物可以包括以下材料,例如(i)被单或二羧酸,酸酐或酯基取代的长链烃; (ii)卤代长链烃; (iii)甲醛和长链烃基取代的苯酚的混合物; 和(iv)甲醛和通过用单或二羧酸,酸酐或酯基和氨基取代的任选被烃基取代的苯酚取代的长链烃反应形成的反应产物的混合物。

    Low volatility lubricating compositions
    64.
    发明授权
    Low volatility lubricating compositions 失效
    低挥发性润滑组合物

    公开(公告)号:US5789355A

    公开(公告)日:1998-08-04

    申请号:US777739

    申请日:1996-12-20

    Abstract: This invention relates to low volatility 5W20, 5W30, 10W40, 10W50, 15W40 or 15W50 multigrade oils for crankcase lubrication of gasoline and diesel engines, the oils comprising: a) basestock having an average basestock neutral number of not less than 105 for a 5W multigrade, not less than 145 for a 10W multigrade and not less than 200 for a 15W multigrade, b) a detergent inhibitor package including an ashless dispersant comprising an oil soluble polymeric hydrocarbon backbone having functional groups in which the hydrocarbon backbone is derived from an ethylene alpha-olefin (EAO) copolymer or alpha-olefin homo- or copolymer having an M.sub.n of from 500 to 7000, and preferably having >30% of terminal vinylidene unsaturation, and c) a viscosity modifier. These multigrade crankcase oils provide better volatility with reduced use or even without the need for expensive light neutral basestocks or non-conventional lubricant basestocks, while at the same time providing adequate control of sludge and varnish.

    Abstract translation: 本发明涉及用于汽油和柴油发动机的曲轴箱润滑的低挥发性5W20,5W30,10W40,10W50,15W40或15W50多级油,所述油包括:a)对于5W多级油料,所述油的平均基础油中性数不小于105的基础油 ,对于10W多级而不小于145,对于15W多重级,不小于200; b)包含无灰分散剂的洗涤剂抑制剂包,其包含具有官能团的油溶性聚合烃骨架,其中烃主链衍生自乙烯α α-烯烃(EAO)共聚物或α-烯烃均聚物或共聚物,其具有500至7000的+ E,ovs M + EE n,优选具有> 30%的末端亚乙烯基不饱和度,和c)粘度调节剂。 这些多级曲轴箱油提供更好的挥发性,减少使用,甚至不需要昂贵的轻质中性基础油或非常规润滑剂基础油,同时提供对污泥和清漆的适当控制。

    Polyolefin-substituted amines grafted with poly (aromatic-N-monomers)
for oleaginous compositions
    65.
    发明授权
    Polyolefin-substituted amines grafted with poly (aromatic-N-monomers) for oleaginous compositions 失效
    与聚(芳族-N-单体)接枝的聚烯烃取代的胺用于油性组合物

    公开(公告)号:US5756434A

    公开(公告)日:1998-05-26

    申请号:US823259

    申请日:1997-03-24

    Abstract: Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments. The long chain hydrocarbon-substituted reactant can comprise materials such as (i) long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups; (ii) halogenated long chain hydrocarbons; (iii) mixtures of formaldehyde and a long chain hydrocarbyl substituted phenol; and (iv) mixtures of formaldehyde and a reaction product formed by reaction of long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups and an amino-substituted, optionally hydrocarbyl-substituted phenol.

    Abstract translation: 已经发现包含与芳族含N单体如苯胺接枝的聚烯烃取代的胺的新型聚合物在含油组合物(包括燃料和润滑油)中提供具有分散剂和抗氧化性能的油溶性聚合物。 本发明的聚合物在电气应用中更有用。 这些材料通过一种方法形成,该方法包括:(a)使具有至少两个反应性氮部分的胺化合物与至少一种长链烃取代的反应物以足以形成含有N的聚合物加合物的量和条件 反应性胺基,和(b)在聚合条件下使含N聚合物加合物与至少一种含芳族N的单体接触,以使含有N的聚合物链段与含N的聚合物链段接枝。 长链烃取代的反应物可以包括以下材料,例如(i)被单或二羧酸,酸酐或酯基取代的长链烃; (ii)卤代长链烃; (iii)甲醛和长链烃基取代的苯酚的混合物; 和(iv)甲醛和通过用单或二羧酸,酸酐或酯基和氨基取代的任选被烃基取代的苯酚取代的长链烃反应形成的反应产物的混合物。

Patent Agency Ranking