公开(公告)号：US07217850B2

公开(公告)日：2007-05-15

申请号：US10840364

申请日：2004-05-07

申请人： Emmanuelle Guillon ,  Eric Sanchez ,  Patrick Briot

发明人： Emmanuelle Guillon ,  Eric Sanchez ,  Patrick Briot

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/50 ,  C07C2529/70 ,  C07C2529/80 ,  C07C15/107

摘要： The invention relates to a process for the production of phenylalkanes comprising an alkylation reaction of at least one aromatic compound by at least one linear olefin having from 9 to 16 carbon atoms per molecule. Said reaction is carried out in a catalytic reactor in which n reaction zones are present each containing at least one same solid acid catalyst, n being greater than or equal to 2, and at the inlet to each of which at least one fraction of the total quantity of olefins necessary for said reaction is introduced. The phenylalkanes obtained by the process according to the invention are particularly suitable for manufacturing detergents.

摘要翻译： 本发明涉及一种制备苯基烷烃的方法，其包括至少一种芳族化合物由至少一种每分子具有9至16个碳原子的直链烯烃的烷基化反应。 所述反应在催化反应器中进行，其中存在n个反应区，每个反应区含有至少一个相同的固体酸催化剂，n大于或等于2，并且在每个反应区至少有一部分 引入所述反应所需的烯烃的量。 通过本发明的方法获得的苯基烷烃特别适用于制造洗涤剂。

公开(公告)号：US07029642B2

公开(公告)日：2006-04-18

申请号：US11071582

申请日：2005-03-04

申请人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

发明人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

IPC分类号： C01B33/38

CPC分类号： C01B39/48 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B37/005 ,  C01B37/02 ,  C01B39/08 ,  C01B39/085 ,  C10G49/08

摘要： The invention concerns a novel crystalline solid UVL-1 which has an X ray diffraction diagram containing at least the following characteristic peaks: dhkl (A)2theta (°)I/I0 11.697.55mw to vs 7.5011.79vw to w 5.7615.36w to mw 3.7024.00m to s 3.5724.91s 3.3626.49vs 3.1428.48w to mw 2.5035.88vw 2.4137.30vw and with a chemical composition, expressed as the anhydrous compound, in terms of moles of oxide: (XO2):(Y2O3)m:(Z2/nO)p in which: X represents at least one tetravalent element selected from the group formed by Si, Ge; Y represents at least one trivalent element selected from Al, B, Cr, Ga; Z represents at least one cation with valency n; and in which: n is in the range 2 to 4, m is in the range 0 to 0.2, preferably in the range 0 to 0.05, and p is in the range 0 to 0.2, preferably in the range 0 to 0.05. The invention also concerns a hydrocracking/hydroconversion process and a hydrorefining process employing said solid in the catalyst composition.

公开(公告)号：US20050196335A1

公开(公告)日：2005-09-08

申请号：US11071582

申请日：2005-03-04

申请人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

发明人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

IPC分类号： B01J21/16 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B33/26 ,  C01B33/38 ,  C01B37/00 ,  C01B37/02 ,  C01B39/08 ,  C01B39/48 ,  C07B61/00 ,  C07C4/06 ,  C10G45/12 ,  C10G45/64 ,  C10G47/20 ,  C10G49/08 ,  H04L12/28 ,  H04L29/06 ,  C01B39/46

CPC分类号： C01B39/48 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B37/005 ,  C01B37/02 ,  C01B39/08 ,  C01B39/085 ,  C10G49/08

摘要： The invention concerns a novel crystalline solid UVL-1 which has an X ray diffraction diagram containing at least the following characteristic peaks: dhkl (A)2theta (°)I/I0 11.697.55mw to vs 7.5011.79vw to w 5.7615.36w to mw 3.7024.00m to s 3.5724.91s 3.3626.49vs 3.1428.48w to mw 2.5035.88vw 2.4137.30vw and with a chemical composition, expressed as the anhydrous compound, in terms of moles of oxide:  (XO2):(Y2O3)m:(Z2/nO)p in which: X represents at least one tetravalent element selected from the group formed by Si, Ge; Y represents at least one trivalent element selected from Al, B, Cr, Ga; Z represents at least one cation with valency n; and in which: n is in the range 2 to 4, m is in the range 0 to 0.2, preferably in the range 0 to 0.05, and p is in the range 0 to 0.2, preferably in the range 0 to 0.05. The invention also concerns a hydrocracking/hydroconversion process and a hydrorefining process employing said solid in the catalyst composition.

公开(公告)号：US09914113B2

公开(公告)日：2018-03-13

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G45/12 ,  C10G47/06 ,  C10G65/12 ,  B01J29/04 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C10G49/08

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

公开(公告)号：US09290704B2

公开(公告)日：2016-03-22

申请号：US13102384

申请日：2011-05-06

申请人： Emmanuelle Guillon ,  Nicolas Cadran ,  Natacha Touchais ,  Laurent Bournay ,  Lionel Magna ,  Helene Olivier-Bourbigou

发明人： Emmanuelle Guillon ,  Nicolas Cadran ,  Natacha Touchais ,  Laurent Bournay ,  Lionel Magna ,  Helene Olivier-Bourbigou

IPC分类号： C10G50/00 ,  C10G1/00 ,  C10G3/00

CPC分类号： C10G50/00 ,  C07C1/24 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P20/52 ,  Y02P30/20 ,  C07C11/04

摘要： The invention describes a process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, comprising a stage for purification of said feedstock, a stage for dehydration of said purified feedstock into an effluent that is for the most part ethylene and comprises water, at least one stage for separating water, a first stage for oligomerization of the effluent that is for the most part ethylene into at least one olefinic effluent that comprises at least 80% by weight of olefins that have four or more carbon atoms, in the presence of a homogeneous catalyst that comprises at least one bivalent nickel compound, whereby a second oligomerization stage produces middle distillate hydrocarbon bases in the presence of an amorphous or zeolitic catalyst that has at least pore openings that contain 10 or 12 oxygen atoms, producing middle distillate hydrocarbon bases, and a fractionation stage.

摘要翻译： 本发明描述了从由生物质获得的可再生来源生产的乙醇原料生产中间馏分烃碱的方法，其包括用于纯化所述原料的阶段，将所述纯化原料脱水成流出物的步骤 大部分是乙烯并且包括水，至少一个用于分离水的阶段，用于将流出物低聚的第一阶段，其大部分是乙烯至少一种烯烃流出物，其包含至少80重量％的烯烃 在含有至少一种二价镍化合物的均相催化剂的存在下，其具有四个或更多个碳原子，由此第二低聚阶段在无定形或沸石催化剂存在下产生中间馏分烃基，其至少具有孔开口， 含有10或12个氧原子，产生中间馏分烃基和分馏阶段。

公开(公告)号：US08936717B2

公开(公告)日：2015-01-20

申请号：US13057781

申请日：2009-07-29

申请人： Emmanuelle Guillon ,  Laurent Simon

发明人： Emmanuelle Guillon ,  Laurent Simon

IPC分类号： C10G47/02 ,  B01J29/072 ,  B01J29/076 ,  B01J29/76 ,  B01J29/78 ,  B01J37/00 ,  B01J37/20 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  B01J21/04 ,  B01J21/12

CPC分类号： B01J29/76 ,  B01J21/04 ,  B01J21/12 ,  B01J29/78 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention relates to a catalyst comprising at least one IZM-2 zeolite, at least one amorphous matrix, at least one hydro-dehydrogenating element selected from the group formed by the elements from group VIB and from group VIII of the periodic table and excluding platinum and palladium. The catalyst also optionally contains a controlled quantity of at least one doping element selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally a group VIIA element. The invention also relates to hydrocracking and hydrotreatment processes implementing this catalyst.

摘要翻译： 本发明涉及包含至少一种IZM-2沸石，至少一种无定形基质，至少一种加氢脱氢元素的催化剂，所述至少一种加氢脱氢元件选自由元素周期表中VIB族和VIII族元素形成的基团，不包括 铂和钯。 催化剂还任选地含有受控量的至少一种选自磷，硼和硅的掺杂元素，任选地包含元素周期表第VB族中的至少一种元素，以及任选的第VIIA族元素。 本发明还涉及实施该催化剂的加氢裂化和加氢处理方法。

公开(公告)号：US08877982B2

公开(公告)日：2014-11-04

申请号：US13812921

申请日：2011-07-19

申请人： Flora Chambon ,  Nadine Essayem ,  Franck Rataboul ,  Catherine Pinel ,  Amandine Cabiac ,  Emmanuelle Guillon

发明人： Flora Chambon ,  Nadine Essayem ,  Franck Rataboul ,  Catherine Pinel ,  Amandine Cabiac ,  Emmanuelle Guillon

IPC分类号： C07C45/51 ,  C07C29/14 ,  B01J37/02 ,  B01J37/30 ,  C07C29/00 ,  B01J37/08 ,  C07C45/60 ,  B01J23/652

CPC分类号： C07C45/51 ,  B01J23/6527 ,  B01J37/0201 ,  B01J37/0209 ,  B01J37/086 ,  B01J37/30 ,  C07C29/00 ,  C07C45/60 ,  C07C31/205 ,  C07C47/19

摘要： The invention relates to a process for transformation of lignoceliulosic biomass or cellulose that uses tungsten-oxide-based heterogeneous catalysts that are dispersed on an oxide-based substrate, preferably with a base of oxide(s) of aluminum and/or zirconium and/or titanium and/or niobium and containing an element in the particular metallic state. The use of these catalysts makes it possible to obtain directly upgradable products containing three carbon atoms, in particular hydroxyacetone and propylene glycol with high selectivity.

摘要翻译： 本发明涉及一种转化木质素生物质或纤维素的方法，其使用分散在基于氧化物的基质上，优选以铝和/或锆的氧化物和/或碱的氧化物为基础的非均相催化剂和/或 钛和/或铌，并含有特定金属状态的元素。 使用这些催化剂使得可以以高选择性获得含有三个碳原子的直接可升级产物，特别是羟基丙酮和丙二醇。

公开(公告)号：US08679323B2

公开(公告)日：2014-03-25

申请号：US12942315

申请日：2010-11-09

申请人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

发明人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC分类号： C10G47/20 ,  B01J29/10

CPC分类号： C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： A process is described for the production of middle distillates from a paraffinic feedstock wherein the feedstock is subjected to hydrocracking and/or hydro-isomerization in the presence of a hydrocracking/hydro-isomerization catalyst. The catalyst comprises at least one hydro-dehydrogenating metal selected from metals of groups VIB and VIII, and a substrate that comprises at least one dealuminified Y zeolite. The dealuminified Y zeolite is modified by a basic treatment stage wherein the dealuminified Y zeolite is mixed with a basic aqueous solution, and at least one heat treatment stage.

摘要翻译： 描述了从石蜡原料生产中间馏分的方法，其中原料在加氢裂化/加氢异构化催化剂存在下进行加氢裂化和/或加氢异构化。 该催化剂包含至少一种选自VIB和VIII族金属的氢化脱氢金属，以及包含至少一种脱铝Y沸石的底物。 脱铝Y沸石通过碱处理阶段进行改性，其中脱铝Y沸石与碱性水溶液和至少一个热处理阶段混合。

公开(公告)号：US08324439B2

公开(公告)日：2012-12-04

申请号：US12489885

申请日：2009-06-23

申请人： Emmanuelle Guillon ,  Christophe Bouchy ,  Nathalie Dupassieux ,  Antoine Daudin ,  Thierry Chapus

发明人： Emmanuelle Guillon ,  Christophe Bouchy ,  Nathalie Dupassieux ,  Antoine Daudin ,  Thierry Chapus

IPC分类号： C07C1/00

CPC分类号： C10G3/50 ,  B01J23/883 ,  B01J29/74 ,  B01J29/78 ,  B01J37/20 ,  B01J37/28 ,  C10G3/46 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

摘要： A method of treating feedstocks from renewable sources in order to produce diesel fuel bases of excellent quality. The feedstocks used can be, for example, raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The method includes fixed bed catalytic hydrotreatment, followed by fixed bed hydroisomerization with a catalyst based on monodimensional 10 MR zeolite and at least one metal from group VIII and/or VIB.

摘要翻译： 一种从可再生能源处理原料以生产出优质柴油燃料基料的方法。 所使用的原料可以是例如以前经受预精制阶段，动物脂肪或这些原料的混合物的生植物油或这种油。 该方法包括固定床催化加氢处理，然后用基于单维10 MR沸石和至少一种VIII族和/或VIB金属的催化剂进行固定床加氢异构化。

公开(公告)号：US20120283498A1

公开(公告)日：2012-11-08

申请号：US13463403

申请日：2012-05-03

申请人： Emmanuelle Guillon ,  Christophe Bouchy ,  Eric Sanchez

发明人： Emmanuelle Guillon ,  Christophe Bouchy ,  Eric Sanchez

IPC分类号： C07C5/22

CPC分类号： B01J27/224 ,  B01J23/08 ,  B01J23/14 ,  B01J23/36 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/466 ,  B01J23/468 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J29/20 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/7073 ,  B01J29/7084 ,  B01J29/7446 ,  B01J29/7469 ,  B01J29/7646 ,  B01J29/7669 ,  B01J29/7846 ,  B01J29/7869 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J2229/186 ,  C01B39/48 ,  C07C5/2754 ,  C07C5/2791 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/224 ,  C07C2529/18 ,  C07C2529/70 ,  C10G45/64 ,  C10G2300/1096 ,  C10G2300/4018 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/08

摘要： A process for isomerization of an aromatic fraction that contains at least one aromatic compound that has eight carbon atoms per molecule is described, with said process comprising bringing said fraction into contact with a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a composite that is formed by a zeolite that is selected from among the EUO-, MTW- and MOR-structural type zeolites and silicon carbide SiC.

摘要翻译： 描述了含有至少一种每分子具有八个碳原子的芳族化合物的芳族馏分的异构化方法，所述方法包括使所述馏分与包含至少一种氢化脱氢金属的催化剂接触，所述催化剂选自 由元素周期表VIB族和VIII族的金属形成的基团和由选自EUO-，MTW-和MOR - 结构型沸石和碳化硅SiC的沸石形成的复合材料。