公开(公告)号：US09109089B2

公开(公告)日：2015-08-18

申请号：US14656743

申请日：2015-03-13

Applicant: PRC-DeSoto International, Inc.

Inventor： Steven J. Hobbs ,  Gregory J. McCollum ,  Juexiao Cai ,  Marfi Ito ,  Lawrence G. Anderson ,  Renhe Lin

IPC: C08G75/10 ,  C08G75/12 ,  C08G77/00 ,  C09J181/02 ,  C08G65/34 ,  C07D251/30 ,  C08G65/336

CPC classification number: C09D175/08 ,  C07C265/04 ,  C07C265/12 ,  C07D251/30 ,  C08G18/006 ,  C08G18/3857 ,  C08G18/5072 ,  C08G65/336 ,  C08G65/34 ,  C08G75/02 ,  C08G75/10 ,  C08G75/12 ,  C08G77/00 ,  C09D5/34 ,  C09D175/10 ,  C09J181/02

Abstract: Disclosed are multifunctional sulfur-containing polymers that are the reaction products of a sulfur-containing diol, a polyol containing at least three hydroxyl groups per polyol molecule, and an aldehyde, a ketone, or a combination thereof. Sealant compositions comprising the multifunctional sulfur-containing polymers are also disclosed.

Abstract translation: 公开了多元官能的含硫聚合物，其是含硫二醇，每多元醇分子含有至少三个羟基的多元醇和醛，酮或其组合的反应产物。 还公开了包含多官能含硫聚合物的密封剂组合物。

公开(公告)号：US09109076B2

公开(公告)日：2015-08-18

申请号：US13143781

申请日：2010-01-08

Applicant: Paul A. Charpentier ,  Kevin D. Burgess

Inventor： Paul A. Charpentier ,  Kevin D. Burgess

IPC: C08G18/48 ,  C08G18/32 ,  C08G18/34 ,  C08G18/38 ,  C08G18/76 ,  C08G18/10 ,  C08G18/82 ,  C08G18/83 ,  C08G18/08 ,  C09D7/12 ,  C09D175/04 ,  C09D175/08 ,  C08L75/04 ,  C08L75/08 ,  C08K3/22 ,  C08K9/02

CPC classification number: C08G18/4854 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/348 ,  C08G18/3897 ,  C08G18/7671 ,  C08G18/82 ,  C08G18/838 ,  C08K3/22 ,  C08K9/02 ,  C08K2003/2241 ,  C08L75/04 ,  C08L75/08 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68 ,  C09D175/04 ,  C09D175/08

Abstract: The present invention provides two methods for synthesizing novel titania-polyurethane (nTiO2-PU) nanocomposites for self-cleaning coatings, one a polymer functionalization method (“grafting to”) and the other, a monomer functionalization method (“grafting from”). Here, 2,2 bis(hydroxymethyl) propionic acid (HMPA) was used as the coordination agent, which was reacted with n-TiO2 (50:50 anatase/rutile) to form nTiO2-HMPA, then polymerized in the monomer functionalization method. In the polymer functionalization method, HMPA was reacted with a pre-polymer to form the PU, and then subsequently reacted with n-TiO2 to form the polymer nanocomposite. The photocatalytic cleanability of the nanocomposites was investigated when exposed to ultraviolet radiation using additional unreacted HMPA or stearic acid as the model “dirt” compounds. Nanocomposites prepared using both strategies showed similar self-cleaning behavior, although the monomer technique gave less substrate degradation.

Abstract translation: 本发明提供两种用于自清洁涂层的新型二氧化钛 - 聚氨酯（nTiO 2 -PU）纳米复合材料的方法，一种是聚合物官能化方法（“接枝”），另一种是单体官能化方法（“从”接枝“）。 这里，使用2,2双（羟甲基）丙酸（HMPA）作为配位剂，与n-TiO2（50:50锐钛型/金红石）反应形成nTiO 2 -HMPA，然后以单体官能化方法进行聚合。 在聚合物官能化方法中，HMPA与预聚物反应形成PU，然后与n-TiO 2反应形成聚合物纳米复合材料。 当使用附加的未反应的HMPA或硬脂酸作为模型“污垢”化合物暴露于紫外线照射时，研究了纳米复合材料的光催化清洁性。 使用这两种策略制备的纳米复合材料显示出类似的自清洁行为，尽管单体技术给出较少的底物降解。

公开(公告)号：US09096773B2

公开(公告)日：2015-08-04

申请号：US13577043

申请日：2011-02-04

Applicant: Dean C. Webster ,  Partha Pratim Sengupta ,  Zhigang Chen ,  Xiao Pan ,  Adlina Paramarta

Inventor： Dean C. Webster ,  Partha Pratim Sengupta ,  Zhigang Chen ,  Xiao Pan ,  Adlina Paramarta

IPC: C08G59/17 ,  C08G59/34 ,  C08G59/58 ,  C08L63/00 ,  C08L63/10 ,  C09D163/00 ,  C08G59/42 ,  C08G59/02 ,  C08G59/14 ,  C08G59/16

CPC classification number: C08G59/027 ,  C07D303/16 ,  C08G59/02 ,  C08G59/1438 ,  C08G59/1455 ,  C08G59/1466 ,  C08G59/34 ,  C08G59/4207 ,  C08G59/4215 ,  C08G59/4223 ,  C08L63/00 ,  C08L63/10 ,  C09D163/00 ,  C09D163/08 ,  C09D175/08

Abstract: The invention provides highly functional epoxy resins that may be used themselves in coating formulations and applications but which may be further functionalized via ring-opening reactions of the epoxy groups yielding derivative resins with other useful functionalities. The highly functional epoxy resins are synthesized from the epoxidation of vegetable or seed oil esters of polyols having 4 or more hydroxyl groups/molecule. In one embodiment, the polyol is sucrose and the vegetable or seed oil is selected from corn oil, castor oil, soybean oil, safflower oil, sunflower oil, linseed oil, tall oil fatty acid, tung oil, vernonia oil, and mixtures thereof. Methods of making of the epoxy resin and each of its derivative resins are disclosed as are coating compositions and coated objects using each of the resins.

Abstract translation: 本发明提供高功能的环氧树脂，其可以自己用于涂料配方和应用中，但可以通过环氧基团的开环反应进一步官能化，从而产生衍生树脂与其它有用的官能团。 高功能环氧树脂由具有4个或更多个羟基/分子的多元醇的植物油或种子油酯的环氧化合成。 在一个实施方案中，多元醇是蔗糖，植物油或种子油选自玉米油，蓖麻油，大豆油，红花油，向日葵油，亚麻籽油，妥尔油脂肪酸，桐油，葵花籽油及其混合物。 公开了环氧树脂及其衍生树脂的制备方法，即涂料组合物和使用每种树脂的涂覆物体。

公开(公告)号：US20150166859A1

公开(公告)日：2015-06-18

申请号：US14413159

申请日：2013-07-12

Applicant: SIKA TECHNOLOGY AG

Inventor： Fabien Choffat ,  Manuel Nestler

IPC: C09J175/08 ,  C09D175/08 ,  C08K5/10 ,  C08K3/26

CPC classification number: C09J175/08 ,  C08G18/10 ,  C08G18/807 ,  C08G65/33348 ,  C08G65/336 ,  C08K3/26 ,  C08K5/10 ,  C08K2003/265 ,  C09D175/08 ,  C09J175/04 ,  C08G18/289

Abstract: A moisture-cure composition is described that includesa) at least one silane-functional polymer P; b) at least one catalyst for cross-linking of silane functional polymers; and c) at least 65% w/w of at least one filler, wherein the composition in the fully cured state has a Shore A hardness of ≧60, determined in accordance with DIN 53505, and prior to curing has an extrusion pressure of ≦1000 N.

Abstract translation: 描述了一种湿气固化组合物，其包括a）至少一种硅烷官能聚合物P; b）至少一种用于硅烷官能聚合物交联的催化剂; 和c）至少65％w / w的至少一种填料，其中完全固化状态的组合物具有根据DIN 53505测定的肖氏A硬度≥60，并且在固化之前的挤出压力为＆amp; ; 1000 N.

公开(公告)号：US20150159042A1

公开(公告)日：2015-06-11

申请号：US14563765

申请日：2014-12-08

Applicant: Thomas P. Daly

Inventor： Thomas P. Daly

IPC: C09D175/08

CPC classification number: C09D175/08 ,  C08G18/3275 ,  C08G18/36 ,  C08G18/73 ,  C09D175/04

Abstract: A water vapor permeable, water resistant film with a pore size greater than that of water vapor, but smaller than that of a water droplet, or roughly about 90 microns, comprising a polymer, prepolymer, oligamer, or copolymer containing a fatty group pendant to a backbone of the form: Where R is a saturated or unsaturated, branched or linear alkyl group with from 5 to 22 carbons and n is the common designation of a repeating unit.

Abstract translation: 具有大于水蒸气孔径的水蒸汽透过性防水膜，但小于水滴的水蒸汽透过性防水膜，或者约为90微米，包含含有脂肪族的聚合物，预聚物，寡聚体或共聚物， 形式的骨架：其中R是具有5至22个碳的饱和或不饱和的支链或直链烷基，n是重复单元的通用名称。

公开(公告)号：US20150130878A1

公开(公告)日：2015-05-14

申请号：US14524502

申请日：2014-10-27

Applicant: Shizuka KOHZUKI ,  Mie Yoshino ,  Takao Hiraoka

Inventor： Shizuka KOHZUKI ,  Mie Yoshino ,  Takao Hiraoka

IPC: C09D11/102 ,  C09D175/06 ,  C09D175/08 ,  C09D175/04

CPC classification number: C09D11/101 ,  C09D11/102 ,  C09D11/30 ,  C09D175/04 ,  C09D175/06 ,  C09D175/08

Abstract: Provided is an active energy ray-curable inkjet ink containing at least photopolymerizable compounds. The photopolymerizable compounds include: at least one monofunctional monomer selected from the group consisting of a monofunctional monomer of which homopolymer has a glass transition temperature of 90° C. or higher, a monofunctional monomer having a ring structure, and a monofunctional monomer of which homopolymer has a glass transition temperature of 90° C. or higher and that has a ring structure; and urethane (meth)acrylate.

Abstract translation: 提供至少含有可光聚合化合物的活性能量射线固化型喷墨油墨。 可光聚合化合物包括：至少一种单官能单体，其选自均聚物的玻璃化转变温度为90℃以上的单官能单体，具有环结构的单官能单体和均聚物的单官能单体 玻璃化转变温度为90℃以上，具有环结构; 和氨基甲酸酯（甲基）丙烯酸酯。

公开(公告)号：US20150110981A1

公开(公告)日：2015-04-23

申请号：US14058751

申请日：2013-10-21

Applicant: PPG Industries Ohio, Inc.

Inventor： John Dudik ,  Qin Li ,  Youssef Moussa ,  Randy Daughenbaugh ,  James Rowley ,  Kareem Kaleem

IPC: C09D175/06

CPC classification number: C09D175/06 ,  C08G71/04 ,  C09D175/08 ,  Y10T428/1352

Abstract: A coating composition for application to the surface of a container comprising: (a) a film-forming resinous material comprising a functional group-containing reaction product of: (i) a cyclic carbonate group-containing material, (ii) a polyamine; (b) a curing agent reactive with functional groups of (a); (c) a liquid diluent.

Abstract translation: 一种用于在容器表面施用的涂料组合物，包括：（a）成膜树脂材料，其包含以下官能团的反应产物：（i）含环碳酸酯基的材料，（ii）多胺; （b）与（a）的官能团反应的固化剂; （c）液体稀释剂。

公开(公告)号：US20150017459A1

公开(公告)日：2015-01-15

申请号：US14375586

申请日：2013-02-04

Applicant: DSM IP ASSETS B.V.

Inventor： Tijs Nabuurs ,  Gerardus Cornelis Overbeek ,  Jeffrey Stubbs ,  Matthew Stewart Gebhard

IPC: C08F220/18 ,  B05D3/10 ,  B05D3/02 ,  B05D3/06 ,  C09D133/12 ,  C09D133/08

CPC classification number: C08F301/00 ,  B05D3/0254 ,  B05D3/06 ,  B05D3/108 ,  C08F8/32 ,  C08F8/42 ,  C08F8/44 ,  C08F22/10 ,  C08F22/38 ,  C08F26/06 ,  C08F26/08 ,  C08F220/06 ,  C08F220/14 ,  C08F220/18 ,  C08F222/04 ,  C08F222/14 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/03 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/50 ,  C08L33/02 ,  C08L33/10 ,  C08L33/12 ,  C08L35/02 ,  C08L51/003 ,  C08L67/08 ,  C08L75/00 ,  C08L75/04 ,  C08L2201/52 ,  C09D125/14 ,  C09D133/02 ,  C09D133/08 ,  C09D133/10 ,  C09D133/12 ,  C09D133/14 ,  C09D135/02 ,  C09D151/003 ,  C09D153/00 ,  C09D167/08 ,  C09D175/04 ,  C09D175/08 ,  Y02P20/582 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: There is described a method of preparing a post-modified polymer the method comprising the steps of: (1) polymerising a monomer composition comprising from 2.5 to 75% by weight of the total monomer composition of at least one itaconic anhydride, precursor thereof and/or derivative thereof in a polymerisation method to obtain an itaconate Polymer A; (2) reacting in a post modification step at least 10 mole-% of the anhydride groups, anhydride precursor groups and/or anhydride derived groups of the Polymer A obtained from step (1) with a Nucleophile B to form a post-modified Polymer C, and optionally using said polymer C as seed or stabiliser in a further step (3) to form a sequential Polymer D.

Abstract translation: 描述了制备后修饰聚合物的方法，该方法包括以下步骤：（1）将包含2.5至75重量％的总单体组合物的至少一个衣康酸酐的前体和/ 或其衍生物在聚合方法中得到衣康酸酯聚合物A; （2）在后修饰步骤中使步骤（1）获得的聚合物A的酸酐基团，酸酐前体基团和/或酸酐衍生基团与亲核试剂B反应，以形成后修饰聚合物 并且在另外的步骤（3）中任选地使用所述聚合物C作为种子或稳定剂以形成顺序的聚合物D.

公开(公告)号：US20140377464A1

公开(公告)日：2014-12-25

申请号：US14376222

申请日：2013-02-04

Applicant: DSM IP ASSETS B.V.

Inventor： Tijs Nabuurs ,  Gerardus Cornelis Overbeek ,  Jeffrey Stubbs ,  Matthew Stewart Gebhard

IPC: C09D133/12 ,  C08L33/02 ,  C08L33/12 ,  C09D133/02

CPC classification number: C08F301/00 ,  B05D3/0254 ,  B05D3/06 ,  B05D3/108 ,  C08F8/32 ,  C08F8/42 ,  C08F8/44 ,  C08F22/10 ,  C08F22/38 ,  C08F26/06 ,  C08F26/08 ,  C08F220/06 ,  C08F220/14 ,  C08F220/18 ,  C08F222/04 ,  C08F222/14 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/03 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/50 ,  C08L33/02 ,  C08L33/10 ,  C08L33/12 ,  C08L35/02 ,  C08L51/003 ,  C08L67/08 ,  C08L75/00 ,  C08L75/04 ,  C08L2201/52 ,  C09D125/14 ,  C09D133/02 ,  C09D133/08 ,  C09D133/10 ,  C09D133/12 ,  C09D133/14 ,  C09D135/02 ,  C09D151/003 ,  C09D153/00 ,  C09D167/08 ,  C09D175/04 ,  C09D175/08 ,  Y02P20/582 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: There are described a dispersion of polymeric beads where the beads comprise a copolymer composition comprising (preferably consisting essentially of): copolymers (and processes for making them) comprising (a) at least 8.5 wt-% preferably >=20 wt-% of a higher itaconate diester (preferably dibutyl itaconate—DBI); (b) less than 23 wt-% acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer, (c) optionally with less than 50 wt-% of other itaconate monomers, and (d) optionally less than 77 wt-% of other monomers not (a) to (c). The DBI may be biorenewable. A further embodiment is an aqueous suspension polymerisation process for preparing vinyl polymer beads from olefinically unsaturated monomers and a free-radical initiator, where at least 10 wt-% of the monomer is DBI.

Abstract translation: 描述了聚合物珠粒的分散体，其中珠粒包含共聚物组合物，其包含（优选基本上由以下组成）：共聚物（及其制备方法），其包含（a）至少8.5重量％，优选> = 20重量％ 衣康酸二酯（衣康酸二丁酯-DBI）较高; （b）小于23重量％的酸单体，但也足以使酸值小于150mg KOH / g的聚合物，（c）任选地含有少于50重量％的其它衣康酸酯单体，和（d）任选地 不超过77重量％的其它单体（a）至（c）。 DBI可能是biorenewable。 另一个实施方案是用于由烯属不饱和单体和自由基引发剂制备乙烯基聚合物珠的水悬浮聚合方法，其中至少10重量％的单体是DBI。

公开(公告)号：US20140339336A1

公开(公告)日：2014-11-20

申请号：US14449497

申请日：2014-08-01

Applicant: BASEF SE

Inventor： Joseph Ogonowski

IPC: C09D175/08 ,  B05B1/02 ,  B05B7/16 ,  B05B7/00 ,  B05B7/26

CPC classification number: C09D175/08 ,  B05B1/02 ,  B05B1/042 ,  B05B1/06 ,  B05B7/0031 ,  B05B7/0075 ,  B05B7/1693 ,  B05B7/26 ,  B05C5/02 ,  B29B7/325 ,  B29B7/7404 ,  B29B7/805 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/4883 ,  C08G18/5033 ,  C08G2101/0025 ,  C08G2150/50 ,  C08G2150/60 ,  C08J9/14 ,  C08J2201/022 ,  C08J2375/04

Abstract: A method minimizes emissions while spraying a mixture of a resin composition and a polyisocyanate onto a surface. The resin composition has a hydroxyl content of at least 400 mg KOH/g and includes a blowing agent that is a liquid under pressure, a first polyol, at least one additional polyol other than the first polyol, and optionally a catalyst, surfactant, and water. The mixture is sprayed onto the surface to form a polyurethane foam having a closed cell content of at least 90 percent. The mixture is also sprayed through a spray nozzle at a spray angle corresponding to a control spray angle of from 15 to 125 degrees measured at a pressure of from 10 to 40 psi using water as a standard. The step of spraying produces less than 50 parts of the polyisocyanate per one billion parts of air according to OSHA Method 47.

Abstract translation: 一种将树脂组合物和多异氰酸酯的混合物喷射到表面上的方法使排放最小化。 树脂组合物的羟基含量为至少400mg KOH / g，并且包括作为压力下的液体的发泡剂，第一多元醇，除第一多元醇以外的至少一种另外的多元醇，以及任选的催化剂，表面活性剂和 水。 将混合物喷雾到表面上以形成具有至少90％的闭孔含量的聚氨酯泡沫。 混合物也以喷雾角度喷雾，喷雾角度对应于使用水作为标准在10至40psi压力下测得的15至125度的控制喷雾角。 根据OSHA方法47，喷雾步骤每十亿份空气产生少于50份的多异氰酸酯。