摘要:
The present invention is directed to preparing distillate fuel having almost no oxygen and no carbon-to-carbon double bonds. The method comprises passing biodiesel and/or lipids derived from vegetable oils, algae oils, and/or animal fats over a bio-feedstock, or lipids, conversion catalyst that performs the hydrocarbon isomerization function, removes oxygen from the feedstock, cracks off the C3 backbone, and saturates double bonds. The process is a single step process eliminating the need of a separate costly hydrotreating step while producing a renewable source distillate fuel.
摘要:
A hydrodeoxygenation catalyst comprises a metal catalyst, an acid promoter, and a support. The metal catalyst is selected from platinum, palladium, ruthenium, rhenium rhodium, osmium, iridium, nickel, cobalt, molybdenum, copper, tin, or mixtures thereof. The support is a promoted-zirconium material including texture promoters and acid promoters. The hydrodeoxygenation catalyst may be used for hydrodeoxygenation (HDO) of sugar or sugar alcohol in an aqueous solution. In one embodiment the HDO catalyst may be used for HDO of fatty acids such as fatty acid methyl esters (FAME), triglycerols (in plant oil and animal fat), pyrolysis oil, or lignin. The hydrodeoxygenation catalyst for fatty acid process does not require the use of an acid promoter, it is optional.
摘要:
The invention relates to methods and equipment for converting C3+ olefin to, e.g., one or more of di-C3+ olefin, oligomers and polymers of C3+ olefin, branched C4+-aldehydes, C4+-carboxylic acids, and C4+ oxygenates. The invention encompasses producing methyl tert-butyl ether and diisobutylene, and converting methyl tert-butyl ether to isobutylene.
摘要:
The present invention relates to a process for converting oxygenates to olefins, comprising (1) providing a gas stream comprising one or more ethers; (2) contacting the gas stream provided in (1) with a catalyst, the catalyst comprising a support substrate and a layer applied to the substrate, the layer comprising one or more zeolites of the MFI, MEL and/or MWW structure type.
摘要:
The present invention produces Cyclic Compound (1) in which organic ring groups including cyclohexane rings and benzene rings are continuously bonded, using a compound having at least one cyclohexane ring and benzene rings with halogen atoms at the two terminuses, in the presence of a nickel compound (bis(1,5-cyclooctadiene)nickel, etc.). Thereafter, by converting the cyclohexane rings in Cyclic Compound (1) into benzene rings, a desired carbon nanoring can be obtained. Thereby, the present invention efficiently produces a carbon nanoring made of a compound having a cyclic structure in which a desired number of organic ring groups are continuously bonded, with a short production process.
摘要:
The present invention provides a method for start-up of an Oxygenate-to-Olefins process, which process comprises the steps: a) providing an oxygenate-comprising feedstock to an Oxygenate-to-Olefins reaction zone and contacting the feedstock with a zeolite-comprising catalyst at a temperature in the range of from 450 to 700° C. ° C., to obtain an reaction product containing olefins; b) separating the reaction product obtained in step a) in at least a product fraction containing ethylene and/or propylene and a product fraction containing C4+ olefins; c) recycling at least part of the C4+ olefins in the product fraction containing C4+ olefins to the Oxygenate-to-Olefins reaction zone in step (a), characterised in that upon start-up the oxygenate-comprising feedstock initially comprises a first amount of externally supplied tert-alkyl ether and subsequently the amount of externally supplied tert-alkyl ether in the oxygenate-comprising feedstock is reduced.
摘要:
The present invention provides a process preparing ethylene and propylene, comprising the step of: a) contacting a feed comprising a tert alkyl ether obtained from an etherification reaction between ethanol and a tertiary iso-olefin with a zeolite-comprising catalyst at a temperature in the range of from 350 to 1000° C. to obtain a olefinic product comprising ethylene and propylene.
摘要:
The present invention provides a process for preparing ethylene and/or propylene, comprising the steps of: a) providing an oxygenate-comprising feedstock; b) contacting the oxygenate-comprising feedstock with a molecular sieve-comprising catalyst at a temperature in the range of from 450 to 700° C. and converting at least part of the oxygenate into an olefinic product comprising ethylene and/or propylene; and c) retrieving the olefinic product, wherein the oxygenate-comprising feedstock comprises in the range of from 1 to 97 wt % of at least one tert-alkyl ether selected from the group MTBE, ETBE, TAME and TAEE, based on the weight of the oxygenates in the oxygenate-comprising feedstock, and further comprises methanol and/or DME.
摘要:
The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).