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    Detergent Additive-Containing Mineral Oils Having Improved Cold Flow Properties
    81.
    发明申请
    Detergent Additive-Containing Mineral Oils Having Improved Cold Flow Properties 审中-公开
    具有改善冷流特性的含洗涤剂添加剂的矿物油

    公开(公告)号：US20100180492A1

    公开(公告)日：2010-07-22

    申请号：US12665005

    申请日：2008-06-17

    申请人： Matthias Krull ,  Robert Janssen

    发明人： Matthias Krull ,  Robert Janssen

    IPC分类号： C10L10/14

    CPC分类号： C10L1/146 ,  C10L1/1641 ,  C10L1/1966 ,  C10L1/1981 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

    摘要： The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from comb polymers that carry alkyl side chains having on average a length of at least 18 C atoms per mole for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.

    摘要翻译： 本发明涉及至少一种作为石蜡结晶成核剂的油溶性化合物B）的用途，其选自带有烷基侧链的梳形聚合物，其平均具有至少18C原子/摩尔的长度 用于改善含有至少一种无灰，含氮洗涤剂添加剂A）的中间馏分中与B）不同的矿物油C）的冷流改进剂的反应，该添加剂A）至少包含油溶性两亲化合物 一个与极性基团结合的烷基或烯基，所述烷基或链烯基具有10-500个C原子，极性基团具有2个或更多个氮原子。

    Fuel oils composed of middle distillates and oils of vegetable or animal origin and having improved cold flow properties
    83.
    发明申请
    Fuel oils composed of middle distillates and oils of vegetable or animal origin and having improved cold flow properties 审中-公开

    公开(公告)号：US20050126071A1

    公开(公告)日：2005-06-16

    申请号：US11009870

    申请日：2004-12-10

    申请人： Matthias Krull ,  Bettina Siggelkow ,  Martina Hess

    发明人： Matthias Krull ,  Bettina Siggelkow ,  Martina Hess

    IPC分类号： C10L1/192 ,  C10L1/02 ,  C10L1/04 ,  C10L1/14 ,  C10L1/18 ,  C10L1/195 ,  C10L1/196 ,  C10L1/197 ,  C10L1/22 ,  C10L1/224 ,  C10L10/14 ,  C10L5/00

    CPC分类号： C10L1/1955 ,  C10L1/143 ,  C10L1/146 ,  C10L1/19 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/221 ,  C10L1/224

    摘要： The invention provides a fuel oil composition F) comprising F1) 89-50% by volume of a fuel oil of mineral origin and F2) 11-50% by volume of a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units composed of B1) at least one olefin as monomer 1 which bears at least one C8-C18-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16-alkyl radical bonded via an ester moiety, where the sum Q Q = ∑ i ⁢ w 1 ⁢ i · n 1 ⁢   ⁢ i + ∑ j ⁢ w 2 ⁢   ⁢ j · n 2 ⁢   ⁢ j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the ester groups of monomer 2 on the other is from 21.0 to 28.0, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the ester groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radicals of the ester groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals in the ester groups of monomer 2.

    Copolymers, and their use as additives for improving the cold-flow properties of middle distillates
    86.
    发明授权
    Copolymers, and their use as additives for improving the cold-flow properties of middle distillates 有权
    共聚物及其作为添加剂的用途，用于改善中间馏分的冷流特性

    公开(公告)号：US06458174B1

    公开(公告)日：2002-10-01

    申请号：US09487066

    申请日：2000-01-19

    申请人： Matthias Krull ,  Waltraud Nagel

    发明人： Matthias Krull ,  Waltraud Nagel

    IPC分类号： C10L118

    CPC分类号： C10L1/146 ,  C08F222/14 ,  C08F255/00 ,  C08F255/10 ,  C08L51/003 ,  C08L51/06 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1985 ,  C08L2666/02

    摘要： Copolymers containing A) from 45 to 54 mol % of divalent structural units of the formula 1 in which a and b=0 or 1 and a+b=1, B) from 35 to 53 mol % of divalent structural units of the formula 2 —H2C—CHR2—  (2) and C) from 1 to 25 mol % of divalent structural units derived from polyolefins, where the polyolefins can be derived from monoolefins having 3 to 5 carbon atoms, wherein a) R1 is an alkyl or alkenyl radical having 10 to 40 carbon atoms or an alkoxyalkyl radical having 1 to 100 alkoxy units and 1 to 30 carbon atoms in the alkyl radical, and b) R2 is an alkyl radical having 10 to 50 carbon atoms, c) the alkylvinylidene content of the polyolefins on which the structural units C) are based is at least 50 mol %, and d) the number of carbon atoms in the polyolefin molecules on which the structural units C) are based is from 35 to 350.

    摘要翻译： 包含A）45至54摩尔％的式1in的二价结构单元，其中a和b = 0或1和a + b = 1，B）35至53摩尔％的式2和C的二价结构单元）来自 1至25mol％衍生自聚烯烃的二价结构单元，其中聚烯烃可以衍生自具有3至5个碳原子的单烯烃，其中a）R 1是具有10至40个碳原子的烷基或烯基或具有1至 烷基中的100个烷氧基单元和1至30个碳原子，和b）R 2是具有10至50个碳原子的烷基，c）结构单元C）所基于的聚烯烃的烷基亚乙烯基含量为至少50摩尔 ％，andd）结构单元C）所基于的聚烯烃分子中的碳原子数为35〜350。

    Detergent additive-containing mineral oils having improved cold flow properties
    90.
    发明授权
    Detergent additive-containing mineral oils having improved cold flow properties 有权
    具有改善的冷流特性的含有洗涤剂添加剂的矿物油

    公开(公告)号：US08734542B2

    公开(公告)日：2014-05-27

    申请号：US12664997

    申请日：2008-06-17

    申请人： Matthias Krull ,  Robert Janssen

    发明人： Matthias Krull ,  Robert Janssen

    IPC分类号： C10L1/18

    CPC分类号： C10L1/146 ,  C10L1/1641 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2383

    摘要： The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from ethylene copolymers and 2 to 10.5 mole % of at least one ethylenically unsaturated carbonic ester for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.

    摘要翻译： 本发明涉及至少一种用作石蜡结晶的成核剂的油溶性化合物B），其选自乙烯共聚物和2至10.5摩尔％的至少一种烯键式不饱和碳酸酯，用于改善反应 在含有至少一种无灰，含氮洗涤剂添加剂A）的中间馏分中的与B）不同的矿物油C）的冷流改进剂，其是包含至少一个烷基或烯基的油溶性两亲化合物 基团与极性基团结合，所述烷基或烯基具有10至500个C原子，极性基团具有2个或更多个氮原子。