Silicophosphate compounds and method of making same
    84.
    发明授权
    Silicophosphate compounds and method of making same 失效
    硅磷酸盐化合物及其制备方法

    公开(公告)号:US5922297A

    公开(公告)日:1999-07-13

    申请号:US953447

    申请日:1997-10-17

    申请人: Gregory A. Merkel

    发明人: Gregory A. Merkel

    摘要: A compound having the general formula AM.sub.1+y.sup.3+ M.sub.2-2y.sup.4+ M.sub.y.sup.5+ Si.sub.2 P.sub.6 O.sub.25, wherein A can be K, Rb, or Cs, M.sup.3+ can be Al, Ga, Cr, Fe, Sc, In, Y, lanthanide series elements, or combinations of these, M.sup.4+ can be Si, Ge, Ti, Ir, Ru, Sn, Hf, Zr, or combinations of these, M.sup.5+ can be V, Nb, Ta, or combinations of these, 0.ltoreq.y.ltoreq.1, the mean ionic radius of the M.sup.3+ cations and the mean ionic radius of the M.sup.5+ cations are each about 0.4 to 1.00 .ANG. when coordinated by six oxygen anions, and the mean ionic radii of the M.sup.4+ cations and the M.sup.5+ cations are each no greater than about 0.53+(0.30.times.the mean ionic radius of the M.sup.3+ cations). The compound can be made by a dry powder method that involves providing a homogeneous powder mixture of raw materials to form the compound, shaping the mixture into a preform, and firing the preform at a sufficient temperature and for a sufficient time to form the product compound. The compound can be made by a sol gel method that involves providing the raw materials in solution form, drying the solution to obtain a sol gel powder, calcining, pulverizing, and shaping the sol gel powder, followed by firing.

    摘要翻译: 具有通式AM1 + y3 + M2-2y4 + My5 + Si2P6O25的化合物,其中A可以是K,Rb或Cs,M3 +可以是Al,Ga,Cr,Fe,Sc,In,Y,镧系元素, 或这些的组合,M4 +可以是Si,Ge,Ti,Ir,Ru,Sn,Hf,Zr或它们的组合,M5 +可以是V,Nb,Ta或这些的组合,0 < = 1,当由六个氧阴离子配位时,M3 +阳离子的平均离子半径和M5 +阳离子的平均离子半径分别为约0.4至1.00安培,M4 +阳离子和M5 +阳离子的平均离子半径各为 大于约0.53+(0.30 + M3 +阳离子的平均离子半径)。 化合物可以通过干粉法制备,其包括提供原料的均匀粉末混合物以形成化合物,将混合物成型为预成型体,并在足够的温度下烧制预制件并足够的时间以形成产物化合物 。 该化合物可以通过溶胶凝胶法制备,其包括以溶液形式提供原料,干燥溶液以获得溶胶凝胶粉末,煅烧,粉碎和成型溶胶凝胶粉末,随后进行烧制。

    Fiber reinforced ceramic matrix composite internal combustion engine
exhaust manifold
    85.
    发明授权
    Fiber reinforced ceramic matrix composite internal combustion engine exhaust manifold 失效
    纤维增强陶瓷基体复合内燃机排气歧管

    公开(公告)号:US5888641A

    公开(公告)日:1999-03-30

    申请号:US783856

    申请日:1997-01-16

    摘要: This invention discloses an exhaust manifold for an engine made of all fiber reinforced ceramic matrix composite material so as to be light weight and high temperature resistant. A method of making the exhaust manifold comprises the steps of forming a liner of a cast monolithic ceramic material containing pores, filling the pores of the cast monolithic ceramic material with a pre-ceramic polymer resin, coating reinforcing fibers with an interface material to prevent a pre-ceramic polymer resin from adhering strongly to the reinforcing fibers, forming a mixture of a pre-ceramic polymer resin and reinforcing fibers coated with the interface material, forming an exhaust manifold shaped structure from the mixture of the pre-ceramic polymer resin and the reinforcing fibers coated with the interface material by placing the mixture on at least a portion of the cast monolithic ceramic material, and firing the exhaust component shaped structure at a temperature and a time sufficient to convert the pre-ceramic polymer resin to a ceramic thereby forming a reinforced ceramic composite.

    摘要翻译: 本发明公开了一种由全部纤维增强陶瓷基复合材料制成的发动机排气歧管,重量轻且耐高温。 制造排气歧管的方法包括以下步骤:形成包含孔的铸造整体陶瓷材料的衬垫,用预陶瓷聚合物树脂填充铸造单块陶瓷材料的孔,用界面材料涂覆增强纤维以防止 预陶瓷聚合物树脂强烈地粘附到增强纤维上,形成预陶瓷聚合物树脂和涂覆有界面材料的增强纤维的混合物,从预陶瓷聚合物树脂和 通过将混合物放置在至少一部分铸塑单片陶瓷材料上,并且在足以将预陶瓷聚合物树脂转化成陶瓷的温度和时间下焙烧排气组分成形结构,从而形成涂覆有界面材料的增强纤维,从而形成 增强陶瓷复合材料。