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公开(公告)号：US09493381B2
公开(公告)日：2016-11-15
申请号：US14123235
申请日：2012-05-31
IPC分类号： C07C1/04 , C10G2/00 , B01J27/224 , B01J21/06 , B01J27/22 , B01J37/02 , B01J23/745 , B01J23/75 , B01J23/78 , B01J23/83 , B01J23/89 , B01J35/00 , B01J35/10 , B01J37/00
CPC分类号： C07C1/044 , B01J21/06 , B01J23/745 , B01J23/75 , B01J23/78 , B01J23/83 , B01J23/8906 , B01J23/8913 , B01J27/22 , B01J27/224 , B01J35/002 , B01J35/1009 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/0201 , C07C1/0435 , C10G2/332 , C10G2300/1022 , C10G2300/703
摘要： Catalytic process for the partial conversion of a gaseous mixture containing carbon monoxide and hydrogen into a mixture of hydrocarbons, including bringing the said gaseous mixture into contact with a solid catalyst, the solid catalyst having a porous support with a composite material including SiC and a titanium carbide and/or a titanium oxide, and an active phase. The support is prepared in the form of grains, beads, or extrudates, or in the form of cylinders or sheets of cellular foam.
摘要翻译： 用于将含有一氧化碳和氢气的气态混合物部分转化成烃混合物的催化方法，包括使所述气态混合物与固体催化剂接触，所述固体催化剂具有多孔载体，所述复合材料包括SiC和钛 碳化物和/或氧化钛，以及活性相。 载体以颗粒，珠粒或挤出物的形式制备，或以圆泡或细胞泡沫片的形式制备。
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2.发明授权Photocatalysts based on structured three-dimensional carbide, in particular β-SiC, foams 有权基于结构化三维碳化物，特别是β-SiC，泡沫的光催化剂公开(公告)号：US08628726B2
公开(公告)日：2014-01-14
申请号：US13063729
申请日：2009-09-14
申请人： Cuong Pham-Huu , Nicolas Keller , Marc-Jacques Ledoux , Valérie Keller-Spitzer , Dominique Begin , Mathieu Grandcolas , Izabela Janowska , Shabnam Hajesmaili
发明人： Cuong Pham-Huu , Nicolas Keller , Marc-Jacques Ledoux , Valérie Keller-Spitzer , Dominique Begin , Mathieu Grandcolas , Izabela Janowska , Shabnam Hajesmaili
IPC分类号： B01J19/08
CPC分类号： B01J19/08 , B01J21/063 , B01J23/30 , B01J23/42 , B01J27/224 , B01J35/004 , B01J35/04 , B01J35/06 , B01J37/0215 , B01J37/0217 , B01J37/0219 , B01J37/0244 , B01J37/084 , C02F1/32 , C02F1/725 , C02F2305/10
摘要： The invention relates to a photocatalyst comprising a β-SiC cellular foam and a photocatalytically active phase, deposited directly on said cellular foam or on an intermediate phase deposited on said cellular foam. The average size of the cells is between 2500 μm and 5000 μm. The foam can comprise nanotubes or nanofibers (particularly of carbon, SiC, and TiO2) that consist of, or carry as an intermediate phase, a photocatalytically active phase.
摘要翻译： 本发明涉及包含β-SiC细胞泡沫和光催化活性相的光催化剂，其直接沉积在所述泡沫泡沫上或沉积在所述泡孔泡沫上的中间相上。 细胞的平均尺寸在2500mum和5000mum之间。 泡沫可以包含由光催化活性相组成或作为中间相携带光催化活性相的纳米管或纳米纤维（特别是碳，SiC和TiO 2）。
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3.发明授权Process for the conversion of a synthesis gas to hydrocarbons in the presence of beta-SiC and effluent from this process 有权在β-SiC存在下将合成气转化为烃的方法和该方法的流出物公开(公告)号：US07393877B2
公开(公告)日：2008-07-01
申请号：US11411085
申请日：2006-04-26
IPC分类号： C07C27/00
CPC分类号： C10G2/332 , B01J23/75 , B01J23/882 , B01J27/224 , B01J35/026 , B01J35/04 , C07C1/0435 , C07C2523/28 , C07C2523/75 , C07C2527/224 , C10G2/33
摘要： In a process for the conversion of carbon monoxide to C2+ hydrocarbons in the presence of hydrogen and of a catalyst comprising a metal and a support comprising silicon carbide, the support comprises more than 50% by weight of silicon carbide in the beta form. A process for the conversion of carbon monoxide to C2+ hydrocarbons in the presence of hydrogen and of a catalyst the effluent thus obtained are also disclosed.
摘要翻译： 在氢气和包含金属和包含碳化硅的载体的催化剂存在下将一氧化碳转化为C 2 H 2 O + CO 2的方法中，载体包含 超过50重量％的β型碳化硅。 还公开了一种在氢气和催化剂存在下将一氧化碳转化为C 2 H 2 CO 2烃的方法。
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公开(公告)号：US07179764B2
公开(公告)日：2007-02-20
申请号：US10345417
申请日：2003-01-16
IPC分类号： B01J29/04
CPC分类号： B01J29/06 , B01J27/224 , B01J29/40 , B01J29/7007 , B01J35/10 , B01J37/0246 , B01J2229/42 , B01J2229/64
摘要： The invention relates to a composite formed of a zeolite (such as ZSM-5 zeolite, β-zeolite and silicalite) deposited on a rigid support, wherein the rigid support comprises silicon carbide (SiC) with a specific surface area BET of at least 5 m2/g. Preferably, the support is a β-SiC foam with a specific area of between 10 and 500 m2/g. This composite may be used as a catalyst and/or a catalyst support for chemical reactions in a gas or liquid medium. For example materials of the present invention are useful for example, in connection with cracking, acylation, alkylation and/or isomerization of hydrocarbons.
摘要翻译： 本发明涉及沉积在刚性载体上的沸石（例如ZSM-5沸石，β-沸石和硅沸石）形成的复合材料，其中刚性载体包括比表面积BET至少为5的碳化硅（SiC） m 2 / g。 优选地，载体是比表面积为10-500m 2 / g的β-SiC泡沫。 该复合材料可用作气体或液体介质中的化学反应的催化剂和/或催化剂载体。 例如，本发明的材料可用于例如烃的裂解，酰化，烷基化和/或异构化。
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公开(公告)号：US07101494B2
公开(公告)日：2006-09-05
申请号：US10481106
申请日：2002-06-18
申请人： Cuong Pham-Huu , Marc-Jacques Ledoux , Pascaline Leroi , Sabine Savin-Poncet , Jacques Bousquet
发明人： Cuong Pham-Huu , Marc-Jacques Ledoux , Pascaline Leroi , Sabine Savin-Poncet , Jacques Bousquet
IPC分类号： C01B3/38
CPC分类号： B01J23/755 , B01J27/224 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/1011 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , Y02P20/52
摘要： The invention relates to a method for obtaining synthesis gas by partial catalytic oxidation, consisting in bringing a hydrocarbon in a gaseous state into contact with an oxidizing gas, and therefore possibly a small amount of water vapor, in the presence of a catalyst comprising at least one silicon carbide at a temperature of more than 800° C. According to the invention, the silicon carbide has a specific surface which is determined by the BET method and which is less than or equal to 100 m2/g, the contact time between the mixture of gaseous hydrocarbon, oxidizing gas and silicon carbide being more than 0.05 seconds and the pressure inside the reactor being greater than atmospheric pressure.
摘要翻译： 本发明涉及一种通过部分催化氧化获得合成气的方法，该方法包括使气态烃与氧化气体接触，因此可能含有少量的水蒸汽，所述催化剂至少包含至少 一个碳化硅在大于800℃的温度下。根据本发明，碳化硅具有通过BET法测定的比表面积小于或等于100微米/ 气体烃，氧化气体和碳化硅的混合物之间的接触时间大于0.05秒，反应器内的压力大于大气压。
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6.发明授权Preparation of a catalyst from metal oxides by reduction and partial carburization by reaction gases 失效通过反应气体还原和部分渗碳从金属氧化物制备催化剂
公开(公告)号：US5468370A
公开(公告)日：1995-11-21
申请号：US162293
申请日：1993-12-07
CPC分类号： B01J37/024 , B01J23/28 , B01J27/22 , B01J37/18 , C10G35/06
摘要： A catalyst for chemical and petrochemical reactions and a process for its production. The catalyst comprises an oxide of one of the transition metals, rare earth elements, or actinide elements, e.g., molybdenum, having on its surface carbides and oxycarbides, the core being the metal or the metal oxide. In the process for catalyst production, the reaction gas mixture containing carbon products is passed onto the oxide, leading to a progressive carburization of the surface of the oxide and to a progressive increase in the efficiency of the catalyst.
摘要翻译： 化学和石油化学反应的催化剂及其生产工艺。 催化剂包括过渡金属，稀土元素或锕系元素之一的氧化物，例如钼，其表面上具有碳化物和碳氧化物，核是金属或金属氧化物。 在催化剂生产过程中，含有碳产物的反应气体混合物通过氧化物，导致氧化物表面逐渐渗碳，催化剂效率逐渐增加。
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公开(公告)号：US5308597A
公开(公告)日：1994-05-03
申请号：US613627
申请日：1990-11-27
IPC分类号： B01D53/86 , B01D53/94 , B01J27/22 , C01B31/00 , C01B31/30 , C01B31/34 , C07B61/00 , C07C5/27 , C07C5/31 , C07C5/367 , C07C5/387 , C07C9/14 , C07C9/16 , C07C15/04 , C10G11/02 , C10G35/06
CPC分类号： B01D53/945 , B01J27/22 , C01B31/30 , C01B31/301 , C01B31/303 , C01B31/34 , C01P2004/50 , C01P2004/80 , C01P2006/12 , C01P2006/80 , Y02T10/22
摘要： A method of producing heavy metal carbides of high specific surface area characterized in that a compound in the gazeous state of said heavy metal is caused to react with reactive carbon having a specific surface area at least equal to 200 m.sup.2. g.sup.-1 at a temperature comprised between 900.degree. and 1400.degree. C., and thus obtained carbides.
摘要翻译： PCT No.PCT / FR90 / 00204 Sec。 371日期1990年11月27日第 102（e）日期1990年11月27日PCT 1990年3月26日PCT公布。 WO90 / 11251 PCT出版物 日本1990年10月4日。一种制造高比表面积的重金属碳化物的方法，其特征在于使所述重金属的眩晕状态的化合物与比表面积至少等于200m 2的反应性碳反应 。 g-1，在900〜1400℃的温度下，由此得到碳化物。
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8.发明授权
公开(公告)号：US5139987A
公开(公告)日：1992-08-18
申请号：US754927
申请日：1991-09-04
摘要： Process for activating carbides of heavy metals with a large specific surface with a view to their use as a catalyst for chemical or petrochemical reactions consisting of treating the said carbides by managed oxidation under an oxidizing gas stream at a temperature between 250.degree. and 450.degree. C., maintaining the temperature for at least 3 hours and then cooling to ambient temperature, still under said oxidizing stream.
摘要翻译： 为了激活具有大比表面积的重金属碳化物的方法，考虑到它们用作化学或石油化学反应的催化剂的用途，其包括在氧化气流下在250-450℃的温度下通过管理氧化处理所述碳化物 ，保持温度至少3小时，然后冷却至环境温度，仍然在所述氧化流下。
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公开(公告)号：US09309122B2
公开(公告)日：2016-04-12
申请号：US13505815
申请日：2010-11-03
申请人： Izabela Janowska , Dominique Begin , Kambiz Chizari , Ovidiu Ersen , Pierre Bernhardt , Thierry Romero , Marc Ledoux , Cuong Pham-Huu
发明人： Izabela Janowska , Dominique Begin , Kambiz Chizari , Ovidiu Ersen , Pierre Bernhardt , Thierry Romero , Marc Ledoux , Cuong Pham-Huu
CPC分类号： C01B31/0206 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/19 , C01B2204/04 , C01B2204/22 , C01B2204/28 , C01B2204/32
摘要： The preparation of graphene, mono-, bi- and multi-layers from graphite-based precursor materials, for example, pencil lead or graphite, by a method of mechanical thinning on the surface of a planar substrate with controlled roughness, followed by sonication in order to collect the graphene deposited on the substrate in a liquid medium. The bearing force during thinning by mechanical friction enables the number of graphene sheets deposited on the surface of the substrate to be controlled.
摘要翻译： 通过在具有受控粗糙度的平面基板的表面上通过机械稀化的方法从石墨基前体材料（例如铅笔铅或石墨）制备石墨烯，单层，双层和多层，然后超声处理 以在液体介质中收集沉积在基底上的石墨烯。 通过机械摩擦减薄的轴承力使得能够控制沉积在基板表面上的石墨烯片的数量。
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10.发明授权Dehydration of methanol to dimethyl ether using catalysts based on a zeolite supported on silicon carbide 有权使用基于负载在碳化硅上的沸石的催化剂将甲醇脱水成二甲醚公开(公告)号：US09073837B2
公开(公告)日：2015-07-07
申请号：US12518196
申请日：2007-12-07
申请人： Svetlana Ivanova , Estelle Vanhaecke , Suzanne Libs , Benoit Louis , Cuong Pham-Huu , Marc Jacques Marie Ledoux
发明人： Svetlana Ivanova , Estelle Vanhaecke , Suzanne Libs , Benoit Louis , Cuong Pham-Huu , Marc Jacques Marie Ledoux
IPC分类号： C07C41/09
CPC分类号： C07C41/09 , C07C43/043
摘要： A process for the preparation of dimethyl ether by catalytic dehydration of methanol, in which there is used a catalyst based on a zeolite immobilized on a silicon carbide support, for example a zeolite of type ZSM-5 supported on silicon carbide extrudates or on a silicon carbide cellular foam.
摘要翻译： 通过甲醇的催化脱水制备二甲醚的方法，其中使用基于固定在碳化硅载体上的沸石的催化剂，例如支持在碳化硅挤出物上或硅上的ZSM-5型沸石 硬质合金细胞泡沫。
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