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    PROCESS FOR THE ENZYMATIC SYNTHESIS OF TRIGLYCERIDES
    3.
    发明申请
    PROCESS FOR THE ENZYMATIC SYNTHESIS OF TRIGLYCERIDES 审中-公开
    合成酶的合成方法

    公开(公告)号：US20070148746A1

    公开(公告)日：2007-06-28

    申请号：US11565696

    申请日：2006-12-01

    申请人： ULRICH SCHOERKEN ,  Carolin Meyer ,  Peter Horlacher ,  Sabine Both

    发明人： ULRICH SCHOERKEN ,  Carolin Meyer ,  Peter Horlacher ,  Sabine Both

    IPC分类号： C12P7/64 ,  C07C57/02

    CPC分类号： C12P7/6472 ,  C12P7/6454

    摘要： The invention relates to a process for the enzymatic synthesis of esters of polyunsaturated, short-chain or sensitive fatty acids with a high triglyceride content, which is made up of an enzymatic synthesis of the mixture of triglycerides and partial glycerides starting from free fatty acid, methyl or ethyl esters and glycerol, a subsequent selective enzymatic back-hydrolysis of the partial glycerides to fatty acid and glycerol and distillation-based separation of the triglycerides, and to the triglyceride-rich ester mixtures obtainable by this process. The process is preferably carried out as a one-pot process in the same reactor and in the presence of the same enzyme.

    摘要翻译： 本发明涉及一种用于酶促合成具有高甘油三酯含量的多不饱和，短链或敏感脂肪酸酯的方法，其由甘油三酯和偏甘油酯从游离脂肪酸开始的混合物的酶合成， 甲基或乙酯和甘油，随后将部分甘油酯选择性酶促回水解成脂肪酸和甘油，并且基于蒸馏的甘油三酸酯分离，以及通过该方法可获得的富含甘油三酯的酯混合物。 该方法优选在同一反应器中和在相同酶存在下作为一锅法进行。

    Production and Use of Monoglycerides
    4.
    发明申请
    Production and Use of Monoglycerides 有权
    单酸甘油酯的生产和使用

    公开(公告)号：US20080045606A1

    公开(公告)日：2008-02-21

    申请号：US11813939

    申请日：2006-01-10

    申请人： Ulrich Schoerken ,  Sabine Both ,  Frank Bongardt ,  Diana Stuhlmann

    发明人： Ulrich Schoerken ,  Sabine Both ,  Frank Bongardt ,  Diana Stuhlmann

    IPC分类号： A61K47/12 ,  A61P43/00 ,  A61Q99/00 ,  C12P7/64

    CPC分类号： C10L1/191 ,  A61K47/44 ,  C10L10/08 ,  C10M129/76 ,  C10M2207/289 ,  C12P7/6445 ,  C12P7/6472 ,  C12P7/649 ,  Y02E50/13

    摘要： A higher-yielding process for the production of monoglycerides in which triglycerides are enzymatically reacted with a catalytic amount of an esterase, preferably lipase, that has been activated by the addition of alkaline salts, in the presence of linear or branched alcohols containing 1 to 8 carbon atoms, then the esterase may be deactivated and it and the remaining alcohol removed, with the monoglycerides thus produced useful in lubricants, fuel additives, and emulsifying constituents in foods, and cosmetic and/or pharmaceutical formulations.

    摘要翻译： 用于生产甘油三酸酯的较高产量的方法，其中甘油三酸酯在催化量的酯酶（优选脂肪酶）中酶催化，其通过加入碱性盐在含有1至8个的直链或支链醇的存在下活化 碳原子，那么酯酶可以失活，并且其和除去的剩余的醇与由此产生的单酸甘油酯可用于食品中的润滑剂，燃料添加剂和乳化成分，以及化妆品和/或药物制剂。

    Method for producing conjugated linoleic acid
    6.
    发明申请
    Method for producing conjugated linoleic acid 失效
    共轭亚油酸的制备方法

    公开(公告)号：US20050255570A1

    公开(公告)日：2005-11-17

    申请号：US10516987

    申请日：2003-05-28

    申请人： Lars Zander ,  Stefan Busch ,  Carolin Meyer ,  Sabine Both ,  Ulrich Schoerken

    发明人： Lars Zander ,  Stefan Busch ,  Carolin Meyer ,  Sabine Both ,  Ulrich Schoerken

    IPC分类号： C12P7/64 ,  C12R1/05

    CPC分类号： C12P7/6427

    摘要： Processes for preparing conjugated linoleic acid are described wherein a conjugated linoleic acid lower alkyl ester is subjected to hydrolysis in the presence of an enzyme to form a hydrolyzate comprising a conjugated linoleic acid and a lower alkanol, wherein at least a portion of the lower alkanol is continuously removed; the hydrolyzate is separated into an organic phase and an aqueous/alcoholic phase; and the conjugated linoleic acid is separated from the organic phase.

    摘要翻译： 描述制备共轭亚油酸的方法，其中共轭亚油酸低级烷基酯在酶存在下进行水解以形成包含共轭亚油酸和低级链烷醇的水解产物，其中至少一部分低级烷醇为 连续删除 将水解产物分离成有机相和水相/醇相; 共轭亚油酸与有机相分离。

    MIXTURE CONTAINING FATTY ACID GLYCERIDES
    7.
    发明申请
    MIXTURE CONTAINING FATTY ACID GLYCERIDES 审中-公开
    含有脂肪酸甘油的混合物

    公开(公告)号：US20080248187A1

    公开(公告)日：2008-10-09

    申请号：US12061276

    申请日：2008-04-02

    申请人： Ulrich Schoerken ,  Peter Kempers ,  Andreas Sander ,  Peter Horlacher

    发明人： Ulrich Schoerken ,  Peter Kempers ,  Andreas Sander ,  Peter Horlacher

    IPC分类号： A23L1/29 ,  C12P7/64 ,  C07C55/00

    CPC分类号： C12P7/6454 ,  A23D9/013 ,  A23D9/02 ,  A23K20/158 ,  A23K50/80 ,  A23L33/12 ,  A23V2002/00 ,  C11C3/003 ,  C11C3/10 ,  A23V2200/30 ,  A23V2250/182 ,  A23V2250/1942 ,  A23V2250/192

    摘要： A mixture containing fatty acid glycerides which has a high percentage content of PUFA acyl groups and a low percentage content of saturated fatty acid acyl groups is described. A process which enables the PUFA acyl groups in a mixture containing fatty acid glycerides (for example a fish oil) to be enriched and, at the same time, the content of saturated fatty acid acyl groups to be maintained at a low content is described. The process is a hydrolytic process or an alcoholysis in which the fatty acid acyl groups to be enriched are hydrolytically or alcoholytically released from the fatty acid glycerides slowly, if at all, the process being carried out in the presence of a lipase.

    摘要翻译： 描述了包含脂肪酸甘油酯的混合物，其具有高百分比含量的PUFA酰基和低百分含量的饱和脂肪酸酰基。 描述了使包含脂肪酸甘油酯（例如鱼油）的混合物中的PUFA酰基富集并且同时使饱和脂肪酸酰基含量维持在低含量的方法。 该方法是水解方法或醇解，其中待富集的脂肪酸酰基缓慢地从脂肪酸甘油酯水解或醇解地释放，如果完全是在脂肪酶存在下进行的。

    STRUCTURED LIPID MIXTURES
    8.
    发明申请
    STRUCTURED LIPID MIXTURES 有权
    结构脂肪混合物

    公开(公告)号：US20070111292A1

    公开(公告)日：2007-05-17

    申请号：US11554799

    申请日：2006-10-31

    申请人： Ulrich Schoerken ,  Doris Bell ,  Peter Horlacher ,  Diana Stuhlmann ,  Carolin Meyer

    发明人： Ulrich Schoerken ,  Doris Bell ,  Peter Horlacher ,  Diana Stuhlmann ,  Carolin Meyer

    IPC分类号： A61K31/22 ,  C12P7/64

    CPC分类号： C11C3/10 ,  A21D2/165 ,  A23D9/00 ,  A23K20/158 ,  A23L33/115 ,  A23L33/12

    摘要： The invention relates to structured lipid mixtures corresponding to formula (I): characterized in that R1CO, R2CO and R3CO independently of one another represent (i) linear saturated acyl groups containing 6 to 12 carbon atoms or (ii) the acyl group of conjugated linoleic acid (CLA) and/or an omega-3 or omega-6 fatty acid (OF), with the proviso that the quantity of CLA acyl groups amounts to 3 to 50 mol-% and the quantity of OF acyl groups to 5 to 25 mol-%, based on the quantity of acyl groups. The mixtures are preferably made by subjecting a mixture of component (a) a medium-chain triglyceride; and component (b) a CLA, an (OF), a TG-CLA (TG-OF) or a mixture thereof to enzymatic transesterification in the presence of a vegetable, marine or microbial oil.

    摘要翻译： 本发明涉及对应于式（I）的结构化脂质混合物：其特征在于R 1 CO，R 2 CO和R 3 CO独立地 彼此表示（i）含有6至12个碳原子的直链饱和酰基或（ii）共轭亚油酸（CLA）和/或ω-3或ω-6脂肪酸（OF）的酰基，其中 条件是基于酰基的量，CLA酰基的量为3至50摩尔％，酰基的量为5至25摩尔％。 混合物优选通过将组分（a），中链甘油三酯的混合物， 和（b）CLA，（OF），TG-CLA（TG-OF）或其混合物在植物，海洋或微生物油的存在下进行酶促酯交换反应。

    Processes for the production of triglycerides of unsaturated fatty acids in the presence of enzymes
    10.
    发明申请
    Processes for the production of triglycerides of unsaturated fatty acids in the presence of enzymes 审中-公开
    在酶存在下生产不饱和脂肪酸甘油三酸酯的方法

    公开(公告)号：US20050233427A1

    公开(公告)日：2005-10-20

    申请号：US11093534

    申请日：2005-03-30

    申请人： Ulrich Schoerken ,  Carolin Meyer ,  Sabine Both ,  Peter Horlacher

    发明人： Ulrich Schoerken ,  Carolin Meyer ,  Sabine Both ,  Peter Horlacher

    IPC分类号： C11C1/04 ,  C11C3/06 ,  C11C3/10 ,  C12P7/64

    CPC分类号： C12P7/6472 ,  C11C3/06

    摘要： Processes for the enzyme-catalyzed synthesis of triglycerides containing polyunsaturated fatty acids in which the synthesis is preceded by a pre-hydrolysis in which (a) C1-4 alkyl esters of polyunsaturated fatty acids are completely or partly hydrolyzed in vacuo with continuous addition of water or are partly hydrolyzed in several stages without vacuum, (b) after the hydrolysis, the water is removed by separation or distillation and (c) the synthesis of the polyunsaturated fatty acids with glycerol in vacuo in the presence of an enzyme to form their triglycerides is carried out under low-water conditions, (d) the enzymes are removed from the triglyceride by separation or filtration and (e) the remaining fatty acids and/or possible residues of C1-4 alkyl esters are removed from the triglyceride by distillation or refining; the pre-hydrolysis and the subsequent synthesis preferably being carried out as a one-pot process in the same reactor and in the presence of the same enzyme.

    摘要翻译： 用于酶催化合成含有多不饱和脂肪酸的甘油三酯的方法，其中合成之前是预水解，其中（a）多不饱和脂肪酸的C 1-4烷基酯是完全或部分 在不加入水的情况下在真空中水解或在几个阶段内没有真空部分水解，（b）水解后，通过分离或蒸馏除去水，和（c）在真空中合成甘油的多不饱和脂肪酸 在低水条件下进行酶的形成甘油三酯的存在，（d）通过分离或过滤从甘油三酯中除去酶，和（e）C 1的剩余脂肪酸和/或可能的残基 通过蒸馏或精制从甘油三酯中除去-4.0烷基酯; 预水解和随后的合成优选在相同的反应器中和在相同的酶的存在下作为一锅法进行。