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公开(公告)号:US20240420962A1
公开(公告)日:2024-12-19
申请号:US18210918
申请日:2023-06-16
Applicant: Applied Materials, Inc.
Inventor: Doreen Wei Ying Yong , Tuck Foong Koh , John Sudijono , Mikhail Korolik , Paul E. Gee , Thai Cheng Chua , Philip A. Kraus
IPC: H01L21/311 , H01J37/32
Abstract: Embodiments of the present disclosure are directed to selective etching processes. The processes include an etching chemistry (a plasma of a fluorine-containing precursor and a first gas mixture), and a passivating chemistry (a plasma of a sulfur-containing precursor and a second gas mixture). In some embodiments, the sulfur-containing precursor and the second gas mixture are present in a ratio of sulfur-containing precursor to second gas mixture in a range of from 0.01 to 5. The methods include etching a substrate having a plurality of alternating layers of silicon oxide and silicon nitride thereon and a trench formed through the plurality of alternating layers. The silicon nitride layers are selectively etched relative to the silicon oxide layers at an etch selectivity of greater than or equal to 500:1.
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公开(公告)号:US20220306662A1
公开(公告)日:2022-09-29
申请号:US17841963
申请日:2022-06-16
Applicant: Applied Materials, Inc. , National University of Singapore
Inventor: Andrea Leoncini , Paul Mehlmann , Nemanja Dordevic , Han Vinh Huynh , Doreen Wei Ying Yong
IPC: C07F11/00 , C23C16/455 , C23C16/18
Abstract: Molybdenum(IV) and molybdenum(III) coordination complexes are described. Methods for depositing molybdenum-containing films on a substrate are described. The substrate is exposed to a molybdenum precursor and a reactant to form the molybdenum-containing film (e.g., elemental molybdenum, molybdenum oxide, molybdenum carbide, molybdenum silicide, molybdenum nitride). The exposures can be sequential or simultaneous.
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公开(公告)号:US20220220137A1
公开(公告)日:2022-07-14
申请号:US17146680
申请日:2021-01-12
Applicant: Applied Materials, Inc. , National University of Singapore
Inventor: Andrea Leoncini , Paul Mehlmann , Nemanja Dordevic , Han Vinh Huynh , Doreen Wei Ying Yong , Mark Saly , Bhaskar Jyoti Bhuyan , Feng Q. Liu
IPC: C07F11/00 , C23C16/455 , C23C16/18 , H01L31/042 , H01L31/18
Abstract: Molybdenum(VI) coordination complexes are described. Methods for depositing molybdenum-containing films on a substrate are described. The substrate is exposed to a molybdenum precursor and a reactant to form the molybdenum-containing film (e.g., elemental molybdenum, molybdenum oxide, molybdenum carbide, molybdenum silicide, molybdenum nitride). The exposures can be sequential or simultaneous.
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公开(公告)号:US20210111033A1
公开(公告)日:2021-04-15
申请号:US16598167
申请日:2019-10-10
Applicant: Applied Materials, Inc. , National University of Singapore
Inventor: Mikhail Korolik , Paul E. Gee , Bhaskar Jyoti Bhuyan , John Sudijono , Doreen Wei Ying Yong , Kah Wee Ang , Debanjan Jana , Niharendu Mahapatra
IPC: H01L21/311
Abstract: Exemplary methods of etching a silicon-containing material may include flowing a fluorine-containing precursor into a remote plasma region of a semiconductor processing chamber. The fluorine-containing precursor may be characterized by a molecular formula of XFy, and y may be greater than or equal to 5. The methods may include forming a plasma within the remote plasma region to generate plasma effluents of the fluorine-containing precursor. The methods may include flowing the plasma effluents into a processing region of the semiconductor processing chamber. A substrate may be positioned within the processing region, and the substrate may include a trench formed through stacked layers including alternating layers of silicon nitride and silicon oxide. The methods may include laterally etching the layers of silicon nitride.
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公开(公告)号:US20250069894A1
公开(公告)日:2025-02-27
申请号:US18223382
申请日:2023-07-18
Applicant: Applied Materials Inc.
Inventor: Doreen Wei Ying Yong , Tuck Foong Koh , Mikhail Korolik , John Sudijono , Paul E. Gee
IPC: H01L21/311
Abstract: Embodiments of the present disclosure are directed to selective etching processes. The processes include flowing a precursor comprising one or more of an interhalogen, a halogen-containing species, a pseudohalogen species, a mixture of one or more of the interhalogen, the halogen-containing species, or the pseudohalogen species and an amine or a phosphine, or a mixture of one or more of the interhalogen, the halogen-containing species, or the pseudohalogen species with a sulfur-containing species, into a semiconductor processing chamber containing a substrate, and forming an activated species of the precursor to etch a substrate. The substrate has a plurality of alternating layers of silicon oxide and silicon nitride thereon and a trench formed through the plurality of alternating layers. The silicon nitride layers are selectively etched relative to the silicon oxide layers at an etch selectivity of greater than or equal to 500:1.
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公开(公告)号:US20240271272A1
公开(公告)日:2024-08-15
申请号:US18635639
申请日:2024-04-15
Applicant: Applied Materials, Inc.
Inventor: Yong Wang , Doreen Wei Ying Yong , Bhaskar Jyoti Bhuyan , John Sudijono
CPC classification number: C23C16/0227 , C23C16/04 , C23C16/56 , C23C22/77 , C23C22/82
Abstract: Methods of patterning semiconductor devices comprising selective deposition methods are described. A blocking layer is deposited on a metal surface of a semiconductor device before deposition of a dielectric material on a dielectric surface. Methods include exposing a substrate surface including a metal surface and a dielectric surface to a heterocyclic reactant comprising a headgroup and a tailgroup in a processing chamber and selectively depositing the heterocyclic reactant on the metal surface to form a passivation layer, wherein the heterocyclic headgroup selectively reacts and binds to the metal surface.
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公开(公告)号:US20230151038A1
公开(公告)日:2023-05-18
申请号:US18097406
申请日:2023-01-16
Applicant: Applied Materials, Inc. , National University of Singapore
Inventor: Andrea Leoncini , Paul Mehlmann , Nemanja Dordevic , Han Vinh Huynh , Doreen Wei Ying Yong
Abstract: Molybdenum(0) coordination complexes comprising an arene ligand and one or more neutral ligands which coordinate to the metal center by carbon, nitrogen or phosphorous are described. Methods for depositing molybdenum-containing films on a substrate are described. The substrate is exposed to a molybdenum precursor and a reactant to form the molybdenum-containing film (e.g., elemental molybdenum, molybdenum oxide, molybdenum carbide, molybdenum silicide, molybdenum nitride). The exposures can be sequential or simultaneous.
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公开(公告)号:US11584768B2
公开(公告)日:2023-02-21
申请号:US17146886
申请日:2021-01-12
Applicant: Applied Materials, Inc. , National University of Singapore
Inventor: Andrea Leoncini , Paul Mehlmann , Nemanja Dordevic , Han Vinh Huynh , Doreen Wei Ying Yong
Abstract: Molybdenum(0) coordination complexes comprising an arene ligand and one or more neutral ligands which coordinate to the metal center by carbon, nitrogen or phosphorous are described. Methods for depositing molybdenum-containing films on a substrate are described. The substrate is exposed to a molybdenum precursor and a reactant to form the molybdenum-containing film (e.g., elemental molybdenum, molybdenum oxide, molybdenum carbide, molybdenum silicide, molybdenum nitride). The exposures can be sequential or simultaneous.
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公开(公告)号:US11515154B2
公开(公告)日:2022-11-29
申请号:US17081506
申请日:2020-10-27
Applicant: Applied Materials, Inc. , National University of Singapore
Inventor: Andrea Leoncini , Yong Wang , Doreen Wei Ying Yong
Abstract: Selective deposition methods are described. An exemplary method comprises exposing the substrate comprising a first surface and a second surface to an anchor reactant and selectively depositing the anchor reactant on the first surface as a seed layer, wherein the anchor reactant comprises an ethynyl derivative with a headgroup that selectively targets the first surface.
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公开(公告)号:US11760768B2
公开(公告)日:2023-09-19
申请号:US17236020
申请日:2021-04-21
Applicant: Applied Materials, Inc.
Inventor: Chandan Kr Barik , John Sudijono , Chandan Das , Doreen Wei Ying Yong , Mark Saly , Bhaskar Jyoti Bhuyan , Feng Q. Liu
CPC classification number: C07F11/005 , C23C16/0272 , C23C16/18 , C23C16/4408 , C23C16/45527 , C23C16/45553 , C23C16/56 , C23C16/0209 , C23C16/0227
Abstract: Molybdenum(0) and coordination complexes are described. Methods for depositing molybdenum-containing films on a substrate are described. The substrate is exposed to a molybdenum precursor and a reactant to form the molybdenum-containing film (e.g., elemental molybdenum, molybdenum oxide, molybdenum carbide, molybdenum silicide, molybdenum disulfide, molybdenum nitride). The exposures can be sequential or simultaneous.
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