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    Transparent articles prepared from thermoplastic compositions having low birefringence
    4.
    发明授权
    Transparent articles prepared from thermoplastic compositions having low birefringence 有权
    由具有低双折射率的热塑性组合物制备的透明制品

    公开(公告)号：US08064140B2

    公开(公告)日：2011-11-22

    申请号：US12879494

    申请日：2010-09-10

    申请人： Theodorus Lambertus Hoeks ,  Jan Henk Kamps ,  Dennis Karlik ,  Edward Kung ,  Michael Teruki Takemori

    发明人： Theodorus Lambertus Hoeks ,  Jan Henk Kamps ,  Dennis Karlik ,  Edward Kung ,  Michael Teruki Takemori

    IPC分类号： G02B3/00 ,  G02B7/00

    CPC分类号： C08G63/64 ,  C08G64/12 ,  C08G64/18 ,  C08L69/00 ,  C08L69/005 ,  G02B1/04 ,  C08L2666/18

    摘要： An optical grade article comprises a thermoplastic composition comprising a poly(aliphatic ester)-polycarbonate copolymer comprising 10 to 25 wt % of a soft block ester unit derived from a C20-44 aliphatic dicarboxylic acid or derivative thereof, 34 to 77 wt % of a carbonate unit derived from 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, 0 to 76 wt % of a carbonate unit derived from a dihydroxyaromatic compound not identical to the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the weight percentages of soft block ester units, 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine units, and dihydroxyaromatic compound units is 100 weight percent of the monomeric units of the poly(aliphatic ester)-polycarbonate, the refractive index of the thermoplastic composition is greater than 1.590, and the glass transition temperature of the poly(aliphatic ester)-polycarbonate is from 120 to 155° C. A camera lens also comprises the poly(aliphatic ester)-polycarbonate.

    摘要翻译： 光学级制品包括热塑性组合物，其包含聚（脂肪族酯） - 聚碳酸酯共聚物，其包含10至25重量％的衍生自C20-44脂族二羧酸或其衍生物的软嵌段酯单元，34至77重量％的 衍生自2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的碳酸酯单元，0至76重量％的衍生自与2-烃基-3,3-双（4- 羟基芳基）苯并二氮嘧啶，其中软嵌段酯单元，2-烃基-3,3-双（4-羟基芳基）苯二酰亚胺单元和二羟基芳族化合物单元的重量百分比为聚（脂族酯）单体单元的100重量％ 聚碳酸酯，热塑性组合物的折射率大于1.590，聚（脂肪族酯） - 聚碳酸酯的玻璃化转变温度为120至155℃。相机透镜还包含聚（脂肪族酯） - 聚碳酸酯 。

    TRANSPARENT ARTICLES PREPARED FROM THERMOPLASTIC COMPOSITIONS HAVING LOW BIREFRINGENCE
    5.
    发明申请
    TRANSPARENT ARTICLES PREPARED FROM THERMOPLASTIC COMPOSITIONS HAVING LOW BIREFRINGENCE 有权
    具有低透光度的热塑性组合物制备的透明物品

    公开(公告)号：US20110071261A1

    公开(公告)日：2011-03-24

    申请号：US12879494

    申请日：2010-09-10

    申请人： Theodorus Lambertus Hoeks ,  Jan Henk Kamps ,  Dennis Karlik ,  Edward Kung ,  Michael Teruki Takemori

    发明人： Theodorus Lambertus Hoeks ,  Jan Henk Kamps ,  Dennis Karlik ,  Edward Kung ,  Michael Teruki Takemori

    IPC分类号： C08G63/91

    CPC分类号： C08G63/64 ,  C08G64/12 ,  C08G64/18 ,  C08L69/00 ,  C08L69/005 ,  G02B1/04 ,  C08L2666/18

    摘要： An optical grade article comprises a thermoplastic composition comprising a poly(aliphatic ester)-polycarbonate copolymer comprising 10 to 25 wt % of a soft block ester unit derived from a C20-44 aliphatic dicarboxylic acid or derivative thereof, 34 to 77 wt % of a carbonate unit derived from 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, 0 to 76 wt % of a carbonate unit derived from a dihydroxyaromatic compound not identical to the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the weight percentages of soft block ester units, 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine units, and dihydroxyaromatic compound units is 100 weight percent of the monomeric units of the poly(aliphatic ester)-polycarbonate, the refractive index of the thermoplastic composition is greater than 1.590, and the glass transition temperature of the poly(aliphatic ester)-polycarbonate is from 120 to 155° C. A camera lens also comprises the poly(aliphatic ester)-polycarbonate.

    摘要翻译： 光学级制品包括热塑性组合物，其包含聚（脂肪族酯） - 聚碳酸酯共聚物，其包含10至25重量％的衍生自C20-44脂族二羧酸或其衍生物的软嵌段酯单元，34至77重量％的 衍生自2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的碳酸酯单元，0至76重量％的衍生自与2-烃基-3,3-双（4- 羟基芳基）苯并二氮嘧啶，其中软嵌段酯单元，2-烃基-3,3-双（4-羟基芳基）苯二酰亚胺单元和二羟基芳族化合物单元的重量百分比为聚（脂族酯）单体单元的100重量％ 聚碳酸酯，热塑性组合物的折射率大于1.590，聚（脂肪族酯） - 聚碳酸酯的玻璃化转变温度为120至155℃。相机透镜还包含聚（脂肪族酯） - 聚碳酸酯 。

    Poly(carbonate-co-urea) copolymers and melt transesterification method of preparing these copolymers
    6.
    发明授权
    Poly(carbonate-co-urea) copolymers and melt transesterification method of preparing these copolymers 失效
    聚（碳酸酯 - 共 - 尿素）共聚物和制备这些共聚物的熔融酯交换法

    公开(公告)号：US07666977B2

    公开(公告)日：2010-02-23

    申请号：US11743761

    申请日：2007-05-03

    申请人： Jan Henk Kamps ,  Edward Kung ,  Jan-Pleun Lens

    发明人： Jan Henk Kamps ,  Edward Kung ,  Jan-Pleun Lens

    IPC分类号： C08G73/00 ,  C08G64/00

    CPC分类号： C08G64/12 ,  C08G63/64 ,  C08G71/02

    摘要： Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.

    摘要翻译： 本文公开了一种制备聚（碳酸酯 - 共 - 尿素）共聚物的方法，其包括在熔体中反应：（a）包含二羟基化合物的二羟基反应组分，（b）包含碳酸二芳基酯的碳酸二芳酯反应组分，（c ）在至少部分反应期间（d）酯交换催化剂存在下包含脲化合物的脲反应组分，并除去酚类副产物以产生聚（碳酸酯 - 共 - 尿素）共聚物，其中脲和二羟基化合物 以摩尔比（尿素化合物的总摩尔数）/（（脲化合物的总摩尔数）+（二羟基化合物的总摩尔数））小于或等于0.5。

    Method of Preparing Polycarbonate
    9.
    发明申请
    Method of Preparing Polycarbonate 有权
    聚碳酸酯的制备方法

    公开(公告)号：US20080004418A1

    公开(公告)日：2008-01-03

    申请号：US11427885

    申请日：2006-06-30

    申请人： Bernd Jansen ,  Jan Henk Kamps ,  Edward Kung ,  Patrick Joseph McCloskey ,  Paul Michael Smigelski

    发明人： Bernd Jansen ,  Jan Henk Kamps ,  Edward Kung ,  Patrick Joseph McCloskey ,  Paul Michael Smigelski

    IPC分类号： C08G64/00

    CPC分类号： C08G64/14 ,  C08G64/307

    摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates in a transesterification process have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, in the presence of a monohydroxy chainstopper such as para-cumyl phenol in an amount that results in 35 to 65 mol % of the end groups being derived from the monohydroxy chainstopper. Suitably, the reactants are provided such that the molar ratio of activated diaryl carbonate to the total of dihydroxy compound plus ½ the chainstopping reagent that is less than 1.

    摘要翻译： 在酯交换方法中，衍生自酯取代的活性碳酸酯的末端碳酸酯基团的聚碳酸酯在颜色，水解稳定性和热稳定性方面具有不利的性质，特别是当含有这样的端基的聚碳酸酯被成型时。 在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以通过在酯化催化剂的存在下使二羟基化合物与活化的碳酸二芳基酯反应来制备聚碳酸酯，在单羟基链断裂剂例如对 - 辛基苯酚，其量导致35-65mol％端基衍生自单羟基链断裂剂。 适当地，提供反应物使得活化的碳酸二芳基酯与二羟基化合物的总和加上1/2的阻滞剂的摩尔比小于1。