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    Process of producing fuel gas for fuel cell
    1.
    发明授权
    Process of producing fuel gas for fuel cell 有权
    生产燃料电池燃料气的工艺

    公开(公告)号：US07175827B2

    公开(公告)日：2007-02-13

    申请号：US10813490

    申请日：2004-03-30

    申请人： Iwao Anzai ,  Takaya Matsumoto

    发明人： Iwao Anzai ,  Takaya Matsumoto

    IPC分类号： C01B3/22 ,  C01B3/26 ,  C01B3/32 ,  C01B3/40 ,  H01M8/04

    CPC分类号： B01J23/63 ,  C01B3/326 ,  C01B3/40 ,  C01B2203/0244 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/1205 ,  C01B2203/1217 ,  C01B2203/1235 ,  Y02P20/52

    摘要： A process for producing a fuel gas for a fuel cell is provided. The process includes a step of converting hydrocarbons and/or oxygen-containing hydrocarbons to a reformed gas which is composed principally of hydrogen by an autothermal reforming reaction using an autothermal reforming catalyst. The catalyst includes rhodium supported on a support containing 5 to 40 percent by mass of a cerium oxide or rare earth element oxide which is composed principally of a cerium oxide, 60 to 95 percent by mass of an aluminum oxide, and 0 to 10 percent by mass in terms of metal of one or more elements selected from the group consisting of an alkaline metal and an alkaline earth metal, the atomic ratio of cerium and rhodium (Ce/Rh) being 1 to 250.

    摘要翻译： 提供一种燃料电池用燃料气体的制造方法。 该方法包括通过使用自热重整催化剂的自热重整反应将烃和/或含氧烃转化为主要由氢组成的重整气体的步骤。 催化剂包括负载在载体上的铑，其含有5〜40质量％的氧化铈或稀土元素氧化物，其主要由氧化铈，60〜95质量％的氧化铝和0〜10质量％ 以选自碱金属和碱土金属的一种或多种元素的金属质量计，铈和铑（Ce / Rh）的原子比为1至250。

    Process of producing fuel gas for fuel cell
    2.
    发明授权
    Process of producing fuel gas for fuel cell 失效
    生产燃料电池燃料气的工艺

    公开(公告)号：US07144566B2

    公开(公告)日：2006-12-05

    申请号：US10813473

    申请日：2004-03-30

    申请人： Iwao Anzai ,  Takaya Matsumoto

    发明人： Iwao Anzai ,  Takaya Matsumoto

    IPC分类号： C01B3/26 ,  C01B3/22 ,  B01J23/10 ,  H01M8/04

    CPC分类号： C01B3/40 ,  B01J23/63 ,  B01J35/10 ,  B01J35/1019 ,  C01B3/326 ,  C01B2203/0244 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1205 ,  C01B2203/1217 ,  C01B2203/1235 ,  Y02P20/52

    摘要： A process for producing a fuel gas for a fuel cell is provided. The process includes a step of converting hydrocarbons and/or oxygen-containing hydrocarbons to a reformed gas which is composed principally of hydrogen by an autothermal reforming reaction using an autothermal reforming catalyst. The catalyst includes ruthenium supported on a support containing 5 to 40 percent by mass of a cerium oxide or rare earth element oxide which is composed principally of a cerium oxide, 60 to 95 percent by mass of an aluminum oxide, and 0 to 10 percent by mass in terms of metal of one or more elements selected from the group consisting of an alkaline metal and an alkaline earth metal, the atomic ratio of cerium and rhodium (Ce/Rh) being 1 to 250.

    摘要翻译： 提供一种燃料电池用燃料气体的制造方法。 该方法包括通过使用自热重整催化剂的自热重整反应将烃和/或含氧烃转化为主要由氢组成的重整气体的步骤。 催化剂包括负载在载体上的钌，其含有5〜40质量％的氧化铈或稀土元素氧化物，其主要由氧化铈，60〜95质量％的氧化铝和0〜10质量％ 以选自碱金属和碱土金属的一种或多种元素的金属质量计，铈和铑（Ce / Rh）的原子比为1至250。

    Method of alkylating the side chain of alkyl-substituted aromatic hydrocarbons
    5.
    发明授权
    Method of alkylating the side chain of alkyl-substituted aromatic hydrocarbons 失效
    烷基取代芳烃侧链的烷基化方法

    公开(公告)号：US5608132A

    公开(公告)日：1997-03-04

    申请号：US417964

    申请日：1995-04-06

    申请人： Takaya Matsumoto ,  Shinji Nishikawa ,  Fumio Kumata

    发明人： Takaya Matsumoto ,  Shinji Nishikawa ,  Fumio Kumata

    IPC分类号： B01J27/232 ,  B01J23/00 ,  B01J37/08 ,  C07B61/00 ,  C07C2/72 ,  C07C15/02

    CPC分类号： C07C2/72 ,  B01J23/002 ,  B01J23/007 ,  B01J37/088 ,  C07C2523/04 ,  C07C2527/232

    摘要： A method of alkylating a side chain of alkyl-substituted aromatic hydrocarbons. The method involves the steps of loading an alkali metal on a thermally treated hydrotalcite carrier represented by formula (I) by an impregnation method using the alkali metal dissolved in liquid ammonia, thermally treating the alkali metal loaded hydrotalcite carrier under vacuum to prepare a catalyst, then reacting an alkyl-substituted aromatic hydrocarbon with an aliphatic monoolefin using the catalyst under an atmosphere substantially free of oxygen, water and carbon dioxide gas to alkylate a side chain of the alkyl-substituted aromatic hydrocarbon:[M.sup.2+.sub.(1-x) .multidot.M.sup.3+.sub.x (OH).sub.2 ].sup.x+ .multidot.[A.sup.n-.sub.x/n ].sup.x- .multidot.yH.sub.2 O (I)wherein M.sup.2+ represents a divalent metallic cation, M.sup.3+ represents a trivalent metallic cation, A.sup.n- represents an n-valent anion, n=0.1 to 0.5, x=0.1 to 0.5, and y=0 to 8.

    摘要翻译： 烷基取代芳烃的侧链烷基化方法。 该方法包括以下步骤：通过浸渍方法将碱金属加载在由式（I）表示的热处理水滑石载体上，使用溶解在液氨中的碱金属，在真空下热处理负载碱金属的水滑石载体以制备催化剂， 然后使用催化剂在基本上不含氧，水和二氧化碳的气氛下使烷基取代的芳族烃与脂族单烯烃反应，烷基取代的芳族烃的侧链烷基化：[M2 +（1-x）xM3 + x（OH）2] x + x [An-x / n] x-xyH 2 O（I）其中M2 +表示二价金属阳离子，M3 +表示三价金属阳离子，An表示n价阴离子，n = 0.5，x = 0.1〜0.5，y = 0〜8。

    Method of alkylating the side chain of alkyl-substituted aromatic hydrocarbons
    8.
    发明授权
    Method of alkylating the side chain of alkyl-substituted aromatic hydrocarbons 失效
    烷基取代芳烃侧链的烷基化方法

    公开(公告)号：US5625102A

    公开(公告)日：1997-04-29

    申请号：US364446

    申请日：1994-12-27

    申请人： Takaya Matsumoto ,  Yoshiichi Kumagai ,  Fumio Kumata

    发明人： Takaya Matsumoto ,  Yoshiichi Kumagai ,  Fumio Kumata

    IPC分类号： B01J23/04 ,  C07B61/00 ,  C07C2/72 ,  C07C15/02 ,  F28D7/00 ,  C07C15/067

    CPC分类号： F28D7/0066 ,  B01J23/04 ,  C07C2/72 ,  C07C2521/04 ,  C07C2523/04

    摘要： A method of alkylating the side chain of alkyl-substituted aromatic hydrocarbons. The method comprises the steps of thermally treating an alumina by calcining in air and then degassing under vacuum to prepare an alumina carrier, loading an alkali metal on the alumina carrier by an impregnation method using the alkali metal dissolved in liquid ammonia, thermally treating the alkali metal loaded alumina carrier under vacuum to prepare a catalyst, then reacting an alkyl-substituted aromatic hydrocarbon with an aliphatic monoolefin, using the catalyst, under an atmosphere substantially free of oxygen, water and carbon dioxide gas to alkylate the side chain of the alkyl-substituted aromatic hydrocarbon.

    摘要翻译： 烷基取代芳烃的侧链烷基化方法。 该方法包括以下步骤：在空气中煅烧氧化铝，然后在真空下进行脱气以制备氧化铝载体，通过浸渍方法将碱金属加载到氧化铝载体上，使用溶于液氨的碱金属，热处理碱 金属负载的氧化铝载体在真空下制备催化剂，然后使用催化剂，在基本上不含氧气的水气和二氧化碳气氛下使烷基取代的芳族烃与脂肪族单烯烃反应，烷基化烷基 - 取代的芳族烃。