公开(公告)号：US20120040823A1

公开(公告)日：2012-02-16

申请号：US13262076

申请日：2010-02-12

申请人： Yasuyuki Iwasa ,  Takaya Matsumoto

发明人： Yasuyuki Iwasa ,  Takaya Matsumoto

IPC分类号： B01J23/46 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08

CPC分类号： B01J23/462 ,  B01J21/04 ,  B01J23/42 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0213 ,  B01J37/16 ,  C01B3/583 ,  C01B3/586 ,  C01B2203/044 ,  C01B2203/0445 ,  C01B2203/047 ,  C10K3/04 ,  H01M8/0612 ,  H01M8/0668

摘要： The present invention provides a method for producing a catalyst for use in preferential carbon monoxide oxidation, which catalyst has a high preferential carbon monoxide oxidation activity and a high methanation activity with respect to the carbon monoxide contained in hydrogen gas, can thus stably reduce the carbon monoxide concentration to an extremely lower level and comprises porous inorganic oxide support particles and, on the basis of the mass thereof, 0.01 to 10 percent by mass of ruthenium and 0.01 to 1 percent by mass of platinum, loaded on the support. The method comprises (1) a step of loading 30 to 70 percent of the total amount of ruthenium to be loaded, on the support particles by a competitive adsorption method and (2) a step of loading the rest of the total amount of ruthenium to be loaded and the total amount of platinum to be loaded, on the ruthenium-loaded support particles produced in step (1) without using a competitive adsorption agent.

摘要翻译： 本发明提供一种用于优先一氧化碳氧化的催化剂的制备方法，该催化剂相对于氢气中所含的一氧化碳具有优先的一氧化碳氧化活性和高甲烷化活性，因此可稳定地降低碳 一氧化碳浓度达到极低水平，并且包含多孔无机氧化物载体颗粒，并且基于其质量，装载在载体上的钌的含量为0.01〜10质量％，铂的0.01〜1质量％。 该方法包括（1）通过竞争性吸附法将负载钌总量的30〜70％载持在载体颗粒上的步骤，和（2）将其余总量的钌负载到 在不使用竞争性吸附剂的情况下，将负载铂和铂的总量添加到在步骤（1）中制备的载有钌的载体颗粒上。

公开(公告)号：US08093178B2

公开(公告)日：2012-01-10

申请号：US12520127

申请日：2007-12-17

申请人： Yasuyuki Iwasa ,  Takaya Matsumoto

发明人： Yasuyuki Iwasa ,  Takaya Matsumoto

IPC分类号： B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J8/00 ,  B01J8/02 ,  B01D47/00 ,  B01D53/34 ,  B01D53/56 ,  B01D53/94 ,  B01D53/14 ,  C01B21/00 ,  C01B23/00 ,  C01B25/00 ,  C01B31/00 ,  C01B33/00 ,  C01B35/00 ,  C01B31/18 ,  C01G28/00 ,  C01G30/00 ,  C01G43/00 ,  C01G56/00 ,  C10K1/00 ,  C01F13/00 ,  C01F15/00

CPC分类号： C01B3/583 ,  B01J21/04 ,  B01J23/462 ,  B01J23/50 ,  B01J35/0073 ,  B01J37/0201 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/042 ,  C01B2203/044 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  H01M8/0668

摘要： Disclosed in a catalyst which enables to reduce the carbon monoxide concentration in a product gas to 5 ppm by volume or less when carbon monoxide in a raw material gas containing hydrogen and carbon monoxide is selectively oxidized. The catalyst comprises a support of an inorganic oxide and ruthenium loaded thereon, and the relative loading depth X(Ru) of ruthenium in the radial direction in a redial cross-section of the catalyst satisfies the requirement defined by the following formula (1) X(Ru)≧15  (1).

摘要翻译： 公开了一种催化剂，其能够在含有氢和一氧化碳的原料气体中的一氧化碳选择性氧化时将产物气体中的一氧化碳浓度降低至5体积ppm以下。 催化剂包括负载有无机氧化物和钌的载体，催化剂的重力横截面中钌的径向相对负载深度X（Ru）满足下式（1）X （Ru）≥15（1）。

公开(公告)号：US20100086814A1

公开(公告)日：2010-04-08

申请号：US12520127

申请日：2007-12-17

申请人： Yasuyuki Iwasa ,  Takaya Matsumoto

发明人： Yasuyuki Iwasa ,  Takaya Matsumoto

IPC分类号： H01M8/18 ,  B01J19/00 ,  B01J23/46 ,  B01J21/04 ,  B01J21/08 ,  B01J23/52 ,  C01B3/58

CPC分类号： C01B3/583 ,  B01J21/04 ,  B01J23/462 ,  B01J23/50 ,  B01J35/0073 ,  B01J37/0201 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/042 ,  C01B2203/044 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  H01M8/0668

摘要： Disclosed in a catalyst which enables to reduce the carbon monoxide concentration in a product gas to 5 ppm by volume or less when carbon monoxide in a raw material gas containing hydrogen and carbon monoxide is selectively oxidized. The catalyst comprises a support of an inorganic oxide and ruthenium loaded thereon, and the relative loading depth X(Ru) of ruthenium in the radial direction in a redial cross-section of the catalyst satisfies the requirement defined by the following formula (1) X(Ru)≧15  (1).

摘要翻译： 公开了一种催化剂，其能够在含有氢和一氧化碳的原料气体中的一氧化碳选择性氧化时将产物气体中的一氧化碳浓度降低至5体积ppm以下。 催化剂包括负载有无机氧化物和钌的载体，催化剂的重力横截面中钌的径向相对负载深度X（Ru）满足下式（1）X （Ru）≥15（1）。

公开(公告)号：US08349762B2

公开(公告)日：2013-01-08

申请号：US13262076

申请日：2010-02-12

申请人： Yasuyuki Iwasa ,  Takaya Matsumoto

发明人： Yasuyuki Iwasa ,  Takaya Matsumoto

IPC分类号： B01J23/00 ,  B01J21/00

CPC分类号： B01J23/462 ,  B01J21/04 ,  B01J23/42 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0213 ,  B01J37/16 ,  C01B3/583 ,  C01B3/586 ,  C01B2203/044 ,  C01B2203/0445 ,  C01B2203/047 ,  C10K3/04 ,  H01M8/0612 ,  H01M8/0668

摘要： The present invention provides a method for producing a catalyst for use in preferential carbon monoxide oxidation, which catalyst has a high preferential carbon monoxide oxidation activity and a high methanation activity with respect to the carbon monoxide contained in hydrogen gas, can thus stably reduce the carbon monoxide concentration to an extremely lower level and comprises porous inorganic oxide support particles and, on the basis of the mass thereof, 0.01 to 10 percent by mass of ruthenium and 0.01 to 1 percent by mass of platinum, loaded on the support. The method comprises (1) a step of loading 30 to 70 percent of the total amount of ruthenium to be loaded, on the support particles by a competitive adsorption method and (2) a step of loading the rest of the total amount of ruthenium to be loaded and the total amount of platinum to be loaded, on the ruthenium-loaded support particles produced in step (1) without using a competitive adsorption agent.

摘要翻译： 本发明提供一种用于优先一氧化碳氧化的催化剂的制备方法，该催化剂相对于氢气中所含的一氧化碳具有优先的一氧化碳氧化活性和高的甲烷化活性，因此可稳定地降低碳 一氧化碳浓度达到极低水平，并且包含多孔无机氧化物载体颗粒，并且基于其质量，装载在载体上的钌的含量为0.01〜10质量％，铂的0.01〜1质量％。 该方法包括（1）通过竞争性吸附法将负载钌总量的30〜70％载持在载体颗粒上的步骤，和（2）将其余总量的钌负载到 在不使用竞争性吸附剂的情况下，将负载铂和铂的总量添加到在步骤（1）中制备的载有钌的载体颗粒上。

公开(公告)号：US09815047B2

公开(公告)日：2017-11-14

申请号：US13976655

申请日：2011-12-28

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

IPC分类号： C07C4/06 ,  B01J29/70 ,  C10G11/18 ,  C10G47/16 ,  C10G11/05 ,  B01J29/85 ,  B01J37/00 ,  C01B39/48 ,  C01B39/10

CPC分类号： B01J29/70 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2229/186 ,  C01B39/10 ,  C01B39/48 ,  C07C4/06 ,  C07C2529/06 ,  C07C2529/40 ,  C10G11/05 ,  C10G11/18 ,  C10G47/16 ,  C10G2300/1033 ,  C10G2300/1048 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/301 ,  C10G2400/30

摘要： The catalyst for producing aromatic hydrocarbon is for producing monocyclic aromatic hydrocarbon having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower and contains crystalline aluminosilicate and phosphorus. A molar ratio (P/Al ratio) between phosphorus contained in the crystalline aluminosilicate and aluminum of the crystalline aluminosilicate is from 0.1 to 1.0. The production method of monocyclic aromatic hydrocarbon is a method of bringing oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower into contact with the catalyst for producing monocyclic aromatic hydrocarbon.

公开(公告)号：US20130281756A1

公开(公告)日：2013-10-24

申请号：US13976701

申请日：2011-12-28

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

IPC分类号： C10G11/05

CPC分类号： C10G11/05 ,  B01J29/40 ,  B01J29/65 ,  B01J29/703 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/80 ,  B01J29/82 ,  B01J29/87 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/04 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/18 ,  C10G45/68 ,  C10G69/04 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2400/30

摘要： In the production method of monocyclic aromatic hydrocarbons, oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with a catalyst for producing monocyclic aromatic hydrocarbons that includes a mixture containing a first catalyst which contains crystalline aluminosilicate containing gallium and/or zinc and phosphorus and a second catalyst which contains crystalline aluminosilicate containing phosphorus.

摘要翻译： 在单环芳烃的制造方法中，使具有140℃或更高的10体积％蒸馏温度和380℃或更低的90体积％蒸馏温度的油原料与用于制备单环芳族化合物的催化剂接触 包括含有含有含有镓和/或锌和磷的结晶硅铝酸盐的第一催化剂和含有含磷结晶硅铝酸盐的第二催化剂的混合物的烃。

公开(公告)号：US20130281755A1

公开(公告)日：2013-10-24

申请号：US13976581

申请日：2011-12-28

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

IPC分类号： B01J29/70 ,  C07C4/06

CPC分类号： B01J29/7049 ,  B01J23/10 ,  B01J29/061 ,  B01J29/40 ,  B01J29/405 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0201 ,  B01J2229/186 ,  B01J2229/42 ,  C07C4/06 ,  C10G11/05 ,  C10G47/16 ,  C10G47/20 ,  C10G69/04 ,  C10G2300/301 ,  C10G2400/30

摘要： The catalyst for producing monocyclic aromatic hydrocarbons is for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower. The catalyst contains crystalline aluminosilicate and a rare earth element, in which the amount of the rare earth element expressed in terms of the element is 0.1 to 10 mass % based on the crystalline aluminosilicate. In the production method of monocyclic aromatic hydrocarbons, oil feed stock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with the catalyst for producing monocyclic aromatic hydrocarbons.

摘要翻译： 用于生产单环芳烃的催化剂用于生产具有10体积％蒸馏温度为140℃或更高，90体积％蒸馏温度为380℃或更低的油原料具有6至8个碳数的单环芳烃 。 催化剂含有结晶硅铝酸盐和稀土元素，其中以元素表示的稀土元素的量相对于结晶铝硅酸盐为0.1〜10质量％。 在单环芳香烃的制造方法中，将具有10体积％蒸馏温度为140℃以上，90体积％蒸馏温度为380℃以下的原料原料与用于制造单环芳烃的催化剂接触 芳烃。

公开(公告)号：US20130184506A1

公开(公告)日：2013-07-18

申请号：US13822556

申请日：2011-09-14

申请人： Shinichiro Yanagawa ,  Ryoji Ida ,  Masahide Kobayashi ,  Yasuyuki Iwasa

发明人： Shinichiro Yanagawa ,  Ryoji Ida ,  Masahide Kobayashi ,  Yasuyuki Iwasa

IPC分类号： C10G11/05

CPC分类号： C10G11/05 ,  C10G35/095 ,  C10G45/44 ,  C10G63/02 ,  C10G69/00 ,  C10G69/08 ,  C10G2300/203 ,  C10G2300/301 ,  C10G2400/30

摘要： Disclosed is a method for producing aromatic hydrocarbons including a cracking reforming reaction step of bringing a feedstock having a 10 vol % distillation temperature of 140° C. or higher and a 90 vol % distillation temperature of 380° C. or lower, into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate to cause the feedstock to react with the catalyst, and thereby obtaining a product including monocyclic aromatic hydrocarbons having 6 to 8 carbon numbers and a heavy oil fraction having 9 or more carbon numbers; a step of separating the monocyclic aromatic hydrocarbons and the heavy oil fraction from the product obtained from the cracking reforming reaction step; a step of purifying the monocyclic aromatic hydrocarbons separated in the separating step, and collecting the hydrocarbons; and a step of separating naphthalene compounds from the heavy oil fraction separated in the separating step, and collecting the naphthalene compounds.

摘要翻译： 本发明公开了一种芳烃化合物的制造方法，其特征在于，包括裂解重整反应步骤，使10vol％蒸馏温度为140℃以上，90体积％蒸馏温度为380℃以下的原料与 含有结晶硅铝酸盐以使原料与催化剂反应的单环芳香烃生产催化剂，从而得到包括具有6至8个碳数的单环芳烃和具有9个或更多个碳数的重油馏分的产物; 从裂解重整反应步骤获得的产物中分离单环芳烃和重油馏分的步骤; 纯化在分离步骤中分离的单环芳烃并收集烃的步骤; 以及从分离步骤中分离的重油馏分中分离萘化合物的步骤，并收集萘化合物。

公开(公告)号：US09382484B2

公开(公告)日：2016-07-05

申请号：US13976701

申请日：2011-12-28

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

IPC分类号： C07C4/18 ,  C07C5/00 ,  C10G11/05 ,  C10G11/18 ,  B01J37/04 ,  B01J29/80 ,  B01J37/00 ,  C10G45/68 ,  C10G69/04 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/82 ,  B01J29/87 ,  B01J35/10

CPC分类号： C10G11/05 ,  B01J29/40 ,  B01J29/65 ,  B01J29/703 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/80 ,  B01J29/82 ,  B01J29/87 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/04 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/18 ,  C10G45/68 ,  C10G69/04 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2400/30

摘要： In the production method of monocyclic aromatic hydrocarbons, oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with a catalyst for producing monocyclic aromatic hydrocarbons that includes a mixture containing a first catalyst which contains crystalline aluminosilicate containing gallium and/or zinc and phosphorus and a second catalyst which contains crystalline aluminosilicate containing phosphorus.

摘要翻译： 在单环芳烃的制造方法中，使具有140℃或更高的10体积％蒸馏温度和380℃或更低的90体积％蒸馏温度的油原料与用于制备单环芳族化合物的催化剂接触 包括含有含有含有镓和/或锌和磷的结晶硅铝酸盐的第一催化剂和含有含磷结晶硅铝酸盐的第二催化剂的混合物的烃。

公开(公告)号：US09255042B2

公开(公告)日：2016-02-09

申请号：US14119571

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C2/42 ,  C10G35/00 ,  C10G15/00 ,  C07C4/06 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  B01D3/00 ,  C10G35/14 ,  C10G35/24 ,  C10G49/26 ,  C10G11/18 ,  B01J29/04 ,  B01J29/08 ,  B01J29/18 ,  B01J29/82 ,  B01J29/86

CPC分类号： C07C4/06 ,  B01D3/009 ,  B01J29/047 ,  B01J29/048 ,  B01J29/08 ,  B01J29/18 ,  B01J29/185 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/82 ,  B01J29/86 ,  B01J29/87 ,  B01J2229/186 ,  C10G11/187 ,  C10G35/14 ,  C10G35/24 ,  C10G49/26 ,  C10G2300/301 ,  C10G2400/30

摘要： A producing method of monocyclic aromatic hydrocarbons from the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140° C. and a 90 volume % distillation temperature of less than or equal to 380° C. by bringing into contact with an aromatic production catalyst includes the steps of: introducing the oil feedstock into a cracking and reforming reaction apparatus housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other at the inside of the cracking and reforming reaction apparatus; heating the oil feedstock in advance before introducing the oil feedstock into the cracking and reforming reaction apparatus and forming a two-phase gas-liquid stream; separating the two-phase gas-liquid stream into a gas fraction and a liquid fraction; and introducing the gas fraction and the liquid fraction at different positions of the cracking and reforming reaction apparatus.

摘要翻译： 来自油原料的单环芳烃的制备方法，其具有大于或等于140℃的10体积％蒸馏温度和小于或等于380℃的90体积％蒸馏温度，通过与 芳族生产催化剂包括以下步骤：将油原料引入到容纳芳族生产催化剂的裂化和重整反应装置中; 使油原料和芳香族生成催化剂在裂化和重整反应装置的内部彼此接触; 在将油原料引入裂解和重整反应装置中并形成两相气 - 液流之前，预先加热油原料; 将两相气 - 液流分离成气体馏分和液体馏分; 并在裂化和重整反应装置的不同位置引入气体馏分和液体馏分。