摘要:
A converter containing a NOx absorbing and reducing catalyst is disposed in the exhaust passage of an internal combustion engine. The upstream half portion (portion of the inlet side) of the substrate of the NOx absorbing and reducing catalyst in the converter carries the oxygen storage component that absorbs oxygen in the exhaust gas when the air-fuel ratio of the exhaust gas is lean and releases the absorbed oxygen when the air-fuel ratio of the exhaust gas flowing in is rich in addition to carrying the NOx absorbing and reducing catalyst. After NOx is absorbed by the NOx absorbing and reducing catalyst as a result of operating the engine at a lean air-fuel ratio, the engine is operated at a rich air-fuel ratio, so that NOx is released from the NOx absorbing and reducing catalyst and is purified by reduction. Here, oxygen is released from the oxygen storage component carried by the upstream half portion of the substrate and is reacted with the H2 and CO components in the exhaust gas, so that the temperature of the NOx absorbing and reducing catalyst is raised within short periods of time due to the heat of reaction. Therefore, the catalyst exhibits increased activity and the NOx absorbing and reducing catalyst exhibits improved NOx purification capability.
摘要:
An exhaust purifying apparatus for an internal combustion engine includes a catalyst that purifies exhaust gas from the engine, a first passage that allows exhaust gas to flow from the engine to the catalyst, and a second passage that allows exhaust gas to flow from the engine to the catalyst. The first passage includes an accelerated cooling portion whose cross section is designed so that a relatively large quantity of heat is released from the exhaust gas in the first passage, and the second passage has a cross section designed so that a relatively small quantity of heat is released from the exhaust gas in the second passage. The apparatus further includes a flow amount controller that controls amounts of exhaust gas flowing through the first and second passages, such that the amount of exhaust gas flow through the first passage is made larger than that through the second passage when the temperature of exhaust gas emitted from the engine is to be lowered by a relatively large degree before reaching the catalyst, and such that the amount of exhaust gas flow through the second passage is made larger than that through the first passage when the temperature of exhaust gas emitted from the engine is to be lowered by a relatively small degree before reaching the catalyst.
摘要:
An NOx occluding and reducing catalyst is disposed in an exhaust gas passage of an internal combustion engine that operates at a lean air-fuel ratio. When the engine is operating at a lean air-fuel ratio, the NOx occluding and reducing catalyst absorbs NOx in the exhaust gas. To release NOx, the engine is operated at a rich air-fuel ratio so that the exhaust gas flowing into the NOx occluding and reducing catalyst acquires a rich air-fuel ratio. While the engine is operated in a region of moderate lean air-fuel ratios of from the stoichiometric air-fuel ratio to an air-fuel ratio of about 20 at the time when the engine operating air-fuel ratio is changing from a lean air-fuel ratio operation to a rich air-fuel ratio operation, an electronic control unit (ECU) of the engine injects secondary fuel, that does not contribute to combustion, into the cylinders of the engine through the direct cylinder fuel injection valves in the expansion stroke or the exhaust stroke of the cylinders, so that the exhaust gas flowing into the NOx occluding and reducing catalyst acquires a rich air-fuel ratio. This prevents unpurified NOx from flowing out of the NOx occluding and reducing catalyst at the time when the engine operating air-fuel ratio is changed.
摘要:
An exhaust manifold (7) of an engine (1) is connected to a three way (TW) catalyst (8a), and the TW catalyst (8a) is connected to an NH3 adsorbing and oxidizing (NH3-AO) catalyst (10a). The engine (1) performs the lean and the rich engine operations alternately and repeatedly. When the engine (1) performs the rich operation and thereby the exhaust gas air-fuel ratio of the exhaust gas flowing into the TW catalyst (8a) is made rich, NOx in the inflowing exhaust gas is converted to NH3 in the TW catalyst (8a). The NH3 is then adsorbed in the NH3-AO catalyst (10a). Next, when the engine (1) performs the lean operation and thereby the exhaust gas air-fuel ratio of the exhaust gas flowing into the TW catalyst (8a) is made lean, NOx in the exhausted gas passes through the TW catalyst (8a), and flows into the NH3-AO catalyst (10a). At this time, NH3 adsorbed in the catalyst (10a) is desorbed therefrom, and reduces the inflowing NOx.
摘要:
An exhaust gas purification device comprising a three way catalyst, an oxidizing catalyst and a NOx absorbent which are arranged in this order in the exhaust passage. A rich air-fuel mixture is burned in the combustion chamber, and the exhaust gas discharged from the engine is initially introduced into the three way catalyst. Secondary air is fed into the exhaust passage between the three way catalyst and the oxidizing catalyst so that the air-fuel ratio of the exhaust gas flowing into the oxidizing catalyst and the NOx absorbent becomes lean.
摘要:
An adsorbent may be positively regenerate by a technique to remove adhered materials such as soot adhered to the adsorbent so that the durability of the adsorbent is enhanced. To meet this, an exhaust gas purifying apparatus for an internal combustion engine, comprises a path switcher for introducing exhaust gas from the internal combustion engine into at least one of a first exhaust gas path and a second exhaust gas path branched downstream of catalysts, an adsorbent disposed in the first exhaust gas path for adsorbing unburnt gas components contained in the exhaust gas, a recirculating device for recirculating the unburnt gas components separated from the adsorbent to an upstream side of the catalysts, and a temperature elevator for elevating a temperature of the adsorbent after the unburnt gas components separated from the adsorbent has been recirculated by the recirculating device.
摘要:
In an exhaust gas purification device, a No. 1 cylinder of the engine is operated at a rich air-fuel ratio and other cylinders (No. 2 to No. 4) are operated at a lean air-fuel ratio. The exhaust gases from the No. 1 and No. 2 cylinders are mixed with each other to form a rich air-fuel ratio exhaust gas mixture. Further, since the air-fuel ratio of the No. 2 cylinder is lean, the exhaust gas from the No. 2 cylinder contains a relatively large amount of NO.sub.x. This rich air-fuel ratio exhaust gas mixture which contains a relatively large amount of NO.sub.X is supplied to a three-way catalyst. At the three-way catalyst, part of the NO.sub.X in the exhaust gas mixture is converted to NH.sub.3. The exhaust gas mixture flowing out from the three-way catalyst and the lean exhaust gas from the No. 3 and No. 4 flow into a common exhaust gas passage where they mix with each other to form a lean exhaust gas containing NH.sub.3 from the three-way catalyst and NO.sub.X from the No. 3 and No. 4 cylinders. This lean exhaust gas flows into a denitrating catalyst disposed on the common exhaust gas passage in which NO.sub.X in the exhaust gas is reduced by the NH.sub.3.
摘要:
To complete a regeneration process of an adsorbent adsorbing unburnt gas components, for a short period of time without making an operational condition of an internal combustion engine unstable and to prevent an ability of the adsorbent from being degraded, an exhaust gas purifying apparatus includes a first exhaust flow path and a second exhaust flow path branched downstream of the catalyst; a n adsorbent disposed in the first exhaust flow path for adsorbing unburnt gas components contained in the exhaust gas; and a recirculating device for recirculating at least part of the exhaust gas discharged from the adsorbent to an intake side of the internal combustion engine. A operational condition of the internal combustion engine is detected. A recirculation amount of the exhaust gas is changed in accordance with the detected operational condition.
摘要:
An exhaust gas purification device comprising a three way catalyst, an oxidizing catalyst and a NOx absorbent which are arranged in this order in the exhaust passage. A rich air-fuel mixture is burned in the combustion chamber, and secondary air is supplied upstream of the three way catalyst so as to make the air-fuel ratio of the exhaust gas flowing into the three way catalyst a rich air-fuel ratio greater than the air-fuel ratio of the air-fuel mixture burned in the combustion chamber. Further, secondary air is supplied upstream of the oxidizing catalyst to make the air-fuel ratio of the exhaust gas flowing into the oxidizing catalyst and the NOx absorbent slightly leaner than the stoichiometric air-fuel ratio.
摘要:
A moisture adsorbent (32) for adsorbing moisture in exhaust gas and an NOx adsorbent (34) for adsorbing NOx are disposed in a bypass passage (30) for bypassing an exhaust passage (16) of an internal combustion engine (10). When an adsorption operation to the NOx adsorbent (34) is executed, inflow of the exhaust gas to the bypass passage (30) is allowed until the moisture amount that flows into the water adsorbent (32) reaches an allowable moisture inflow amount. The allowable moisture inflow amount is determined based on a residual moisture amount before the starting of the adsorption operation in the moisture adsorbent (32). The residual moisture amount in the water adsorbent (32) can be determined based on the temperature of the moisture adsorbent (32) at the immediately preceding execution of the purge operation.