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公开(公告)号：US06156835A
公开(公告)日：2000-12-05
申请号：US117768
申请日：1998-08-05
IPC分类号： C08J5/18 , B29C70/06 , C08G59/42 , C08G59/50 , C08J9/00 , C08K3/34 , C08K9/04 , C08K13/06 , C08L63/00 , C08L67/00 , C08L71/00 , C09C3/10 , C09D163/00 , C09D167/00 , C09D171/00 , C09J163/00 , C09J167/00 , C09J171/00
CPC分类号： C09D167/00 , C08G59/42 , C08G59/50 , C08K3/34 , C08K9/04 , C08L71/00 , C09J167/00
摘要： A polymer composite comprising a hydroxy-phenoxyether or polyester polymer matrix having dispersed therein layers of an inorganic material derived from a multilayered inorganic material having organophilic properties. The dispersion of the multilayered inorganic material in the polymer matrix is such that an increase in the average interlayer spacing of the layered inorganic material occurs. This increase in interlayer spacing occurs to a significant extent resulting in the formation of a nanocomposite. The polymers are preferably derived from a diglycidyl ether or ester or an epihalohydrin and a dinucleophile such as a dicarboxylic acid, a difunctional amine, a bisphenol or a sulfonamide. As the organophilic inorganic material clay minerals modified with organic ammonium compounds are used.
摘要翻译： PCT No.PCT / US97 / 23861 Sec。 371日期：1998年8月5日 102（e）日期1998年8月5日PCT 1997年12月22日PCT公布。 第WO98 / 29491号公报 日期1998年7月9日一种包含羟基 - 苯氧基醚或聚酯聚合物基质的聚合物复合材料，其分散有由具有亲有性质的多层无机材料衍生的无机材料层。 多层无机材料在聚合物基质中的分散体使得层状无机材料的平均层间距的增加发生。 层间间隔的这种增加在很大程度上发生，导致形成纳米复合材料。 聚合物优选衍生自二缩水甘油醚或酯或表卤代醇和二亲核体如二羧酸，双官能胺，双酚或磺酰胺。 由于使用有机铵化合物改性的亲有机无机材料粘土矿物。
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公开(公告)号：US06287992B1
公开(公告)日：2001-09-11
申请号：US09062915
申请日：1998-04-20
IPC分类号： B32B300
CPC分类号： C08K9/08 , C08G59/1461 , Y10T442/20 , Y10T442/2025 , C08L67/06 , C08L63/00
摘要： A polymer composite comprising an epoxy vinyl ester resin or unsaturated polyester matrix having dispersed therein particles derived from a multilayered inorganic material which possesses organophilic properties. The dispersion of the multilayered inorganic material in the polymer matrix is such that an increase in the average interlayer spacing of the layered inorganic material occurs to a significant extent resulting in the formation of a nanocomposite.
摘要翻译： 一种聚合物复合材料，其包含环氧乙烯基酯树脂或不饱和聚酯基质，其分散有衍生自具有亲有机性的多层无机材料的颗粒。多层无机材料在聚合物基质中的分散体使得平均层间距的增加 层状无机材料在很大程度上发生导致形成纳米复合材料。
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公开(公告)号：US20130178591A1
公开(公告)日：2013-07-11
申请号：US13814807
申请日：2011-09-22
IPC分类号： C08G63/672
CPC分类号： C08G63/672 , C08G59/066 , C08G59/186 , C08G63/181 , C08L63/00 , C08L2205/05 , C08L33/04 , C08L67/00
摘要： A poly epoxy ester resin composition of the following chemical structure: where n is a number from 2 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical), Ar is a divalent aryl group or heteroarylene group;_and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
摘要翻译： 具有以下化学结构的聚环氧酯树脂组合物：其中n为2至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基（饱和二价脂族烃基），Ar为二价芳基或亚杂芳基; X为亚环烷基，包括取代的亚环烷基，其中取代基包括烷基， 环烷基，芳基或芳烷基或其它取代基，例如卤素，硝基，封端异氰酸酯或烷氧基; 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。
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公开(公告)号：US20130178584A1
公开(公告)日：2013-07-11
申请号：US13816772
申请日：2011-09-20
IPC分类号： C09D167/02
CPC分类号： C09D167/025 , C08G59/066 , C08G59/4223 , C08L2205/05 , C09D163/00 , C09D167/02 , C08L33/02 , C08L67/00
摘要： A coating composition comprising an advanced poly epoxy ester resin polymeric composition having the following chemical structure: where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); Ar is a divalent aromatic fused-ring moiety, which is most preferably a divalent naphthalene group, substituted divalent naphthalene group, where the substitute groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent; and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
摘要翻译： 一种涂料组合物，其包含具有以下化学结构的先进的聚环氧酯树脂聚合物组合物：其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基（饱和二价脂族烃基）; Ar是二价芳香稠环部分，其中最优选二价萘基，取代二价萘基，其中取代基包括烷基，环烷基，芳基或芳烷基或其它取代基; X是亚环烷基，包括取代的亚环烷基，其中取代基包括烷基，环烷基，芳基或芳烷基或其它取代基，例如卤素，硝基，封端异氰酸酯或烷氧基; 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。
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公开(公告)号：US07745652B2
公开(公告)日：2010-06-29
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C07C51/43
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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公开(公告)号：US07678872B2
公开(公告)日：2010-03-16
申请号：US12165867
申请日：2008-07-01
申请人： Terry W. Glass , William J. Harris , Jerry E. White , Mike Cavitt , David C. Jammer , Louis A. Willy, Jr.
发明人： Terry W. Glass , William J. Harris , Jerry E. White , Mike Cavitt , David C. Jammer , Louis A. Willy, Jr.
CPC分类号： C08G73/06 , C08G59/066 , C08G73/024 , C08G73/0273 , C08G2650/56 , C08L71/00
摘要： A water soluble polymer comprising a copolyhydroxyaminoether having side-chains of polyalkylene oxides, an aqueous solution of said polymer and process for preparing the copolyhydroxyaminoether.
摘要翻译： 包含具有聚亚烷基氧化物侧链的共聚羟基氨基醚的水溶性聚合物，所述聚合物的水溶液和制备共聚羟基氨基醚的方法。
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公开(公告)号：US20080287595A1
公开(公告)日：2008-11-20
申请号：US10589713
申请日：2005-03-24
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L63/00 , C08L63/10 , C08L67/06 , C09D5/033 , C09D153/00 , C09D167/06 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： A composition comprising (1) a thermosettable resin selected from the group consisting of an epoxy resin, an epoxy vinyl ester resin, an unsaturated polyester resin or a mixture thereof, and (2) an amphiphilic mock copolymer dispersed in the thermosettable resin; fiber-reinforced plastics (FRP), coatings and composites prepared therefrom; and methods of preparing these.
摘要翻译： 一种组合物，其包含（1）选自环氧树脂，环氧乙烯基酯树脂，不饱和聚酯树脂或其混合物的热固性树脂，和（2）分散在所述可热固化树脂中的两亲模拟共聚物; 纤维增强塑料（FRP），由其制备的涂料和复合材料; 及其制备方法。
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公开(公告)号：US06589621B1
公开(公告)日：2003-07-08
申请号：US09108620
申请日：1998-07-01
申请人： John M. Beckerdite , Terry W. Glass , Joe F. Sanford , David S. Wang , Jerry E. White , Peter T. Keillor, III , Thomas E. Moseman
发明人： John M. Beckerdite , Terry W. Glass , Joe F. Sanford , David S. Wang , Jerry E. White , Peter T. Keillor, III , Thomas E. Moseman
IPC分类号： B29D2200
CPC分类号： C08G73/024 , C08G59/64 , Y10T428/1352 , Y10T428/1397
摘要： Compositions comprising a blend of an inorganic base, an organic base, a monofunctional organic nucleophile or a multifunctional organic nucleophile and a thermoplastic hydroxy-functionalized polyetheramine can be formed into films and laminate structures by using conventional extrusion techniques. Containers and other molded parts can be fabricated from the films or laminate structures by using conventional fabricating techniques for thermoplastic polymers such as compression molding, injection molding, extrusion, thermoforming, blow molding and solvent casting.
摘要翻译： 通过使用常规挤出技术，可以将包含无机碱，有机碱，单官能有机亲核试剂或多官能有机亲核试剂和热塑性羟基官能化聚醚胺的混合物的组合物形成为膜和层压结构。 通过使用常规的热塑性聚合物的制造技术，例如压塑，注射成型，挤出，热成型，吹塑和溶剂浇铸，可以通过膜或层压结构来制造容器和其它模塑部件。
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公开(公告)号：US5686551A
公开(公告)日：1997-11-11
申请号：US179029
申请日：1994-01-07
IPC分类号： C08G59/14 , C08G59/24 , C08G59/42 , C08G59/44 , C08G59/50 , C08G59/62 , C08G59/66 , C08G59/10 , C08G59/20 , C08G65/14
CPC分类号： C08G59/66 , C08G59/1433 , C08G59/245 , C08G59/42 , C08G59/444 , C08G59/50 , C08G59/621
摘要： Thermoplastic hydroxy ether polymers containing inertly substituted or unsubstituted stilbene and ether linkages in the backbone chain and pendant hydroxyl moieties are prepared by reacting (a) an inertly substituted or unsubstituted dihydroxy-stilbene with (b) a diglycidyl ether and, optionally, (c) a difunctional monomer under conditions sufficient to cause the hydroxyl moieties to react with the epoxy moieties to form ether linkages and pendant hydroxyl moieties. The polymers exhibit excellent oxygen barrier properties and are useful in packaging oxygen-sensitive materials.
摘要翻译： 通过使（a）惰性取代或未取代的二羟基 - 二苯乙烯与（b）二缩水甘油醚和任选地（c）的二缩水甘油醚反应，制备在主链和侧羟基部分含惰性取代或未取代的二苯乙烯和醚键的热塑性羟基醚聚合物， 双官能单体在足以使羟基部分与环氧部分反应以形成醚键和侧羟基部分的条件下进行。 聚合物表现出优异的氧气阻隔性能，并且可用于包装氧敏感材料。
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10.发明授权Amide and hydroxymethyl functionalized polyethers as thermoplastic barrier resins 失效酰胺和羟甲基官能化聚醚作为热塑性阻隔树脂
公开(公告)号：US5115075A
公开(公告)日：1992-05-19
申请号：US520689
申请日：1990-05-08
IPC分类号： C07C235/34 , C07D303/24 , C08G59/62
CPC分类号： C08G59/621 , C07C235/34 , C07D303/24
摘要： Polyethers having improved barrier to oxygen are normally solid, thermoplastic polyethers having aromatic ether repeating units in their backbones and pendent hydroxyl moieties and pendent amido, N-substituted amido and/or hydroxyalkyl moieties. Such polyethers are prepared by reacting diglycidyl ethers of dihydric aromatic compounds such as diglycidyl ether of bisphenol A with dihydric phenols having pendent amido, N-substituted amido and/or hydroxyalkyl moieties such as 2,2-bis(4-hydroxyphenyl)acetamide and 3,5-dihydroxybenzamide.
摘要翻译： 具有改善的对氧的屏障的聚醚通常是固体，其主链中具有芳族醚重复单元的热塑性聚醚和侧挂的羟基部分以及侧链酰胺基，N-取代的酰胺基和/或羟烷基部分。 这样的聚醚通过使二羟基芳族化合物的二缩水甘油醚如双酚A的二缩水甘油醚与具有侧枝酰氨基的二元酚，N-取代的酰氨基和/或羟烷基部分如2,2-双（4-羟基苯基）乙酰胺和3 ，5-二羟基苯甲酰胺。
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