公开(公告)号：US20160090537A1

公开(公告)日：2016-03-31

申请号：US14867415

申请日：2015-09-28

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Kshudiram MANTRI ,  Chidambaram MANDAN ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: C10G1/06 ,  C10B53/02 ,  C10B57/12

CPC classification number: C10G1/065 ,  C10G1/083 ,  C10G1/086 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1014 ,  Y02E50/14 ,  Y02P30/20

Abstract: The present disclosure relates to a process for the production of crude bio-oil which involves heating a mixture of biomass slurry and a mixed catalyst system in the presence of a hydrogen source at a temperature ranging from 200 to 350° C. and at a pressure ranging from 70 to 250 bars to obtain a mass containing crude bio-oil. The crude bio-oil can then be separated from said mass containing crude bio-oil. The mixed catalyst system remains in solid form and can be easily separated and reused in the next cycle of hydrothermal conversion of biomass to crude bio-oil.

Abstract translation: 本公开涉及一种生产粗生物油的方法，其包括在氢源存在下，在200-350℃的温度和压力下加热生物质浆料和混合催化剂体系的混合物 范围为70至250巴，以获得含有粗生物油的质量。 然后将粗生物油与所述含有粗生物油的物质分离。 混合催化剂体系保持固体形式，并且可以在下一个生物质水热转化为粗生物油的循环中容易地分离和重新使用。

公开(公告)号：US20170216829A1

公开(公告)日：2017-08-03

申请号：US15302079

申请日：2015-07-17

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chudasama CHINTANSINH DHARMENDRASINH ,  Sachin RAWALEKAR ,  Sunil AGRAHARI ,  Kalpana GOPALAKRISHNAN ,  Katravulapalli VEERA VENKATA BHASKARA SITA RAMA MURTHY ,  Ajay KUMAR ,  Anilkumar METTU ,  Nagesh SHARMA ,  Raksh VIR JASRA

IPC: B01J33/00 ,  B01J37/02 ,  B01J23/62 ,  B01J21/04 ,  B01J23/656

CPC classification number: B01J33/00 ,  B01J21/04 ,  B01J23/42 ,  B01J23/54 ,  B01J23/626 ,  B01J23/6567 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/0219 ,  B01J37/0221 ,  C10G35/09 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2400/30

Abstract: The present disclosure relates to a process and system for modifying heterogeneous catalysts by contacting them with chemical compounds. Specifically, the present disclosure relates to an easy and convenient process for surface functionalizing of a heterogeneous catalyst such as polymetallic catalyst including bimetallic catalyst by employing precursor of inorganic compound, wherein the precursor is organometallic compound and wherein the inorganic compound includes but is not limited to a metal based inorganic compound such as aluminium oxide. The present disclosure thus provides for easy and convenient process and system for surface modification/functionalization of heterogeneous catalysts by employing precursor of inorganic compound at conditions including but not limiting to room temperature and atmospheric pressure.

公开(公告)号：US20150329789A1

公开(公告)日：2015-11-19

申请号：US14796335

申请日：2015-07-10

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chidambaram MANDAN ,  Kshudiram MANTRI ,  Supriya APEGAONKAR ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: C10G3/00 ,  C10G1/00

CPC classification number: C10G3/00 ,  B01J21/04 ,  B01J21/066 ,  B01J23/464 ,  B01J23/882 ,  B01J23/883 ,  B01J27/16 ,  B01J29/041 ,  B01J29/045 ,  B01J37/0203 ,  B01J37/036 ,  C10G1/00 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10L1/326 ,  C10L9/086 ,  Y02P30/20

Abstract: The present disclosure relates to a process for the production of bio-oil which involves heating a mixture of a biomass slurry and a first catalyst composition at a temperature ranging from 200 to 350° C. and at a pressure ranging from 70 to 250 bars to obtain a mass containing crude bio oil, a residue and the catalyst; separating the crude bio oil from said mass to obtain a separated crude bio oil; extracting said separated crude bio oil with at least one solvent and evaporating said solvent to obtain a solvent free crude bio oil; subjecting said solvent free crude bio oil to reduction in the presence of a second catalyst composition and hydrogen source at temperature and pressure conditions similar to those employed for the conversion of bio mass into crude bio oil to obtain bio-oil. The second catalyst composition is the same as that of the first catalyst composition. The process also comprises a method step of recovering the first catalyst and reusing it either for preparing crude bio oil or bio oil or both.

Abstract translation: 本公开涉及一种用于生产生物油的方法，其涉及在200-350℃和70-250巴的压力范围内加热生物质浆料和第一催化剂组合物的混合物， 获得含有粗生物油，残余物和催化剂的物质; 将粗生物油与所述物质分离以获得分离的粗生物油; 用至少一种溶剂萃取所述分离的粗制生物油并蒸发所述溶剂以获得无溶剂的粗生物油; 在第二催化剂组合物和氢源的存在下，使所述无溶剂的粗生物油在与用于将生物质量转化为粗生物油以获得生物油的温度和压力条件类似的温度和压力条件下进行还原。 第二催化剂组合物与第一催化剂组合物相同。 该方法还包括回收第一催化剂并将其用于制备粗生物油或生物油或二者的方法步骤。

公开(公告)号：US20190083961A1

公开(公告)日：2019-03-21

申请号：US16186118

申请日：2018-11-09

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chidambaram MANDAN ,  Kshudiram MANTRI ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: B01J27/19 ,  B01J37/02 ,  B01J37/16 ,  C10G3/00 ,  B01J37/08 ,  B01J37/18 ,  B01J37/20 ,  B01J37/28 ,  B01J23/00 ,  B01J23/882 ,  B01J23/887 ,  B01J27/051 ,  B01J35/00 ,  B01J35/10

Abstract: The present disclosure provides a multi-metallic catalyst system comprising at least one support, and at least one promoter component and an active component comprising at least two metals uniformly dispersed on the support. The present disclosure also provides a process for preparing the multi-metallic catalyst system. Further, the present disclosure provides a process for preparing upgraded fuel from biomass. The process is carried out in two steps. In the first step, a biomass slurry is prepared and is heated in the presence of hydrogen and a multi-metallic catalyst that comprises at least one support, at least one promoter component, and an active component comprising at least two metals to obtain crude biofuel as an intermediate product. The intermediate product obtained in the first step is then cooled and filtered to obtain a filtered intermediate product. In the second step, the filtered intermediate product is hydrogenated in the presence of the multi-metallic catalyst to obtain the upgraded fuel. The fuel obtained from the process of the present disclosure is devoid of heteroatoms such as oxygen, nitrogen and sulfur.

公开(公告)号：US20170021341A1

公开(公告)日：2017-01-26

申请号：US15135054

申请日：2016-04-21

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chidambaram MANDAN ,  Kshudiram MANTRI ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: B01J27/19 ,  B01J23/882 ,  B01J37/20 ,  B01J37/02 ,  B01J37/16 ,  C10G3/00 ,  B01J37/08

CPC classification number: B01J27/19 ,  B01J23/002 ,  B01J23/882 ,  B01J23/8877 ,  B01J27/0515 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08 ,  B01J37/16 ,  B01J37/18 ,  B01J37/20 ,  B01J37/28 ,  B01J2523/00 ,  C10G3/44 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/202 ,  Y02P30/20 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/821 ,  B01J2523/845 ,  B01J2523/56

Abstract: The present disclosure provides a multi-metallic catalyst system comprising at least one support, and at least one promoter component and an active component comprising at least two metals uniformly dispersed on the support. The present disclosure also provides a process for preparing the multi-metallic catalyst system. Further, the present disclosure provides a process for preparing upgraded fuel from biomass. The process is carried out in two steps. In the first step, a biomass slurry is prepared and is heated in the presence of hydrogen and a multi-metallic catalyst that comprises at least one support, at least one promoter component, and an active component comprising at least two metals to obtain crude biofuel as an intermediate product. The intermediate product obtained in the first step is then cooled and filtered to obtain a filtered intermediate product. In the second step, the filtered intermediate product is hydrogenated in the presence of the multi-metallic catalyst to obtain the upgraded fuel. The fuel obtained from the process of the present disclosure is devoid of heteroatoms such as oxygen, nitrogen and sulfur.

Abstract translation: 本公开内容提供了包含至少一种载体和至少一种促进剂组分和包含均匀分散在载体上的至少两种金属的活性组分的多金属催化剂体系。 本公开还提供了制备多金属催化剂体系的方法。 此外，本公开提供了一种从生物质制备升级燃料的方法。 该过程分两步进行。 在第一步骤中，制备生物质浆料并在氢气和多金属催化剂的存在下加热，所述多金属催化剂包含至少一种载体，至少一种助催化剂组分和包含至少两种金属的活性组分以获得粗生物燃料 作为中间产品。 然后将在第一步骤中获得的中间产物冷却并过滤以获得过滤的中间产物。 在第二步中，过滤的中间产物在多金属催化剂的存在下氢化以获得升级的燃料。 从本公开的方法获得的燃料没有杂原子，例如氧，氮和硫。

公开(公告)号：US20170247619A1

公开(公告)日：2017-08-31

申请号：US15596638

申请日：2017-05-16

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Kshudiram MANTRI ,  Mandan CHIDAMBARAM ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: C10G1/10 ,  C10G1/06

CPC classification number: B01J21/04 ,  B01J21/066 ,  B01J23/464 ,  B01J23/882 ,  B01J23/883 ,  B01J27/24 ,  B01J29/85 ,  B01J31/0237 ,  B01J31/26 ,  B01J31/38 ,  B01J35/02 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/08 ,  B01J2231/005 ,  B01J2531/005 ,  B01J2531/008 ,  C10B57/12 ,  C10G1/00 ,  C10G1/06 ,  C10G1/10 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/02 ,  C10L9/086 ,  Y02E50/14 ,  Y02P30/20

Abstract: The present disclosure provides a process for preparing a hydrocarbon fuel from waste rubber. The process involves admixing, in a reaction vessel, at least one fluid medium with the waste rubber to obtain a slurry; wherein the concentration of the waste rubber in the slurry ranges from 45% to 70%. A reactor is charged with the slurry and a predetermined amount of at least one catalyst composition to obtain a mixture, followed by introduction of hydrogen to the reactor to attain a predetermined pressure and heating the mixture at a predetermined temperature, to attain an autogenously generated pressure, and for a predetermined time period to obtain a reaction mass comprising the hydrocarbon fuel. This reaction mass comprising the hydrocarbon fuel is then cooled to obtain a cooled reaction mass. The hydrocarbon fuel is then separated from the cooled reaction mass.

公开(公告)号：US20170106352A1

公开(公告)日：2017-04-20

申请号：US15285127

申请日：2016-10-04

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Nagesh SHARMA ,  Ajay Kumar ,  Katravulapalli VEERA VENKATA SATYA BHASKARA SITA RAMA MURTHY ,  Anilkumar METTU ,  Kalpana GOPALAKRISHNAN ,  Raksh VIR JASRA

IPC: B01J23/62 ,  B01J23/02 ,  B01J37/02 ,  C10G11/04 ,  B01J37/08 ,  B01J37/22 ,  B01J23/10 ,  B01J21/10

CPC classification number: B01J23/626 ,  B01J21/10 ,  B01J23/002 ,  B01J23/02 ,  B01J23/10 ,  B01J23/58 ,  B01J23/63 ,  B01J27/135 ,  B01J27/138 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/18 ,  B01J37/22 ,  B01J37/24 ,  C10G11/04 ,  C10G35/09 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2400/02 ,  C10G2400/30 ,  B01J2523/00 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/43 ,  B01J2523/828 ,  B01J2523/25 ,  B01J2523/3706

Abstract: The present disclosure relates to a composition, wherein the composition is a catalyst comprising support matrix, active metal, promoter metal and halide, wherein the support matrix is additionally subjected to a modifier to obtain a modified support matrix. The catalyst in the reaction reduces the percentage coke formation and provides for an enhanced reformate yield having an increase total aromatic yield and C8 aromatic yield when compared to the known/commercially available catalyst for naphtha reforming process, and also improves the quality of reformate obtained at end of the reaction. The disclosure further relates to process of preparation of the catalyst, the catalyst of the present disclosure derived from the process described, displays lower deactivation during the reaction demonstrating increased stability and reduction in the regeneration frequency and thereby making the catalyst economically feasible.

公开(公告)号：US20160130504A1

公开(公告)日：2016-05-12

申请号：US14982624

申请日：2015-12-29

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Badrish Ranjitlal SONI ,  Mandan CHIDAMBARAM ,  Kshudiram MANTRI ,  Vijayakumar VINODHKUMAR ,  Sasanka RAHA ,  Venkatesh PRASAD ,  Ramesh BHUJADE ,  Santanu DASGUPTA ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: C10B53/02 ,  C10B57/06 ,  B01J21/04 ,  B01J23/28 ,  B01J23/75

CPC classification number: C10G1/10 ,  B01J21/04 ,  B01J21/066 ,  B01J23/464 ,  B01J23/882 ,  B01J23/883 ,  B01J27/24 ,  B01J29/85 ,  B01J31/0237 ,  B01J31/26 ,  B01J31/38 ,  B01J35/02 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/08 ,  B01J2231/005 ,  B01J2531/005 ,  B01J2531/008 ,  C10B57/12 ,  C10G1/00 ,  C10G1/06 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/02 ,  C10L9/086 ,  Y02E50/14 ,  Y02P30/20

Abstract: The present disclosure relates to a process for the conversion of biomass to crude bio-oil. Phycocyanin is extracted from the biomass to form phycocyanin extracted biomass (PEB) and subjecting the PEB to HTL conversion to obtain crude bio-oil. PEB results in improved yield of crude bio-oil as compared to the crude bio-oil yield from biomass without first extracting the phycocyanin from the biomass.

Abstract translation: 本公开涉及将生物质转化为粗生物油的方法。 从生物质中提取藻蓝蛋白以形成藻蓝蛋白提取的生物质（PEB），并使PEB进行HTL转化以获得粗生物油。 与来自生物质的首先从生物质中提取藻蓝蛋白相比，生物油粗产率提高了生物油的粗产率。

公开(公告)号：US20150306575A1

公开(公告)日：2015-10-29

申请号：US14652283

申请日：2014-05-08

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chidambaram MANDAN ,  Kshudiram MANTRI ,  Supriya APEGAONKAR ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh JASRA

IPC: B01J23/883 ,  B01J27/24 ,  B01J31/26 ,  B01J29/85 ,  B01J23/882 ,  B01J23/46 ,  B01J21/04 ,  B01J21/06 ,  B01J31/38 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  C10G1/00 ,  C10B57/12 ,  B01J31/02

CPC classification number: B01J23/883 ,  B01J21/04 ,  B01J21/066 ,  B01J23/464 ,  B01J23/882 ,  B01J27/24 ,  B01J29/85 ,  B01J31/0237 ,  B01J31/26 ,  B01J31/38 ,  B01J35/02 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/08 ,  B01J2231/005 ,  B01J2531/005 ,  B01J2531/008 ,  C10B57/12 ,  C10G1/00 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  Y02P30/20

Abstract: The present disclosure provides a catalyst composition for conversion of biomass to crude bio oil. The composition comprises at least one metal compound, at least one support and at least one stabilizing/solubilizing agent. Also disclosed are processes for the preparation of catalyst composition, and hydrothermal conversion of biomass to crude bio oil.

Abstract translation: 本公开提供了用于将生物质转化为粗生物油的催化剂组合物。 组合物包含至少一种金属化合物，至少一种载体和至少一种稳定/增溶剂。 还公开了制备催化剂组合物和将生物质水热转化为粗生物油的方法。