摘要:
A lubricant which is prepared from at least one synthetic ester composition exhibiting thermal and oxidative stability which comprises the reaction product of 3,5,5-trimethyl-1-hexanol and an acid or anhydride; and a lubricant additive package; whereby the incorporation of an antioxidant in the lubricant additive package for the purpose of maintaining oxidative and thermal stability of the crankcase lubricating oil formulation to at least 20 minutes as measured by HPDSC at 220.degree. C., 3.445 MPa air and 0.5 wt. % dioctyl diphenyl amine can be either reduced or eliminated. The synthetic ester composition preferably exhibits the following additional properties: a metals content of 10 ppm or less metals based on the total synthetic ester composition, an ash content of 15 ppm or less ash based on the total synthetic ester composition, a total acid number of 0.05 mg KOH/g or less, and a volume resistivity of at least about 1.times.10.sup.11 ohm cm.
摘要:
A synthetic ester composition exhibiting low odor, and high thermal and oxidative stability which comprises the reaction product of: (a) a polyol which comprises at least dipentaerythritol, e.g., technical grade pentaerythritol and mixtures of technical grade pentaerythritol or dipentaerythritol and monopentaerythritol; and (b) a mixture of monocarboxylic acids comprising at least one linear acid selected from the group consisting of between C5-C10 acids and at least one branched acid selected from the group consisting of C7-C9 acids, wherein the amount of C5 and C6 acids is between about 20 to 45 weight %, based upon the total amount of said mixture of monocarboxylic acids, and wherein said synthetic ester composition has a viscosity of at least 4 cSt at 99° C., a viscosity of less than about 8,000 cSt at 40° C., and a pour point of at least as low as −54° C.
摘要:
A complex alcohol ester which comprises the reaction product of an add mixture of the following: a polyhydroxyl compound represented by the general formula: R(OH).sub.n wherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a pour point of less than or equal to -20.degree. C., a viscosity in the range between about 100-700 cSt at 40.degree. C. and having a polybasic acid ester concentration of less than or equal to 70 wt. %, based on the complex alcohol ester.
摘要:
A polyol ester distillate fuel additive exhibits improved lubricity and friction and wear performance. The ester has between about 1% and about 35% unconverted hydroxyl groups and is characterized as having a hydroxyl number from about 5 to about 180.
摘要:
An alkylaromatic hydrocarbon composition prepared by the process which comprises oligomerizing an olefin selected from the group consisting of propylene, n-butene and mixtures thereof over an oligomerization catalyst, to form a oligomerization product comprising at least 95% by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprise at least 20% by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.
摘要翻译:通过该方法制备的烷基芳族烃组合物,其包括在低聚催化剂上使选自丙烯,正丁烯及其混合物的烯烃低聚以形成低聚产物,其包含至少95重量%的单烯烃低聚物 经验式:C n H 2n其中n大于或等于10,单烯烃低聚物包含至少20重量%的具有至少12个碳原子的烯烃,并且具有至少12个碳原子的烯烃具有平均为 每个碳链0.8至2.0个C1-C3烷基支链。 烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物,例如生物降解性和冷水和冷水性能。
摘要:
A crankcase engine lubricant which comprises the add mixture of the following components: (A) a lubricating oil which comprises the add mixture of the following components: a complex alcohol ester basestock and at least one additional basestock; and (B) an additive package; wherein the crankcase engine lubricant exhibits a percent fuel economy improvement in the range between about 0.3 to 5.0%, versus the lubricating oil without the complex alcohol ester basestock.
摘要:
In a process for preparing an alkylaromatic hydrocarbon composition an olefinic hydrocarbon mixture and an aromatic compound are contacted under alkylation conditions with an aromatic alkylation catalyst selected from a homogeneous acid catalyst and heterogeneous acid catalyst comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstroms. The olefinic hydrocarbon mixture comprises at least 5 wt % by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprising at least 20 percent by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.
摘要翻译:在制备烷基芳族烃组合物的方法中,烯烃混合物和芳族化合物在烷基化条件下与选自均相酸催化剂的芳族烷基化催化剂和包含具有包括d的X射线衍射图的分子筛的多相酸催化剂接触 最大值为12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃。 烯烃混合物包含至少5重量%的经验式为C n H 2n的单烯烃低聚物,其中n大于或等于10,单烯烃低聚物包含至少20重量%的至少具有至少20重量% 12个碳原子,并且具有至少12个碳原子的烯烃在每个碳链上平均具有0.8至2.0个C 1 -C 3烷基支链。 烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物,例如生物降解性和冷水和冷水性能。
摘要:
In a process for preparing an olefinic hydrocarbon mixture comprising at least 5% by weight of mono-olefin oligomers of the empirical formula: CnH2n where n is greater than or equal to 6, a feedstock comprising n-butene and propylene in a molar ratio of about 1:0.01 to about 1:0.49 is contacted under oligomerization conditions with surface deactivated ZSM-23. The resultant mono-olefin oligomers comprise at least 20 percent by weight of olefins having at least 12 carbon atoms, wherein said olefins having at least 12 carbon atoms have an average of from about 0.8 to about 2.0 C1–C3 alkyl branches per carbon chain.
摘要:
A lubricating oil comprising an add mixture of the following components: (A) a complex alcohol ester basestock which comprises the reaction product of an add mixture of the following: (1) a polyhydroxyl compound represented by the general formula:R(OH).sub.nwherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; (2) a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and (3) a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a viscosity in the range between about 100-700 cSt at 40.degree. C. and having a polybasic acid ester concentration of less than or equal to 70 wt. %, based on the complex alcohol ester; and (B) at least one additional basestock.
摘要:
A biodegradable two-cycle lubricant which is prepared from an add mixture of: (1) a biodegradable lubricating oil comprising an add mixture of the following components: a complex alcohol ester basestock which comprises the reaction product of an add mixture of the following: a polyhydroxyl compound represented by the general formula:R(OH).sub.nwherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a viscosity in the range between about 100-700 cSt at 40.degree. C. and has a polybasic acid ester concentration of less than or equal to 70 wt. %, based on the complex alcohol ester; and at least one additional basestock, wherein the biodegradable lubricating oil exhibits biodegradability of greater than 60% as measured by the Sturm test; and (2) an additive package.