Process for the preparation of 4,4'-dinitrodibenzyls
    1.
    发明授权
    Process for the preparation of 4,4'-dinitrodibenzyls 失效
    制备4,4'-二硝基二苄基的方法

    公开(公告)号:US4734532A

    公开(公告)日:1988-03-29

    申请号:US871018

    申请日:1986-06-04

    CPC分类号: C07C201/12

    摘要: 4,4'-dinitrodibenzyls are prepared by reaction of 4-nitrotoluenes, in the presence of an organic solvent and/or diluent, with an alkali metal-alcoholate and/or an alkaline earth metal alcoholate, and subsequent treatment of the reaction mixture with an aqueous solution of hypohalous acids and/or their salts or with chlorine, bromine or an aqueous solution of hydrogen peroxide and/or its salts, or with organic or inorganic peracids and/or their salts.

    摘要翻译: 4,4'-二硝基二苄基通过4-硝基甲苯在有机溶剂和/或稀释剂存在下与碱金属醇盐和/或碱土金属醇化物反应制备,随后用反应混合物处理 次卤酸和/或其盐的水溶液或氯,溴或过氧化氢和/或其盐的水溶液,或与有机或无机过酸和/或其盐的水溶液。

    Process for the preparation of low molecular weight
4,4'-diphenylmethane-uretdione-diisocyanates
    7.
    发明授权
    Process for the preparation of low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates 失效
    制备低分子量4,4'-二苯基甲烷 - 二酮二异氰酸酯的方法

    公开(公告)号:US4521338A

    公开(公告)日:1985-06-04

    申请号:US404106

    申请日:1982-08-02

    CPC分类号: C07D229/00 C08G18/798

    摘要: Low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates corresponding to the formula: ##STR1## wherein n is a number from 0 to 1,are made by dimerizing diphenylmethane-4,4'-diisocyanate at a temperature of 50.degree. C. or less in a mixture of non-polar and moderately polar solvents in the presence of a dimerization catalyst. The dimerization product may then be worked up at low temperatures (i.e., .ltoreq.50.degree. C.). The dimerization products of diphenylmethane-diisocyanate thus obtained generally have only a small amount of oligomeric uretdione-diisocyanates present. These dimerization products may be used advantageously in the synthesis of polyurethanes.

    摘要翻译: 对应于下式的低分子量4,4'-二苯基甲烷 - 脲二酮 - 二异氰酸酯:其中n为0至1的数,通过二苯基甲烷-4,4'- 二异氰酸酯在50℃或更低的温度下在非极性和中等极性溶剂的混合物中在二聚催化剂存在下进行。 然后可以在低温下(即

    Aromatic diisocyanates containing N,N-disubstituted sulfonamide groups
and processes for their production
    8.
    发明授权
    Aromatic diisocyanates containing N,N-disubstituted sulfonamide groups and processes for their production 失效
    含有N,N-二取代磺酰胺基团的芳族二异氰酸酯及其制备方法

    公开(公告)号:US4496491A

    公开(公告)日:1985-01-29

    申请号:US401036

    申请日:1982-07-22

    CPC分类号: C07D295/26 C08G18/775

    摘要: Diisocyanates corresponding to the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 (an isocyanate-containing radical) are as defined herein are made by several processes. These diisocyanates may be made by phosgenating the diamine in which the diisocyanate is based. They may also be produced by treating the bis-urethane of the tertiary alcohol corresponding to the diisocyanate with phosgene. Such diisocyanates may also be made by treating a specific type of bis-urea with hydrogen chloride. The diisocyanates corresponding to the above-given formula are particularly useful in the production of polyurethanes having good flame-proof and mechanical properties.

    摘要翻译: 其中R 1,R 2,R 3,R 4,R 5和R 6(含异氰酸酯的基团)如本文所定义的式“IMAGE”的二异氰酸酯通过几种方法制备。 这些二异氰酸酯可以通过使二异氰酸酯所基于的二胺光气化而制成。 它们也可以通过用光气处理对应于二异氰酸酯的叔醇的双 - 氨基甲酸酯来制备。 这种二异氰酸酯也可以通过用氯化氢处理特定类型的双脲来制备。 对应于上述给定配方的二异氰酸酯特别可用于生产具有良好的阻燃和机械性能的聚氨酯。

    Heat curable, one-component polyurethane reactive compositions
    10.
    发明授权
    Heat curable, one-component polyurethane reactive compositions 失效
    可热固化的单组分聚氨酯反应组合物

    公开(公告)号:US5574123A

    公开(公告)日:1996-11-12

    申请号:US396182

    申请日:1995-02-24

    摘要: The present invention relates to a heat curable, one-component polyurethane reactive compositions containingA) surface-modified, finely divided polyisocyanates in which 0.1 to 25 equivalent percent, based on the total number of NCO groups, of the NCO groups are deactivated andB) a mixture of relatively high molecular weight compounds having isocyanate-reactive groups containing1) 5 to 40 wt. %, based on the weight of component B), of one or more aliphatic polyether polyamines and2) 60 to 95 wt. %, based on the weight of component B), of a polyol mixture containingi) 10 to 60 wt. %, based on the weight of component B2), of at least one polyester polyol andii) 40 to 90 wt. %, based on the weight of component B2), of at least one polyether polyol with predominantly primary hydroxyl groups.The present invention also relates to use of the heat curable, one-component polyurethane reactive compositions to prepare coatings, adhesives, anti-drumming products and sealants, especially seam sealants.

    摘要翻译: 本发明涉及一种可热固化的单组分聚氨酯反应性组合物,其包含A)表面改性的细碎多异氰酸酯,其中NCO基团的NCO基团的总数为0.1至25当量百分数为失活,B为 )具有异氰酸酯反应性基团的相对高分子量化合物的混合物,其含有1〜5重量% 基于组分B)的重量),一种或多种脂族聚醚多胺,和2)60至95重量% 基于组分B)的重量,多元醇混合物含有i)10至60wt。 %,基于组分B2的重量),至少一种聚酯多元醇,和ii)40至90重量% 至少一种主要为伯羟基的聚醚多元醇,基于组分B2的重量%)。 本发明还涉及可热固化的单组分聚氨酯反应性组合物用于制备涂料,粘合剂,抗打击产品和密封剂,特别是缝隙密封剂的用途。