公开(公告)号：US20080299430A1

公开(公告)日：2008-12-04

申请号：US11571010

申请日：2005-06-21

申请人： Satoru Ichikawa ,  Masahiro Yamamoto ,  Norihisa Waki

发明人： Satoru Ichikawa ,  Masahiro Yamamoto ,  Norihisa Waki

IPC分类号： H01M8/10 ,  H01M4/86

CPC分类号： H01M8/0239 ,  H01M4/8605 ,  H01M4/8636 ,  H01M4/8657 ,  H01M8/0234 ,  H01M8/1007

摘要： A gas diffusion electrode includes: an electrode catalyst layer 13; microporous layers 11 and 12 arranged on the electrode catalyst layer 13 and including at least two layers which are second and first microporous layers 12 and 11 formed of materials having different water repellencies, wherein the second microporous layer 12 disposed on the electrode catalyst layer 13 side is composed to have higher water repellency than the first microporous layer 11; and an oxidant gas diffusion substrate 10 disposed on the microporous layers 11 and 12 and formed of carbon fiber. According to the gas diffusion electrode of the present invention, drainability of generated water from the electrode catalyst layer to the gas diffusion layer and moisture retention and gas diffusibility of the electrode catalyst layer can be enhanced. Moreover, according to a solid polymer electrolyte fuel cell of the present invention, stable power generation characteristics can be obtained even under an operating condition with wide humidity range and current density range.

摘要翻译： 气体扩散电极包括：电极催化剂层13; 布置在电极催化剂层13上并且包括至少两层的微孔层11和12是由具有不同防水性的材料形成的第二和第一微孔层12和11，其中设置在电极催化剂层13侧的第二微孔层12 被构成为具有比第一微孔层11更高的拒水性; 以及设置在微孔层11和12上并由碳纤维形成的氧化剂气体扩散基板10。 根据本发明的气体扩散电极，可以提高从电极催化剂层到气体扩散层的产生的水的排水性和电极催化剂层的保湿性和气体扩散性。 此外，根据本发明的固体高分子电解质型燃料电池，即使在宽湿度范围和电流密度范围的运行条件下也能够获得稳定的发电特性。

公开(公告)号：US07749639B2

公开(公告)日：2010-07-06

申请号：US11571010

申请日：2005-06-21

申请人： Satoru Ichikawa ,  Masahiro Yamamoto ,  Norihisa Waki

发明人： Satoru Ichikawa ,  Masahiro Yamamoto ,  Norihisa Waki

IPC分类号： H01M4/86 ,  H01M8/10

CPC分类号： H01M8/0239 ,  H01M4/8605 ,  H01M4/8636 ,  H01M4/8657 ,  H01M8/0234 ,  H01M8/1007

摘要： A gas diffusion electrode includes: an electrode catalyst layer; microporous layers arranged on the electrode catalyst layer and including at least second and first microporous layers, wherein the second microporous layer disposed on the electrode catalyst layer side is composed to have higher water repellency than the first microporous layer; and an oxidant gas diffusion substrate disposed on the microporous layers and formed of carbon fiber. According to the gas diffusion electrode of the present invention, drainability of generated water from the electrode catalyst layer to the gas diffusion layer and moisture retention and gas diffusibility of the electrode catalyst layer can be enhanced. Moreover, according to a solid polymer electrolyte fuel cell of the present invention, stable power generation characteristics can be obtained even under an operating condition with a wide humidity range and current density range.

摘要翻译： 气体扩散电极包括：电极催化剂层; 布置在所述电极催化剂层上并且包括至少第二和第一微孔层的微孔层，其中设置在所述电极催化剂层侧上的所述第二微孔层具有比所述第一微孔层更高的拒水性; 以及设置在微孔层上并由碳纤维形成的氧化剂气体扩散基板。 根据本发明的气体扩散电极，可以提高从电极催化剂层到气体扩散层的产生的水的排水性和电极催化剂层的保湿性和气体扩散性。 此外，根据本发明的固体高分子电解质型燃料电池，即使在宽湿度范围和电流密度范围的操作条件下也能获得稳定的发电特性。

公开(公告)号：US07344605B2

公开(公告)日：2008-03-18

申请号：US11311148

申请日：2005-12-20

申请人： Hideaki Ono ,  Norihisa Waki ,  Munekatsu Shimada

发明人： Hideaki Ono ,  Norihisa Waki ,  Munekatsu Shimada

IPC分类号： H01F1/055 ,  H01F1/057

CPC分类号： B82Y25/00 ,  C21D6/007 ,  C21D2201/03 ,  C22C38/005 ,  C22C38/10 ,  C22C45/02 ,  H01F1/0579 ,  H01F1/058 ,  H01F1/059

摘要： An anisotropic exchange spring magnet powder complexing a hard magnetic material and a soft magnetic material, wherein a rare earth metal element, a transition metal element, boron and carbon and the like are contained, and the hard magnetic material and soft magnetic material have crystal particle diameters of 150 nm or less. A method of producing an anisotropic exchange spring magnet powder comprises treating a crystalline mother material containing a hard magnetic material and soft magnetic material or the crystalline mother material having amorphous parts, in a continuous process composed of an amorphising process and the following crystallizing process, repeated once or more times. An anisotropic exchange spring magnet is obtained by treatment, in an anisotropy- imparting molding process and a solidification process, of an anisotropic exchange spring magnet powder.

摘要翻译： 包含硬磁性材料和软磁性材料的各向异性交换弹簧磁铁粉末，其中含有稀土金属元素，过渡金属元素，硼和碳等，并且硬磁性材料和软磁性材料具有晶体颗粒 直径为150nm以下。 制造各向异性交换弹簧磁铁粉末的方法包括：在由非晶化过程和随后的结晶过程组成的连续工艺中处理含有硬磁性材料和软磁性材料的结晶母材或具有无定形部分的结晶母材，重复 一次或多次。 通过在各向异性交换弹簧磁铁粉末的各向异性赋予模制过程和固化过程中进行处理，获得各向异性交换弹簧磁体。

公开(公告)号：US20120148732A1

公开(公告)日：2012-06-14

申请号：US13390810

申请日：2010-09-03

申请人： Takuya Hasegawa ,  Norihisa Waki ,  Hiroshi Kuwahara

发明人： Takuya Hasegawa ,  Norihisa Waki ,  Hiroshi Kuwahara

IPC分类号： B05D5/12

CPC分类号： H01M4/8821 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0245 ,  H01M2008/1095 ,  Y02P70/56

摘要： The invention is to provide a gas diffusion layer for fuel cells having excellent adaptability against load change by attaining a good balance between anti-dry-out properties and anti-flooding properties. The gas diffusion layer for fuel cells containing a substrate layer and an conductive fine particle layer is formed by coating a coating liquid for forming the conductive fine particle layer on at least one surface of a substrate for forming the substrate layer using a gravure roll and by a kiss coating. In coating of the coating liquid, a speed difference is generated between a line speed of transferring the substrate and a circumferential speed of the gravure roll, and apparent viscosity [η(Pa·s)] of the coating liquid as determined by type B viscosimeter satisfies the following relations: 1.0

摘要翻译： 本发明提供一种燃料电池用气体扩散层，通过实现防干燥性能和抗淹水性能之间的良好平衡，具有优异的耐负荷变化适应性。 含有基材层和导电性微粒层的燃料电池用气体扩散层通过使用凹版辊在基材层的基板的至少一个表面上涂布形成导电性微粒层的涂布液而形成， 一个吻涂层。 在涂布液体中，基板转印线速度与凹版滚筒的圆周速度之间产生速度差，以及由B型确定的涂布液的表观粘度[＆egr（（Pa·s）]） 粘度计满足以下关系：1.0 <＆eegr <200.0（3rpm）0.2 <＆eegr <10.0（30rpm）

公开(公告)号：US08557327B2

公开(公告)日：2013-10-15

申请号：US13390810

申请日：2010-09-03

申请人： Takuya Hasegawa ,  Norihisa Waki ,  Hiroshi Kuwahara

发明人： Takuya Hasegawa ,  Norihisa Waki ,  Hiroshi Kuwahara

IPC分类号： B05D5/12 ,  B05D3/12 ,  B05D1/28

CPC分类号： H01M4/8821 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0245 ,  H01M2008/1095 ,  Y02P70/56

摘要： The invention is to provide a gas diffusion layer for fuel cells having excellent adaptability against load change by attaining a good balance between anti-dry-out properties and anti-flooding properties. The gas diffusion layer for fuel cells containing a substrate layer and an conductive fine particle layer is formed by coating a coating liquid for forming the conductive fine particle layer on at least one surface of a substrate for forming the substrate layer using a gravure roll and by a kiss coating. In coating of the coating liquid, a speed difference is generated between a line speed of transferring the substrate and a circumferential speed of the gravure roll, and apparent viscosity [η(Pa·s)] of the coating liquid as determined by type B viscosimeter satisfies the following relations: 1.0

摘要翻译： 本发明提供一种燃料电池用气体扩散层，通过实现防干燥性能和抗淹水性能之间的良好平衡，具有优异的耐负荷变化适应性。 含有基材层和导电性微粒层的燃料电池用气体扩散层通过使用凹版辊在基材层的基板的至少一个表面上涂布形成导电性微粒层的涂布液而形成， 一个吻涂层。 在涂布液中，在B型粘度计测定的涂布液的转印速度和凹版滚筒的圆周速度之间产生速度差，涂布液的表观粘度[η（Pa·s）] 满足以下关系：1.0

公开(公告)号：US20060156628A1

公开(公告)日：2006-07-20

申请号：US10546862

申请日：2004-02-27

申请人： Norihisa Waki

发明人： Norihisa Waki

IPC分类号： B01J8/00 ,  B01J8/04

CPC分类号： B01J19/0013 ,  B01J2208/0053 ,  B01J2219/00049 ,  B01J2219/00051 ,  B01J2219/00076 ,  C01B3/583 ,  C01B2203/0244 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/142 ,  C01B2203/146 ,  C01B2203/1685 ,  C01B2203/169 ,  C01B2203/82 ,  H01M8/04022 ,  H01M8/0612 ,  H01M8/0662

摘要： A reformer (8) reforms hydrocarbon fuel and generates reformate gas. A first carbon monoxide oxidizer (1) and second carbon monoxide oxidizer (2) disposed in series decrease the carbon monoxide concentration of the reformate gas by a prefential oxidation. The air for the preferential oxidation is supplied to the carbon monoxide oxidizer (1, 2) from a compressor (9). The reformer (8) consumes the water heated by the reaction heat of the first carbon monoxide oxidizer (1). The water amount supplied for the reformer (8) increases as a fuel reforming requirement of the reformer (8) increases. When the fuel reforming requirement increases, the water heating capability of the first carbon monoxide oxidizer (1) is enhanced with a sufficient response by increasing the proportion of air supplied to the first carbon monoxide oxidizer (1).

摘要翻译： 改革者（8）改革碳氢化合物燃料并产生重整气。 串联设置的第一一氧化碳氧化器（1）和第二一氧化碳氧化器（2）通过预氧化降低重整气体的一氧化碳浓度。 用于优先氧化的空气从压缩机（9）供应到一氧化碳氧化剂（1,2）。 重整器（8）消耗由第一一氧化碳氧化器（1）的反应热加热的水。 由于重整器（8）的燃料重整要求增加，为重整器（8）供给的水量增加。 当燃料重整要求增加时，通过增加供应到第一一氧化碳氧化剂（1）的空气的比例，通过充分的响应来提高第一一氧化碳氧化剂（1）的水加热能力。

公开(公告)号：US06736909B2

公开(公告)日：2004-05-18

申请号：US09960972

申请日：2001-09-25

申请人： Norihisa Waki ,  Hideaki Ono ,  Munekatsu Shimada ,  Tatsuo Sugiyama

发明人： Norihisa Waki ,  Hideaki Ono ,  Munekatsu Shimada ,  Tatsuo Sugiyama

IPC分类号： H01F1057

CPC分类号： B82Y25/00 ,  H01F1/0579

摘要： A bulk exchange-spring magnet 12, a method of producing the same, and a device 20 incorporating the bulk exchange-spring magnet are disclosed. The magnet includes magnet powders 10 having hard and soft phases, and boron and oxygen atoms which cohere in boundary areas 16 between grains 14 of the densified magnet powders 10. In a production method, the magnet powders 10 are compacted so as to incorporate boron and oxygen atoms into the boundary areas 16 and are heated under a compacted state of the magnet powders at varying operating temperatures for a given time period. This results in formation of a highly densified magnet at a lower potential operating temperature for a shorter time period without the grain growth. The device 20 includes the bulk exchange-spring magnet 12 containing the boron and oxygen atoms cohering between the grains of the densified magnet powders.

摘要翻译： 公开了一种大容量交换弹簧磁体12及其制造方法，以及结合本体交换弹簧磁体的装置20。 磁体包括具有硬相和软相的磁体粉末10，以及与致密磁体粉末10的晶粒14之间的边界区域16中的硼原子和氧原子。在制造方法中，将磁体粉末10压实，从而结合硼和 氧原子进入边界区域16，并在变化的工作温度下在磁体粉末的压实状态下加热给定的时间段。 这导致在更低的电势工作温度下形成高度致密的磁体较短的时间段而没有晶粒生长。 装置20包括体积交换弹簧磁体12，其包含在致密的磁体粉末的颗粒之间粘附的硼和氧原子。

公开(公告)号：US10230112B2

公开(公告)日：2019-03-12

申请号：US14119308

申请日：2012-05-22

申请人： Yusuke Kato ,  Takashi Ito ,  Masami Yanagida ,  Satoshi Oku ,  Hiroyuki Ogino ,  Masato Kusakabe ,  Ryutaro Mukai ,  Masahiro Kojima ,  Takashi Kikuchi ,  Akiko Waki ,  Shiho Inoue ,  Shigeo Ibuka ,  Yasuyuki Tanaka ,  Yoshio Shimoida ,  Yuji Muroya ,  Norihisa Waki

发明人： Yusuke Kato ,  Takashi Ito ,  Masami Yanagida ,  Satoshi Oku ,  Hiroyuki Ogino ,  Masato Kusakabe ,  Ryutaro Mukai ,  Masahiro Kojima ,  Takashi Kikuchi ,  Akiko Waki ,  Shiho Inoue ,  Shigeo Ibuka ,  Yasuyuki Tanaka ,  Yoshio Shimoida ,  Yuji Muroya ,  Norihisa Waki

IPC分类号： H01M4/66 ,  H01M10/052 ,  H01M4/02

摘要： A conductive film includes a layer 1 formed by a conductive material 1 that includes a polymer material 1 containing any of (1) an amine and an epoxy resin (where the epoxy resin and the amine are mixed in a ratio of 1.0 or more in terms of the ratio of the number of active hydrogen atoms in the amine with respect to the number of functional groups in the epoxy resin), (2) a phenoxy resin and an epoxy resin, (3) a saturated hydrocarbon polymer having a hydroxyl group, and (4) a curable resin and an elastomer and conductive particles 1. The conductive film has excellent stability in an equilibrium potential environment in a negative electrode and low electric resistance per unit area in the thickness direction. A multilayer conductive film including the conductive film achieves excellent interlayer adhesion, and using them as a current collector enables the production of a battery satisfying both weight reduction and durability.

公开(公告)号：US20110171563A1

公开(公告)日：2011-07-14

申请号：US13120811

申请日：2009-09-16

申请人： Norihisa Waki ,  Nagakazu Furuya

发明人： Norihisa Waki ,  Nagakazu Furuya

IPC分类号： H01M8/04

CPC分类号： H01M8/0245 ,  H01M8/0234 ,  H01M8/0239 ,  H01M2008/1095

摘要： A gas diffusion layer for a fuel cell includes a conductive microparticle layer and a base material layer. The conductive microparticle layer is formed with first pores of no less than 0.5 μm and no more than 50 μm and second pores of no less than 0.05 μm and less than 0.5 μm. Pores are also formed in the base material layer. A total volume of the second pores is no less than 50% and less than 100% of a total volume of all of the pores in the conductive microparticle layer. By properly setting a pore size D1 of pores having a maximum volume ratio from among the first pores, water passages are formed in the first pores separately from gas passages formed in the second pores.

摘要翻译： 燃料电池用气体扩散层包括导电性微粒层和基材层。 导电性微粒层由不小于0.5μm且不大于50μm的第一孔和不小于0.05μm且小于0.5μm的第二孔形成。 孔也形成在基材层中。 第二孔的总体积不小于导电性微粒层中的所有孔的总体积的50％以上且小于100％。 通过适当地设定从第一孔之间具有最大体积比的孔的孔径D1，在第一孔中形成与第二孔中形成的气体通道分开的水通道。

公开(公告)号：US09601780B2

公开(公告)日：2017-03-21

申请号：US14119290

申请日：2012-05-22

申请人： Yusuke Kato ,  Masahiro Kojima ,  Ryutaro Mukai ,  Masato Kusakabe ,  Hiroyuki Ogino ,  Takashi Kikuchi ,  Takashi Ito ,  Satoshi Oku ,  Akiko Waki ,  Shiho Inoue ,  Yuji Muroya ,  Norihisa Waki ,  Yasuyuki Tanaka ,  Shigeo Ibuka ,  Yoshio Shimoida

发明人： Yusuke Kato ,  Masahiro Kojima ,  Ryutaro Mukai ,  Masato Kusakabe ,  Hiroyuki Ogino ,  Takashi Kikuchi ,  Takashi Ito ,  Satoshi Oku ,  Akiko Waki ,  Shiho Inoue ,  Yuji Muroya ,  Norihisa Waki ,  Yasuyuki Tanaka ,  Shigeo Ibuka ,  Yoshio Shimoida

IPC分类号： H01M4/66 ,  H01M10/0525 ,  C08K3/04 ,  C08J7/04 ,  B32B27/08 ,  B32B27/20 ,  B32B27/28 ,  B32B27/32 ,  H01M4/02

CPC分类号： H01M4/668 ,  B32B27/08 ,  B32B27/20 ,  B32B27/281 ,  B32B27/325 ,  B32B2264/10 ,  B32B2264/105 ,  B32B2307/202 ,  B32B2307/206 ,  B32B2457/10 ,  C08G2261/3324 ,  C08G2261/418 ,  C08J7/047 ,  C08J2379/08 ,  C08J2465/00 ,  C08K3/04 ,  C08K2201/001 ,  H01M4/661 ,  H01M4/663 ,  H01M4/666 ,  H01M4/667 ,  H01M10/0525 ,  H01M2004/029 ,  Y02E60/122 ,  C08L65/00

摘要： A multilayer conductive film includes a layer 1 including a conductive material containing a polymer material 1 having an alicyclic structure and conductive particles 1 and a layer 2 including a material having durability against positive electrode potential. The multilayer conductive film has stability in an equilibrium potential environment in a negative electrode and stability in an equilibrium potential environment in a positive electrode, has low electric resistance per unit area in the thickness direction, and has excellent barrier properties for a solvent of an electrolytic solution. A battery including a current collector employing the multilayer conductive film can achieve both weight reduction and durability.