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    Ion-selective electrodes
    3.
    发明授权
    Ion-selective electrodes 失效
    离子选择电极

    公开(公告)号：US5132345A

    公开(公告)日：1992-07-21

    申请号：US624623

    申请日：1990-12-10

    申请人： Stephen J. Harris ,  Michael A. McKervey ,  Gyula Svehla ,  Dermot Diamond

    发明人： Stephen J. Harris ,  Michael A. McKervey ,  Gyula Svehla ,  Dermot Diamond

    IPC分类号： G01N27/333

    CPC分类号： G01N27/333

    摘要： An ion-selective polymeric membrane for an electrochemical sensor for use in analytical chemistry, comprisinga) a supporting matrix e.g. of PVC, andb) an ionophore selected from calixarene or oxacalixarene derivatives of the formula IV ##STR1## wherein n+m=3-8;m=0-8;n=0-8;a, which may be the same or different on each aryl group, is 0 or 1;R.sup.2 is alkyl, aryl, alkaryl, alkoxy, alkoxyalkoxy, aryloxy, alkaryloxy, alicyclic, alkylthio, arylthio, alkarylthio, or a substituted derivative thereof;R.sup.3 is --H, alkyl or alkenyl;X is --OH or a group containing an acrylate or methacrylate functional group;provided that when X is --OH, n is at least 1/2(n+m);and provided that when m=0, n=4, a=0 and R.sup.3 is alkyl or allyl, R.sup.2 is not alkoxy having 4 or more carbon atoms in the alkyl group;and provided that when m=0, n=4, a=0 and R.sup.3 is t-butyl, R.sup.2 is not methoxy or ethoxy;or of the formula V ##STR2## wherein R.sup.4 is alkyl; or polymers of those compounds of the formula IV in which X is a group containing an acrylate or methacrylate group.New compounds in which R.sup.2 is --SCH.sub.2 CH.sub.3 are described.Selectivity coefficients and slope measurements are given for the ionophores in PVC electrodes which are selective for sodium, potassium and caesium.

    摘要翻译： 一种用于分析化学中的用于电化学传感器的离子选择性聚合物膜，包括：a） 的PVC，和b）选自式IV的杯芳烃或氧杂七环芳烃衍生物的离子载体，其中n + m = 3-8; m = 0-8; n = 0-8; a在每个芳基上可以相同或不同，为0或1; R2是烷基，芳基，烷芳基，烷氧基，烷氧基烷氧基，芳氧基，烷氧基，脂环族，烷硫基，芳硫基，烷芳硫基或其取代衍生物。 R3是-H，烷基或烯基; X是-OH或含有丙烯酸酯或甲基丙烯酸酯官能团的基团; 条件是当X为-OH时，n为至少1/2（n + m）; 并且条件是当m = 0时，n = 4，a = 0和R3是烷基或烯丙基，R2不是烷基中具有4个或更多个碳原子的烷氧基; 并且条件是当m = 0时，n = 4，a = 0和R3是叔丁基，R 2不是甲氧基或乙氧基; 或其中R 4是烷基的式V V 或其中X为含丙烯酸酯或甲基丙烯酸酯基团的式Ⅳ化合物的聚合物。 描述了其中R2是-SCH2CH3的新化合物。 对于对钠，钾和铯有选择性的PVC电极中的离子载体，给出了选择性系数和斜率测量。

    Chromoionophores, optical sensors containing them and a method for determining the presence of alkali metal cations or of a base
    4.
    发明授权
    Chromoionophores, optical sensors containing them and a method for determining the presence of alkali metal cations or of a base 失效
    含铬荧光体，含有它们的光学传感器和用于测定碱金属阳离子或碱的存在的方法

    公开(公告)号：US5599913A

    公开(公告)日：1997-02-04

    申请号：US381912

    申请日：1995-03-28

    申请人： Stephen J. Harris ,  Dermot Diamond ,  Michael A. McKervey

    发明人： Stephen J. Harris ,  Dermot Diamond ,  Michael A. McKervey

    IPC分类号： C07C205/42 ,  C07C205/43 ,  C07C205/45 ,  C07C245/08 ,  G01N31/22

    CPC分类号： C07C205/43 ,  C07C205/42 ,  C07C205/45 ,  C07C245/08 ,  C07C2103/92 ,  Y10S435/808 ,  Y10T436/11 ,  Y10T436/173845 ,  Y10T436/174614

    摘要： New chromoionophores of the formula IV ##STR1## wherein a=0-3, b=0 or 1, c =0 or 1, x=0 or 1, y=0 or 1, z=0 or 1,R', which may be the same or different in each aryl group, is H, halogen, hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof;R, which may be the same or different, is hydrocarbyl, aryl, hydrocarbylaryl, or a substituted derivative thereofare useful in optical sensors or colourmetric reagents for clinical use particularly for lithium, When complexed with lithium, the chromoionophores of the invention and other calixarene derivatives can be used for detecting amines, particularly trimethylamine, as an indicator of fish spoilage.

    摘要翻译： PCT No.PCT / IE93 / 00046 Sec。 371日期：1995年3月28日 102（e）1995年3月28日PCT PCT 1993年8月6日PCT公布。 公开号WO94 / 04483 日期1994年3月3日公式IV的新的铬离子荧光素其中a = 0-3，b = 0或1，c = 0或1，x = 0或1，y = 0或1，z = 0或1，R'在每个芳基中可以相同或不同，为H，卤素，烃基，芳基，烃基芳基或其取代的衍生物; R可以相同或不同，是烃基，芳基，烃基芳基或其取代的衍生物，可用于特别用于锂的临床用光学传感器或色度试剂中。当与锂络合时，本发明的染色体和其他杯芳烃 衍生物可用于检测胺，特别是三甲胺，作为鱼类腐败的指标。

    Nitrogen-containing oxacalixarene and calixarene derivatives, polymers including groups related to such derivatives, and use of such compounds
    6.
    发明授权
    Nitrogen-containing oxacalixarene and calixarene derivatives, polymers including groups related to such derivatives, and use of such compounds 失效
    含氮氧杂环芳烃和杯芳烃衍生物，包括与这种衍生物有关的基团的聚合物，以及这些化合物的用途

    公开(公告)号：US5043415A

    公开(公告)日：1991-08-27

    申请号：US248874

    申请日：1988-09-23

    申请人： Stephen J. Harris ,  Maureen G. MacManus ,  John Guthrie

    发明人： Stephen J. Harris ,  Maureen G. MacManus ,  John Guthrie

    IPC分类号： C07D313/00 ,  C07D321/00 ,  C07D323/00

    CPC分类号： C07D321/00 ,  C07D313/00 ,  C07D323/00

    摘要： The application describes nitrogen-containing an oxacalixarene or calixarene derivative of formula I: ##STR1## wherein m'+m"=0-8n=0-8m'.gtoreq.1/2(m'+M")3.ltoreq.m'+m"+n.ltoreq.8if n=0, m'+m".gtoreq.4R.sup.3 is H, halogen, or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof and R.sup.3 may be the same or different on each aryl group;R.sup.1 and R.sup.15 which may be the same or different are H or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof;R.sup.2 is selected from:R.sup.4 which is H, or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof, ##STR2## wherein R.sup.5 and R.sup.6 which may be the same or different are H, or hydrocarbyl, aryl, hydrocarbylaryl, or a substituted derivative thereof,-OR.sup.1, wherein R.sup.1 is as defined aboveand R.sup.17 which is a residue of a hydrocarbyl, aryl, or hydrocarbylaryl group or of a substituted derivative thereof providing a bond to another oxacalixarene or calixarene derivative of formula I wherein R.sup.2 is R.sup.17.The derivatives may be polymer-bound. Use of the derivatives for sequestration of metals is also described.

    LITHIUM ION SECONDARY BATTERY ELECTRODE AND METHOD OF FORMING SAME
    8.
    发明申请
    LITHIUM ION SECONDARY BATTERY ELECTRODE AND METHOD OF FORMING SAME 有权
    锂离子二次电池电极及其形成方法

    公开(公告)号：US20120301790A1

    公开(公告)日：2012-11-29

    申请号：US13114458

    申请日：2011-05-24

    申请人： Xinran Xiao ,  Adam T. Timmons ,  Stephen J. Harris

    发明人： Xinran Xiao ,  Adam T. Timmons ,  Stephen J. Harris

    IPC分类号： H01M4/74 ,  H01M4/26 ,  B05D5/12

    CPC分类号： H01M4/13 ,  H01M4/0404 ,  H01M4/139 ,  H01M4/625 ,  H01M10/0525 ,  H01M2220/20 ,  Y02E60/122 ,  Y02T10/7011 ,  Y10S977/742 ,  Y10S977/762 ,  Y10S977/948 ,  Y10T29/49115

    摘要： A method of forming an electrode of a lithium ion secondary battery includes combining a binder and active particles to form a mixture, coating a surface with the mixture to form a coated article, translating the article along a first plane, cutting a first plurality of carbon fibers, each having a first average length, to form a second plurality of carbon fibers, each having a longitudinal axis and a second average length that is shorter than the first average length, inserting the second plurality of fibers into the mixture layer so that the longitudinal axis of each of at least a portion of the second plurality of fibers is not parallel to the first plane to form a preform, wherein the second plurality of fibers forms a truss structure disposed in three dimensions within the mixture layer, and heating the preform to form the electrode. An electrode is also disclosed.

    摘要翻译： 形成锂离子二次电池的电极的方法包括将粘合剂和活性颗粒组合以形成混合物，用混合物涂覆表面以形成涂布制品，沿着第一平面平移物品，切割第一多个碳 纤维，每个具有第一平均长度，以形成第二多个碳纤维，每个碳纤维具有比第一平均长度短的纵向轴线和第二平均长度，将第二多个纤维插入混合物层中，使得 所述第二多根纤维的至少一部分中的每一个的纵向轴线不平行于所述第一平面以形成预成型件，其中所述第二多根纤维形成三维地设置在所述混合物层内的桁架结构，并且加热所述预制件 以形成电极。 还公开了一种电极。

    Sensor for measuring alcohol content of alcohol gasoline fuel mixtures
    9.
    发明授权
    Sensor for measuring alcohol content of alcohol gasoline fuel mixtures 失效
    用于测量酒精汽油燃料混合物的酒精含量的传感器

    公开(公告)号：US5262645A

    公开(公告)日：1993-11-16

    申请号：US754475

    申请日：1991-09-03

    申请人： David K. Lambert ,  Stephen J. Harris ,  Stephen J. Swarin

    发明人： David K. Lambert ,  Stephen J. Harris ,  Stephen J. Swarin

    IPC分类号： G01N21/31 ,  G01N21/35 ,  G01N33/28

    CPC分类号： G01N21/314 ,  G01N21/3504 ,  G01N21/3577 ,  G01N21/359 ,  G01N33/2852

    摘要： An alcohol sensing device is provided for determining the alcohol content within an alcohol/gasoline fuel mixture provided to an internal combustion engine. The sensing device uses infrared spectrometry measuring techniques. The infrared sensing device determines the ratio of light absorption by the alcohol/gasoline mixture at two discrete wavelengths within the near-infrared spectrum. The two particular wavelengths of interest are preferably chosen so that at one of the infrared wavelengths, alcohol is strongly absorbing while the gasoline exhibits very little absorption, and at the second wavelength both the alcohol and the gasoline exhibit are essentially non-absorbing. A light beam is transmitted through the alcohol/gasoline fuel mixture such that the two discrete wavelengths traverse the same optical path. A first and second detector are adjacently disposed so as to receive the emitted light from each wavelength after their transmission through the alcohol/gasoline fuel mixture. A third and fourth detector are adjacently disposed in proximity to the first and second detectors for sensing the drift in ambient temperatures corresponding to the first and second detectors. Once the signals corresponding to the two wavelengths are obtained and the signals corresponding to the ambient temperatures are factored out, the ratio of the absorbances by the fuel mixture at both wavelengths is computed. From this ratio and the fuel temperature the concentration of alcohol in the fuel is determined.

    摘要翻译： 提供了一种酒精感测装置，用于确定提供给内燃机的醇/汽油燃料混合物中的醇含量。 感测装置使用红外光谱测量技术。 红外感测装置确定近红外光谱中两个离散波长下的醇/汽油混合物的光吸收率。 优选选择感兴趣的两个特定波长，使得在红外波长的一个处，醇是强吸收的，而汽油表现出非常少的吸收，而在第二波长下，醇和汽油表现出基本上不吸收。 光束通过酒精/汽油燃料混合物传播，使得两个离散的波长穿过相同的光路。 相邻地设置第一和第二检测器，以便在透过酒精/汽油燃料混合物之后接收来自每个波长的发射光。 第三和第四检测器相邻设置在第一和第二检测器附近，用于感测对应于第一和第二检测器的环境温度的漂移。 一旦获得对应于两个波长的信号，并且将与环境温度相对应的信号进行分解，则计算两个波长处的燃料混合物的吸光度比。 从该比率和燃料温度确定燃料中的醇的浓度。

    Polyvinyl acetal resin, use thereof as an adhesion promoting additive, method of producing same, and adhesive composition comprising same
    10.
    发明授权
    Polyvinyl acetal resin, use thereof as an adhesion promoting additive, method of producing same, and adhesive composition comprising same 失效
    聚乙烯醇缩醛树脂，其作为粘合促进添加剂的用途，其制造方法以及包含其的粘合剂组合物

    公开(公告)号：US4992509A

    公开(公告)日：1991-02-12

    申请号：US252831

    申请日：1988-10-03

    申请人： Stephen J. Harris

    发明人： Stephen J. Harris

    IPC分类号： C08F8/28 ,  C08F8/14

    CPC分类号： C08F8/14 ,  C08F2810/30

    摘要： Polyvinyl acetal resin, use thereof as an adhesion promoting additive, method of producing same, and adhesive composition comprising sameAn acrylate- or methacrylate-substituted polyvinyl acetal resin of formula I: ##STR1## wherein the weight percentages of the X, Y and Z groups are variable, R is a hydrogen atom or an alkyl group, andR.sub.1 is hydrogen atom or a methyl group, is described.The resin of formula I is produced by acrylating or methacrylating a polyvinyl acetal resin of formula II: ##STR2## in which the weight percentages of the X', Y' and Z' groups are variable, particularly in the range 68 to 88% X, 6 to 19% Y' and 1 to 26% Z.The compounds of formula I are used to promote adhesion of acrylate or methacrylate ester based adhesive compositions to polyester plastic substrates.