AMIDE-EXTENDED CROSSLINKING COMPOUNDS AND METHODS FOR USE THEREOF
    1.
    发明申请
    AMIDE-EXTENDED CROSSLINKING COMPOUNDS AND METHODS FOR USE THEREOF 有权
    AMIDE-EXTENDED CROSSLINKING COMPOUNDS及其使用方法

    公开(公告)号:US20130338313A1

    公开(公告)日:2013-12-19

    申请号:US13970523

    申请日:2013-08-19

    摘要: The invention is based on the discovery that a remarkable improvement in the performance of maleimide thermosets can be achieved by incorporating amide-extended maleimides into an adhesive formulation. Amide-extended maleimides described herein can be used to toughen bismaleimide thermosetting materials without sacrificing any thermal stability. Amide-extended maleimides are readily prepared by reacting a bismaleimide with an appropriate amine via the well-known Michael addition reaction. Acylation of the resulting secondary amines provides the amide-extended maleimide. The acylating agent can also be used to introduce polymerizable functional groups into the backbones of these thermoset monomers. Amide-extended acrylate and methacrylate monomers can also be prepared.

    摘要翻译: 本发明基于以下发现,即通过将酰胺延伸的马来酰亚胺掺入粘合剂制剂中可以显着改善马来酰亚胺热固性材料的性能。 本文所述的酰胺延伸的马来酰亚胺可用于增强双马来酰亚胺热固性材料,而不牺牲任何热稳定性。 酰胺延伸的马来酰亚胺通过公知的迈克尔加成反应使双马来酰亚胺与适当的胺反应容易地制备。 所得仲胺的酰化提供了酰胺延伸的马来酰亚胺。 酰化剂也可用于将可聚合官能团引入这些热固性单体的主链。 还可以制备酰胺延伸的丙烯酸酯和甲基丙烯酸酯单体。

    THERMOSETTING ADHESIVE COMPOSITIONS
    2.
    发明申请
    THERMOSETTING ADHESIVE COMPOSITIONS 审中-公开
    热固性胶粘剂组合物

    公开(公告)号:US20130187095A1

    公开(公告)日:2013-07-25

    申请号:US13769317

    申请日:2013-02-16

    IPC分类号: C09J4/06

    摘要: The invention is based on the discovery that adhesive compositions containing certain low-viscosity, mono-ethylenically unsaturated monomers have surprisingly good cure parameters, resulting in very little weight loss upon cure. Many of these monofunctional monomers used alone or in combination with other monofunctional monomers described herein have high glass transition temperatures when cured. Moreover, since these monomers are monofunctional the crosslink density of the adhesive composition does not increase (relative to multi-functional monomers), which in turns results in lower stress, lower modulus adhesive compositions. As such, these monomers are useful in a variety of thermoset adhesive compositions, such as for example, die attach adhesive compositions.

    摘要翻译: 本发明基于以下发现:含有某些低粘度单烯属不饱和单体的粘合剂组合物具有惊人的良好固化参数,导致固化时重量损失非常小。 单独使用或与本文所述的其它单官能单体组合使用的许多这些单官能单体在固化时具有高的玻璃化转变温度。 此外,由于这些单体是单官能的,粘合剂组合物的交联密度不会增加(相对于多官能单体),这又导致较低的应力,较低的模量粘合剂组合物。 因此,这些单体可用于各种热固性粘合剂组合物,例如模具附着粘合剂组合物。

    Di-cinnamyl compounds and methods for use thereof
    4.
    发明授权
    Di-cinnamyl compounds and methods for use thereof 有权
    二肉桂基化合物及其使用方法

    公开(公告)号:US08308892B2

    公开(公告)日:2012-11-13

    申请号:US12421616

    申请日:2009-04-09

    申请人: Stephen M Dershem

    发明人: Stephen M Dershem

    摘要: The invention generally relates to di-cinnamyl compounds useful in a variety of adhesive applications. More specifically, the invention provides chain-extended bismaleimides and methods for generating them by reaction with di-cinnamyl compounds, including particular di-cinnamyl compounds disclosed herein. Invention di-cinnamyl compounds can also be used as co-monomers in a Diels-Alder type cure, and can act as a co-monomer in a thermoset composition with a maleimide monomer.

    摘要翻译: 本发明一般涉及可用于各种粘合剂应用的二肉桂基化合物。 更具体地说,本发明提供了链延伸的双马来酰亚胺和通过与二肉桂基化合物反应生成它们的方法,包括本文公开的具体的二肉桂酰化合物。 本发明的二肉桂酰化合物也可以作为Diels-Alder型固化中的共聚单体使用,并且可以作为马来酰亚胺单体的热固性组合物中的共聚单体。

    MALEIMIDE-FUNCTIONAL MONOMERS IN AMORPHOUS FORM
    6.
    发明申请
    MALEIMIDE-FUNCTIONAL MONOMERS IN AMORPHOUS FORM 有权
    非晶形式的马来酰亚胺官能单体

    公开(公告)号:US20120049106A1

    公开(公告)日:2012-03-01

    申请号:US13218406

    申请日:2011-08-25

    摘要: The present invention provides amorphous maleimide-bismaleimide hybrid mixtures and methods for synthesizing such mixtures by condensation of diamine compounds with maleic anhydride along with one or more additional anhydrides. The invention provides a route to get passed the high melting point and the solubility issues of bismaleimide resins, yet to still obtain the good thermo-mechanical properties of these valuable molecules.

    摘要翻译: 本发明提供无定形马来酰亚胺 - 双马来酰亚胺混合物混合物和通过二胺化合物与马来酸酐与一种或多种另外的酸酐的缩合来合成这种混合物的方法。 本发明提供了通过双马来酰亚胺树脂的高熔点和溶解度问题的途径,仍然获得了这些有价值的分子的良好的热机械性能。

    Imide-linked maleimide and polymaleimide compounds
    9.
    发明授权
    Imide-linked maleimide and polymaleimide compounds 有权
    酰亚胺化马来酰亚胺和聚马来酰亚胺化合物

    公开(公告)号:US07208566B2

    公开(公告)日:2007-04-24

    申请号:US10835911

    申请日:2004-04-30

    IPC分类号: C08G69/08 C08G73/10 C08G73/14

    摘要: The invention is based on the discovery that a remarkable improvement in the performance of maleimide thermosets can be achieved through the incorporation of imide-extended mono-, bis-, or polymaleimide compounds. These imide-extended maleimide compounds are readily prepared by the condensation of appropriate anhydrides with appropriate diamines to give amine terminated compounds. These compounds are then condensed with excess maleic anhydride to yield imide-extended maleimide compounds.

    摘要翻译: 本发明基于以下发现:通过引入酰亚胺延伸的单 - ,双 - 或聚马来酰亚胺化合物可以实现马来酰亚胺热固性材料性能的显着改进。 这些酰亚胺扩展的马来酰亚胺化合物可以通过将适当的酸酐与合适的二胺缩合得到胺封端的化合物而容易地制备。 然后将这些化合物与过量的马来酸酐缩合,得到酰亚胺扩展的马来酰亚胺化合物。

    EXTREME HIGH TEMPERATURE STABLE ADHESIVES AND COATINGS

    公开(公告)号:US20220213267A1

    公开(公告)日:2022-07-07

    申请号:US17604985

    申请日:2020-04-17

    IPC分类号: C08G73/10 C08J5/24

    摘要: The present invention provides curable polyimides with low color that are resistant to long term thermo-oxidative degradation. These materials, which include polyimides that are fully aromatic, are synthesized in anisole and are contemplated for use in high temperature applications such as in the aerospace industry and for use as encapsulants for light emitting diodes that will be exposed to high temperatures.