摘要:
The disclosure relates to the cyanocarbon compositions and processes for producing the same. The cyanocarbon compositions comprise tricyanohexane and one or more coproducts of the tricyanohexane production reaction. Exemplary coproducts include tetracyano compounds, cyanoalkenes, cyanooximes, cyanoamides, and combinations thereof.
摘要:
Die Erfindung betrifft ein Verfahren zur Herstellung von ionischen Flüssigkeiten auf der Basis von Tricyanomethansalze der Formel (I) worin Q + ein organisches Kation ist, das mindestens ein Heteroatom enthält, ausgewählt aus der Gruppe bestehend aus Stickstoff, Phosphor, Schwefel und Sauerstoff, sowie ionische Flüssigkeiten auf der Basis von Tricyanomethaniden.
摘要:
Battery has an electrolyte comprising a solvent and a salt (I) comprising a hydroxonium, nitrosonium, ammonium, metal, organic or organometallic cation and a 5-membered (hetero)cyclic anion. Battery has an electrolyte comprising a solvent and a salt (I) comprising a hydroxonium, nitrosonium, ammonium, metal, organic or organometallic cation and a 5-membered (hetero)cyclic anion with the following formula: [Image] X1-X5-N=, -N->-, -C(Y)=, -C->(Y)-, -S(O)(Q)=, -S(Q)= or -P(Q')(Q)=, provided that no more than four comprise N, no more than two comprise S (nonadjacent) and no more than one comprises P; Q', Q : 1-8C perhaloalkyl, perhaloalkenyl or optionally substituted 6-12C aryl or aralkyl, each optionally containing O, S or N heteroatoms; Q : an alkyl, alkenyl, aryl, aralkyl, alkylaryl, alkenylaryl, alicyclic or heterocyclic group optionally substituted with halogen and/or ether, thioether, amine, imine, amide, carboxy, carbonyl, isocyanate, isothiocyanate and hydroxy groups; an aromatic group with ring(s) and/or substituent(s) containing heteroatoms; a polymeric group; or a group having one or more cationic and/or anionic ionophore groups; Y : H, F, Cl, Br, CN, SCN, NCS, NCO, NO2, perfluoroalkyl, perfluoroalkoxy, perfluoroalkylmethyl, tetrafluoroethoxy, SCF3, perfluoroalkylthio, tetrafluoroethylthio, trifluorovinyloxy, trifluorovinylthio, SO2F, SO2Q, COOQ, Q-N-SO2- (sic) or COQ; a group comprising one or more aromatic rings that optionally contain N, O, S or P and are optionally substituted with halogen, CN, CO2, SCN, N3, trifluorovinyloxy, (1-12C perfluoroalkyl)methyl, fluoroalkoxy, fluoroalkylthioxy, alkyl, alkenyl, oxaalkyl, oxaalkenyl, azaalkyl, azaalkenyl, thiaalkyl, thiaalkenyl, polymeric groups and groups having one or more cationic and/or anionic ionophore groups; alternatively, two of Y, Q, Q' and Q can form a 4- to 8-membered ring, or one of Y and Q is a multivalent group attached to a second 5-membered (hetero)cyclic anion, or one of Y and Q is a repeat unit of a polymer; provided that at least one Y or Q comprises a dissociating dipole.
摘要:
Provided herein are processes for purifying TCH in a feed stream, such as an adiponitrile process stream. The processes include a first separating step of separating the adiponitrile process stream to form a first overhead stream comprising low-boiling components and high- boiling components and a first bottoms stream comprising high-boiling components. The processes also include a second separating step of separating the first overhead stream in one or more distillation columns to form a lights stream comprising low-boiling components, a heavies stream comprising high-boiling components, and a TCH stream.
摘要:
A process for preparation of the compound (I) and salts thereof is provided. The process comprises reacting an alkali cyanide and paraformaldehyde to form a slurry of glycolonitrile followed by neutralizing, mixing the neutralized slurry containing glycolonitrile with an alkali ethoxide and an cyanoacetate to obtain the alkali salt of compound (I), and neutralizing the alkali salt of compound (I) to obtain the compound (I), wherein R represents a straight or branched chain alkyl having C 1 -C 18 carbon atoms.
摘要:
Die vorliegende Erfindung betrifft ein technisch gangbares Verfahren zur Herstellung von Alkali- und Erdalkalimetalltricyanomethaniden in einer besonders hohen Reinheit.