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    Substituted .alpha.-pyrones
    4.
    发明授权
    Substituted .alpha.-pyrones 失效
    取代的α-吡喃酮

    公开(公告)号：US5011944A

    公开(公告)日：1991-04-30

    申请号：US356825

    申请日：1989-05-24

    申请人： Vratislav Kvita ,  Marcus Baumann ,  Walter Fischer ,  Carl W. Mayer ,  Thomas Allmendinger

    发明人： Vratislav Kvita ,  Marcus Baumann ,  Walter Fischer ,  Carl W. Mayer ,  Thomas Allmendinger

    IPC分类号： C07D309/30 ,  B05D1/20 ,  C07C45/00 ,  C07C50/24 ,  C07C67/00 ,  C07C69/95 ,  C07D309/38 ,  C07F7/08 ,  C07F7/18 ,  C08G61/12 ,  C09K9/02 ,  H01B1/12

    CPC分类号： B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C07D309/38 ,  C08G61/123 ,  C09K9/02 ,  H01B1/121

    摘要： .alpha.-Pyrones of the formula I ##STR1## in which R.sup.1 is --CF.sub.3 or --COOR.sup.3 and R.sup.3 is the radical of a C.sub.1 -C.sub.18 alcohol diminished by a hydroxyl group, and R.sup.2 is --F, --Br, --Cl, --CN, --CF.sub.3, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.2 -C.sub.18 alkynyl, C.sub.1 -C.sub.18 alkoxy, C.sub.1 -C.sub.18 alkylthio, C.sub.1 -C.sub.18 alkylsulfonyl, C.sub.6 -C.sub.16 aryl, C.sub.7 -C.sub.24 alkaryl, C.sub.7 -C.sub.12 aralkyl, C.sub.8 -C.sub.24 alkaralkyl, C.sub.6 -C.sub.16 aryloxy, C.sub.6 -C.sub.16 arylthio, C.sub.6 -C.sub.16 arylsulfonyl, C.sub.7 -C.sub.24 alkaryloxy, C.sub.7 -C.sub.24 alkarylthio, C.sub.7 -C.sub.24 alkarylsulfonyl, C.sub.7 -C.sub.12 aralkyloxy, C.sub.7 -C.sub.12 aralkylthio, C.sub.7 -C.sub.12 aralkylsulfonyl, C.sub.8 -C.sub.24 alkaralyloxy, C.sub.8 -C.sub.24 alkaralylthio, C.sub.8 -C.sub.24 alkaralylsulfonyl, secondary amine having 2 to 24 C atoms or trialkylsilyl or trialkoxysilyl each of which has 3 to 18 C atoms. They are suitable for the preparation of naphtho-1,4-quinones and anthra-1,4-quinones, from which tetrathiotetracenes or tetraselenotetracenes having electrochromic properties can be obtained.

    摘要翻译： 其中R 1为-CF 3或-COOR 3且R 3为被羟基减弱的C 1 -C 18醇基团的式I（I）的α-吡喃酮，R2为-F，-Br，-Cl ，-CN，-CF 3，C 1 -C 18烷基，C 2 -C 18烯基，C 2 -C 18炔基，C 1 -C 18烷氧基，C 1 -C 18烷硫基，C 1 -C 18烷基磺酰基，C 6 -C 16芳基，C 7 -C 24烷芳基，C 7 -C 12芳烷基，C 8 -C 24烷基烷基，C 6 -C 16芳氧基 ，C 6 -C 16芳硫基，C 6 -C 16芳基磺酰基，C 7 -C 24链烯氧基，C 7 -C 24烷芳硫基，C 7 -C 24烷芳基磺酰基，C 7 -C 12芳烷氧基，C 7 -C 12芳烷硫基，C 7 -C 12芳烷基磺酰基，C 8 -C 24链烷氧基，C 8 -C 24烷酰基硫代，C 8 -C 24烷酰基磺酰基， 24个C原子或三烷基甲硅烷基或三烷氧基甲硅烷基，各自具有3至18个C原子。 它们适用于制备萘并-1,4-醌和蒽-1,4-醌，可从中得到具有电致变色特性的四硫代四烯或四硒代四烯。

    Substituted tetrathiotetracenes and tetraselenotetracenes
    5.
    发明授权
    Substituted tetrathiotetracenes and tetraselenotetracenes 失效

    公开(公告)号：US4981962A

    公开(公告)日：1991-01-01

    申请号：US356824

    申请日：1989-05-24

    申请人： Marcus Baumann ,  Walter Fischer ,  Vratislav Kvita ,  Carl W. Mayer ,  Wolfgang Wernet

    发明人： Marcus Baumann ,  Walter Fischer ,  Vratislav Kvita ,  Carl W. Mayer ,  Wolfgang Wernet

    IPC分类号： B05D1/20 ,  C07D495/06 ,  C07D517/06 ,  C07D517/16 ,  C08G61/12 ,  C09K9/02 ,  H01B1/12

    CPC分类号： C07D495/06 ,  B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C07D517/06 ,  C07D517/08 ,  C08G61/123 ,  C09K9/02 ,  H01B1/121

    摘要： Substituted tetrathiotetracenes and tetraselenotetracenes of the formula I ##STR1## in which Z is --S-- or --Se-- and (a) R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are H and R.sup.5 to R.sup.8 are each H and at least one of the radicals R.sup.5 to R.sup.8 independently of one another is a substituent belonging to the group comprising C.sub.1 -C.sub.20 alkyl--X--.sub.p which is unsubstituted or substituted by halogen, --CN, --CONR.sup.9 R.sup.10, --OR.sup.9, --SR.sup.9 or --COOR.sup.9, with the exception of C.sub.1 -C.sub.4 alkyl and methoxy, C.sub.2 -C.sub.18 alkenyl--X--.sub.p, C.sub.2 -C.sub.18 -alkynyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, (C.sub.1 -C.sub.12 alkyl)--C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl-C.sub.r H.sub.2r --X--.sub.p, (C.sub.1 -C.sub.12 alkyl)-C.sub.3 -C.sub.8 -cyclo alkyl-C.sub.r H.sub.2r --X--.sub.p, phenyl--X--.sub.p, (C.sub.1 -C.sub.12)alkyl)-phenyl--X--, phenyl-C.sub.r H.sub. 2r --X--.sub.p and (C.sub.1 -C.sub.12 alkyl)-phenyl-C.sub.r H.sub.2r --X--.sub.p, r is 1 or 2 and p is 0 or 1 and X is --O--, --S--, --SO-- or --SO.sub.2 --, or R.sup.5 to R.sup.8 independently are a substituent belonging to the group comprising --Br, --CF.sub.3, --CN, --Si(C.sub.1 -C.sub.4 alkyl).sub.3, --S--(C.sub.m H.sub.2m O)--.sub.n R.sup.11 or --O--C.sub.m H.sub.2m --O--R.sup.11, or each one of R.sup.5 to R.sup.8 is --F or --Cl and at least one further member of R.sup.5 to R.sup.8 is a substituent of the groups defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, R.sup.9 and R.sup.10 independently of one another are H, C.sub.1 -C.sub.12 alkyl, phenyl or --C.sub.m H.sub.2m --O--.sub.q R.sup.11, or R.sup.9 and R.sup.10 together are tetramethylene, pentamethylene, 3-oxapentylene or --CH.sub.2 CH.sub.2 NR.sup.9 CH.sub.2 CH.sub.2 --, R.sup.11 is H or C.sub.1 -C.sub.12 -alkyl, m is a number from 2 to 4, n is a number from 2 to 20 and q is a number from 1 to 20, orb) R.sup.1 to R.sup.8 independently of one another are H or one of the substituents defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, or --COOR.sup.9 or --CONR.sup.9 R.sup.10 or two pairs of adjacent radicals of R.sup.1 to R.sup.8 are --CO--O--CO-- or --CO--NR.sup.9 --CO--, and at least one of R.sup.1 to R.sup.4 and also R.sup.5 to R.sup.8 is a substituent, with the exception of R.sup.2, R.sup.3, R.sup.6 and R.sup.7 when these are --F and methyl, and where R.sup.9 and R.sup.10 are as defined above.With electron acceptors they form charge-transfer complexes which can be used as organic electrical conductors, displays, optical switches and sensors.

    Imidyl compounds
    8.
    发明授权
    Imidyl compounds 失效
    咪唑基化合物

    公开(公告)号：US4193927A

    公开(公告)日：1980-03-18

    申请号：US898754

    申请日：1978-04-21

    申请人： Marcus Baumann ,  Vratislav Kvita ,  Martin Roth ,  John S. Waterhouse

    发明人： Marcus Baumann ,  Vratislav Kvita ,  Martin Roth ,  John S. Waterhouse

    IPC分类号： C07D207/44 ,  C07D207/452 ,  C07D209/48 ,  C07F7/18 ,  C07F7/21 ,  C08G69/26 ,  C07D403/10

    CPC分类号： C07D207/452 ,  C07D209/48 ,  C07F7/182 ,  C07F7/21 ,  C08G69/265

    摘要： The imidyl compounds, according to the invention, of the formula I are suitable for the manufacture of polymers which can be crosslinked by light, which polymers can be, for example, polyesters, polyamides, polyamide-imides, polyimides, polyester-polyamides, polyester-amide-imides, polyethers, polyamines, polysaccharides and polysiloxanes. Polymers of this type are suitable for carrying out photochemical processes. Compared with known polymers, the polymers based on the imidyl compounds according to the invention have the advantage that they are photochemically substantially more sensitive. In addition, this sensitivity can also be further increased effectively by a combination with sensitizers.

    摘要翻译： 根据本发明的式I的亚氨基化合物适用于制造可通过光交联的聚合物，该聚合物可以是例如聚酯，聚酰胺，聚酰胺 - 酰亚胺，聚酰亚胺，聚酯 - 聚酰胺，聚酯 酰胺 - 酰亚胺，聚醚，聚胺，多糖和聚硅氧烷。 这种聚合物适用于进行光化学处理。 与已知的聚合物相比，基于本发明的亚氨基化合物的聚合物具有光电化学上更加敏感的优点。 此外，通过与敏化剂的组合，也可以有效地进一步提高该灵敏度。

    Imidyl compounds
    10.
    发明授权
    Imidyl compounds 失效
    咪唑基化合物

    公开(公告)号：US4172836A

    公开(公告)日：1979-10-30

    申请号：US898748

    申请日：1978-04-21

    申请人： Marcus Baumann ,  Vratislav Kvita ,  Martin Roth ,  John S. Waterhouse

    发明人： Marcus Baumann ,  Vratislav Kvita ,  Martin Roth ,  John S. Waterhouse

    IPC分类号： C07D207/44 ,  C07D207/452 ,  C07D209/48 ,  C07F7/18 ,  C07F7/21 ,  C08G69/26 ,  C07D207/12 ,  C07D403/04 ,  C07D403/10

    CPC分类号： C07D207/452 ,  C07D209/48 ,  C07F7/182 ,  C07F7/21 ,  C08G69/265

    摘要： The imidyl compounds, according to the invention, of the formula I are suitable for the manufacture of polymers which can be crosslinked by light, which polymers can be, for example, polyesters, polyamides, polyamide-imides, polyimides, polyester-polyamides, polyester-amide-imides, polyethers, polyamines, polysaccharides and polysiloxanes. Polymers of this type are suitable for carrying out photochemical processes. Compared with known polymers, the polymers based on the imidyl compounds according to the invention have the advantage that they are photochemically substantially more sensitive. In addition, this sensitivity can also be further increased effectively by a combination with sensitisers.

    摘要翻译： 根据本发明的式I的亚氨基化合物适用于制造可通过光交联的聚合物，该聚合物可以是例如聚酯，聚酰胺，聚酰胺 - 酰亚胺，聚酰亚胺，聚酯 - 聚酰胺，聚酯 酰胺 - 酰亚胺，聚醚，聚胺，多糖和聚硅氧烷。 这种聚合物适用于进行光化学处理。 与已知的聚合物相比，基于本发明的亚氨基化合物的聚合物具有光电化学上更加敏感的优点。 此外，通过与敏化剂的组合，也可以有效地进一步提高该灵敏度。