Method for forming coating film
    91.
    发明授权
    Method for forming coating film 失效
    涂膜形成方法

    公开(公告)号:US5064695A

    公开(公告)日:1991-11-12

    申请号:US580969

    申请日:1990-09-12

    摘要: A method for forming a coating film is here disclosed which comprises the steps of coating a member with a coating material containing a pigment for a thermosetting base coat, overcoating the coated member with a coating material for a thermosetting clear coat in a wet-on-wet coating manner, and then thermosetting the uncured coating films simultaneously;a binder component in the coating material for the base coat comprising50 to 90% by weight of an acrylic copolymer having a hydroxyl value of from 40 to 80 mg KOH/g and an acid value of from 0.5 to 30 mg KOH/g and a glass transition temperature of from -40.degree. to 20.degree. C. which is obtained by copolymerizing 10 to 40% by weight of a hydroxyl group-containing (meth)acrylic ester, 0.2 to 10% by weight of a carboxyl group-containing vinyl monomer, 30 to 89.8% by weight of a (meth)acrylic ester and 0 to 30% by weight of another vinyl monomer, and10 to 50% by weight of a curing agent;a binder component in the coating material for the clear coat comprisingan acrylic copolymer having a hydroxyl value of from 50 to 180 mg KOH/g, an acid value of from 2 to 40 mg KOH/g and a glass transition temperature of from -40.degree. to 20.degree. C. which is obtained by copolymerizing5 to 60% by weight of a fluorine-containing (meth)-acrylic ester, 10 to 60% by weight of a hydroxyl group-containing (meth)acrylic ester, 0.2 to 10% by weight of a vinyl monomer containing an acidic group, 15 to 70% by weight of a (meth)acrylic ester and 5 to 50% by weight of another vinyl monomer, anda polyisocyanate compound;a ratio X/Y of an equivalent (X) of the OH group present in the acrylic copolymer to an equivalent (Y) of the NCO group in the polyisocyanate compound being in the range of from 1/0.5 to 1/1.5.

    摘要翻译: 这里公开了一种形成涂膜的方法,其包括以下步骤:用含有用于热固性基底涂层的颜料的涂层材料涂覆部件,用涂覆材料涂覆用于热固性透明涂层的涂层材料, 湿法涂布,然后同时热固未固化涂膜; 用于底涂层的涂料中的粘合剂组分包含羟基值为40至80mg KOH / g,酸值为0.5至30mg KOH / g的丙烯酸共聚物的50至90重量%,和 通过共聚10〜40重量%的含羟基的(甲基)丙烯酸酯,0.2〜10重量%的含羧基的乙烯基单体得到的玻璃化转变温度为-40〜20℃ ,30〜89.8重量%的(甲基)丙烯酸酯和0〜30重量%的其它乙烯基单体,10〜50重量%的固化剂; 用于透明涂层的涂料中的粘合剂组分包括羟值为50至180mg KOH / g,酸值为2至40mg KOH / g和玻璃化转变温度为-40℃的丙烯酸共聚物 通过使5〜60重量%的含氟(甲基)丙烯酸酯,10〜60重量%的含羟基的(甲基)丙烯酸酯,0.2〜10重量% 含有酸性基团的乙烯基单体的重量%,(甲基)丙烯酸酯15〜70重量%,其它乙烯基单体5〜50重量%,多异氰酸酯化合物; 存在于丙烯酸类共聚物中的OH基当量(X)与多异氰酸酯化合物中的NCO基的当量(Y)的比X / Y为1 / 0.5〜1 / 1.5。