公开(公告)号：US07807604B2

公开(公告)日：2010-10-05

申请号：US11914048

申请日：2005-05-12

Applicant: Michel Strebelle ,  André Petitjean

Inventor： Michel Strebelle ,  André Petitjean

IPC: B01J23/72 ,  B01J21/04 ,  B01J23/78 ,  C07C17/013

CPC classification number: B01J23/72 ,  B01J23/78 ,  C07C17/156 ,  C07C19/045

Abstract: Oxychlorination catalyst containing at least copper as an active element deposited on a support characterized in that the support consists essentially of an alumina obtained by calcination of an alumina hydrate obtained as by-product of the ALFOL® linear primary alcohol process and use of such catalyst in an oxychlorination process of a hydrocarbon containing 1 to 4 carbon atoms.

Abstract translation: 含有至少铜作为沉积在载体上的活性元素的氧氯化催化剂，其特征在于，载体主要由氧化铝组成，该氧化铝通过煅烧作为线性伯醇方法的副产物得到的氧化铝水合物和使用这种催化剂 含有1至4个碳原子的烃的氧氯化方法。

公开(公告)号：US20100160156A1

公开(公告)日：2010-06-24

申请号：US12637686

申请日：2009-12-14

Applicant: Mark Ibsen ,  Sergio Mohedas

Inventor： Mark Ibsen ,  Sergio Mohedas

IPC: B01J23/75 ,  B01J19/00 ,  B01J23/745 ,  B01J23/72 ,  B01J23/78 ,  B01J21/08

CPC classification number: B01J37/18 ,  B01J23/745 ,  B01J23/75 ,  B01J23/78 ,  B01J37/08 ,  B01J37/16 ,  C10G2/332 ,  C10G2300/703

Abstract: A system for activating Fischer-Tropsch catalyst comprising a reactor having a reactor outlet for overhead gas and operable under suitable conditions whereby a catalyst in a volume of liquid carrier comprising Fischer-Tropsch diesel, hydrocracking recycle oil, or a combination thereof may be activated in the presence of an activation gas; a condenser comprising an inlet fluidly connected to the reactor outlet for overhead gas and comprising a condenser outlet for condensed liquids; and a separation unit comprising an inlet fluidly connected to the condenser outlet and a separator outlet for a stream comprising primarily Fischer-Tropsch diesel; and a recycle line fluidly connecting the separator outlet, a hydrocracking unit, or both to the reactor, whereby Fischer-Tropsch diesel recovered from the reactor overhead gas, hydrocracking recycle oil, or a combination thereof may serve as liquid carrier for catalyst in the reactor. A method for activating Fischer-Tropsch catalyst is also provided.

Abstract translation: 用于活化费 - 托催化剂的系统，其包括具有用于塔顶气体的反应器出口的反应器并且在合适的条件下可操作的反应器，由此在一定体积的包含费 - 托柴油，加氢裂化循环油或其组合的液体载体中的催化剂可以在 活化气体的存在; 冷凝器，包括流体连接到塔顶气体的反应器出口的入口，并且包括用于冷凝液体的冷凝器出口; 以及分离单元，其包括流体连接到冷凝器出口的入口和用于主要包含费 - 托柴油的物流的分离器出口; 以及将分离器出口，加氢裂化单元或二者流体连接到反应器的循环管线，其中从反应器塔顶气体回收的费 - 托柴油，加氢裂化循环油或其组合可用作反应器中的催化剂的液体载体 。 还提供了一种活化费 - 托催化剂的方法。

公开(公告)号：US20080280750A1

公开(公告)日：2008-11-13

申请号：US12149628

申请日：2008-05-06

Applicant: Pao-Chu Liu

Inventor： Pao-Chu Liu

IPC: B01J27/053 ,  B01J27/055 ,  B01J21/18 ,  B01J31/06 ,  B01J23/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/14 ,  B01J23/34 ,  B01J23/72 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  B01J23/889 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J21/02 ,  B01J21/06 ,  B01J21/16

CPC classification number: B01J23/78 ,  B01D53/8659 ,  B01D53/8671 ,  B01D2255/202 ,  B01D2255/204 ,  B01D2255/2047 ,  B01D2255/206 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/30 ,  B01D2255/702 ,  B01D2257/2022 ,  B01D2257/2025 ,  B01D2257/2027 ,  B01D2257/204 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/60 ,  B01D2258/0216 ,  B01J21/18 ,  B01J23/02 ,  B01J23/04 ,  B01J23/08 ,  B01J23/10 ,  B01J23/14 ,  B01J23/70 ,  B01J23/8892 ,  B01J27/232 ,  B01J37/0063 ,  B01J37/0201 ,  Y02C20/30

Abstract: Catalysts for treating acid gases and halogen gases and the production methods thereof. The acid and halogen gases include HCl, HF, HBr, HI, F2, Cl2, Br2, I2, ClF3, PH3, PCl3, PCl5, POCl3, P2O5, AsH3, SiH4, SiF4, SiCl4, SiHCl3, SiH2Cl2, BF3, BCl3, GeCl4, GeH4, NO, NO2, SO2, SO3 and SF6, etc.The catalysts comprise one or more carrier materials selected from activated carbon, argil, diatomite, cement, silica and ceramic materials; and one or more metal compounds selected from: alkali metal hydroxides, oxides, carbonates and bicarbonates, alkaline earth metal hydroxides, oxides, carbonates and bicarbonates, Group IIIA metal oxides, Group IVA metal oxides, and transition metal oxides, oxide hydrates, sulfates and carbonates.

Abstract translation: 用于处理酸性气体和卤素气体的催化剂及其制备方法。 酸和卤素气体包括HCl，HF，HBr，HI，F 2，Cl 2，Br 2，I 2， 3个，3个，3个，3个，3个，3个，3个，3个，3个，3个，3个， ，2个O 2，3个H，3个SiH 4，4个SiF 4， SiCl 3，SiCl 4，SiHCl 3，SiH 2 Cl 2，BF 3，/ 3 >，BCl 3，GeCl 4，GeH 4，NO，NO 2，SO 2， SO 3，SO 3和SF 6等。催化剂包含一种或多种选自活性炭，硅，硅藻土，水泥，二氧化硅和陶瓷材料的载体材料; 和一种或多种选自以下的金属化合物：碱金属氢氧化物，氧化物，碳酸盐和碳酸氢盐，碱土金属氢氧化物，氧化物，碳酸盐和碳酸氢盐，IIIA族金属氧化物，IVA族金属氧化物和过渡金属氧化物，氧化物水合物，硫酸盐和 碳酸盐

公开(公告)号：US20080200741A1

公开(公告)日：2008-08-21

申请号：US12022416

申请日：2008-01-30

Applicant: Ruth Mary KOWALESKI

Inventor： Ruth Mary KOWALESKI

IPC: C07C2/64 ,  B01J23/745 ,  B01J23/83 ,  B01J23/78 ,  B01J23/888 ,  B01J23/88

CPC classification number: C01G49/06 ,  B01J23/745 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8872 ,  B01J35/0026 ,  B01J35/1009 ,  B01J37/0009 ,  B01J37/06 ,  B82Y30/00 ,  C01G49/009 ,  C01P2002/52 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/80 ,  C07C5/3332 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/83 ,  C07C2523/881 ,  C07C15/46

Abstract: A process for preparing a dehydrogenation catalyst comprising preparing a mixture comprising a treated regenerator iron oxide and at least one additional catalyst component; and calcining the mixture wherein the treated regenerator iron oxide is prepared by washing a regenerator iron oxide at a temperature below 350° C. such that the treated regenerator iron oxide has a chloride content of at most 500 ppmw relative to the weight of iron oxide, calculated as Fe2O3; the catalyst prepared by this process and the use of the catalyst in a dehydrogenation process.

Abstract translation: 一种制备脱氢催化剂的方法，包括制备包含经处理的再生器氧化铁和至少一种另外的催化剂组分的混合物; 并煅烧所述混合物，其中所述处理的再生器氧化铁通过在低于350℃的温度下洗涤再生器氧化铁来制备，使得所述处理的再生器氧化铁相对于氧化铁的重量具有至多500ppmw的氯化物含量， 计算为Fe 2 O 3 O 3; 通过该方法制备的催化剂和在脱氢方法中使用催化剂。

公开(公告)号：US20050203194A1

公开(公告)日：2005-09-15

申请号：US10510836

申请日：2003-04-15

Applicant: Frederick Botes ,  Tracy Bromfield

Inventor： Frederick Botes ,  Tracy Bromfield

IPC: B01J23/745 ,  B01J23/78 ,  B01J29/04 ,  B01J29/40 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/03 ,  C07C1/04 ,  C07C27/06 ,  C10G2/00

CPC classification number: C10G2/332 ,  B01J23/745 ,  B01J23/78 ,  B01J29/40 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/031 ,  C10G2/334

Abstract: This invention relates to a high temperature Fischer-Tropsch (HTFT) hydrocarbon synthesis process comprising the conversion of a feed of H2 and at least one carbon oxide to hydrocarbons containing at least 30% on a mass basis hydrocarbons with five or more carbon atoms (hereinafter referred to as C5+ compounds). The conversion is carried out in the presence of an alkali-promoted iron hydrocarbon synthesis catalyst, and the process is characterised therein that the reaction mixture formed during the conversion contains less than 0.02 mol alkali per 100 g iron, and that the H2:carbon oxide molar ratio in the feed of H2 and carbon oxide is at least 2.

Abstract translation: 本发明涉及一种高温费 - 托（HTFT）烃合成方法，其包括将H 2 O 2和至少一种碳氧化物的进料转化成基于烃的至少30％的烃 具有五个或更多个碳原子（以下称为C 5+ +化合物）。 转化在碱促进的铁烃合成催化剂的存在下进行，其特征在于转化中形成的反应混合物含有每100g铁少于0.02摩尔的碱， H 2 CO 2和CO 2的进料中的二氧化碳摩尔比为至少2。

公开(公告)号：US20050096216A1

公开(公告)日：2005-05-05

申请号：US11002275

申请日：2004-12-03

Applicant: Keld Johansen ,  Petru Gordes

Inventor： Keld Johansen ,  Petru Gordes

IPC: B01J23/00 ,  B01J23/06 ,  B01J23/26 ,  B01J23/70 ,  B01J23/745 ,  B01J23/78 ,  B01J23/80 ,  B01J23/86 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/08 ,  C01B13/18 ,  C01G9/00 ,  C01G49/00 ,  C01G49/06 ,  C01G51/00 ,  C07C29/156 ,  B01J23/02 ,  B01J23/04

CPC classification number: B01J23/78 ,  B01J23/002 ,  B01J23/06 ,  B01J23/26 ,  B01J23/70 ,  B01J23/745 ,  B01J23/80 ,  B01J23/86 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/031 ,  B01J37/086 ,  B01J2523/00 ,  B82Y30/00 ,  C01B13/185 ,  C01G9/006 ,  C01G49/06 ,  C01G51/006 ,  C01G53/00 ,  C01P2002/50 ,  C01P2002/52 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2004/64 ,  C01P2006/12 ,  C07C29/156 ,  Y02P20/52 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/67 ,  B01J2523/842 ,  B01J2523/845 ,  C07C31/04

Abstract: A process for the production mixed metal oxide containing catalysts comprising the steps of: dissolution of metals Me=Fe, Ni, Al, Cu, Co, Zn, Cr, in nitric acid providing an acid solution of metal mixed nitrate products, aluminium can be added either as nitrate or hydroxide; addition of a carbonhydrate, an amino acid and/or a carboxylic acid; decomposition at 250-700° C. with free air supply of the acid solution by spraying onto the inner surface of one or more rotary kilns, into a spray calcination fluid bed, into a tower kiln or into a steel band conveyor furnace to iron oxide and NOx; and optionally regeneration of the formed NOx to concentrated nitric acid and recycling of produced nitric acid to the first step.

Abstract translation: 一种制备含有催化剂的混合金属氧化物的方法，包括以下步骤：在硝酸中溶解金属Me = Fe，Ni，Al，Cu，Co，Zn，Cr，提供金属混合硝酸盐产物的酸溶液，铝可以 加入硝酸盐或氢氧化物; 加入碳水化合物，氨基酸和/或羧酸; 在250-700℃下分解，通过喷洒到一个或多个旋转窑的内表面上的酸溶液的自由空气进入喷雾煅烧流化床，进入塔窑或钢带输送炉中至氧化铁 和NO ; 并且任选地将形成的NO x x再生成浓硝酸并将产生的硝酸再循环到第一步骤。

公开(公告)号：US20050049143A1

公开(公告)日：2005-03-03

申请号：US10911648

申请日：2004-08-05

Applicant: Asako Eguchi ,  Shuji Fujii ,  Akihiro Sawata ,  Yasuhiko Tsuru

Inventor： Asako Eguchi ,  Shuji Fujii ,  Akihiro Sawata ,  Yasuhiko Tsuru

IPC: F01N3/02 ,  B01D53/94 ,  B01J23/00 ,  B01J23/26 ,  B01J23/34 ,  B01J23/656 ,  B01J23/78 ,  B01J23/83 ,  B01J23/89 ,  B01J37/00 ,  F01N3/10 ,  B01J21/18 ,  B01J23/58 ,  B01J27/20 ,  F01N3/00

CPC classification number: B01J23/8946 ,  B01D53/9422 ,  B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1028 ,  B01D2255/202 ,  B01D2255/204 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/402 ,  B01J23/002 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J23/83 ,  B01J37/0036 ,  B01J2523/00 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/67 ,  B01J2523/72 ,  B01J2523/828 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/11 ,  B01J2523/12 ,  B01J2523/14 ,  B01J2523/15 ,  B01J2523/25

Abstract: The present invention provides an exhaust gas treatment catalyst characterized by containing a compound oxide expressed by the following general formula (1), AMxOy  (1)(wherein A represents an alkali metal or alkaline earth metal, M represents Cr, Mn, Fe, Co or Ni, O represents oxygen, and 0

Abstract translation: 本发明提供一种废气处理催化剂，其特征在于含有下述通式（1）表示的复合氧化物AMxOy（1）（式中，A表示碱金属或碱土金属，M表示Cr，Mn，Fe，Co 或Ni，O表示氧，0

公开(公告)号：US20050004407A1

公开(公告)日：2005-01-06

申请号：US10909954

申请日：2004-07-30

Applicant: Hugo Gerard Ingelbrecht ,  Sabyasachi Mandal ,  Ashok Menon ,  Pradeep Nadkarni ,  Rupesh Pawar ,  Kuppuswamy Raghunathan ,  Gert-Jan Schoenmakers ,  Sahida Sharma

Inventor： Hugo Gerard Ingelbrecht ,  Sabyasachi Mandal ,  Ashok Menon ,  Pradeep Nadkarni ,  Rupesh Pawar ,  Kuppuswamy Raghunathan ,  Gert-Jan Schoenmakers ,  Sahida Sharma

IPC: B01J21/10 ,  B01J23/78 ,  B01J23/86 ,  B01J35/10 ,  B01J37/00 ,  C07B61/00 ,  C07C37/16 ,  C07C39/07 ,  C07C37/14

CPC classification number: B01J21/10 ,  B01J23/78 ,  B01J23/862 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0018 ,  C07C37/16 ,  C07C2521/10 ,  C07C2523/745 ,  C07C39/07

Abstract: A method of making a catalyst comprising mixing a metal oxide precursor and a pore former to form a metal oxide precursor mixture and calcining the metal oxide precursor mixture in the presence of a flowing gas having a flow rate to form the catalyst comprising metal oxide. The catalyst comprises a first distribution of pores having a median pore diameter of 10 to 50 angstroms and a second distribution of pores having a median pore diameter of 1 to 500 angstroms. The median pore diameter of the second distribution of pores is inversely related to the flow rate of the gas.

Abstract translation: 一种制备催化剂的方法，包括将金属氧化物前体和成孔剂混合以形成金属氧化物前体混合物，并在流动的气体存在下煅烧金属氧化物前体混合物以形成包含金属氧化物的催化剂。 该催化剂包括中值孔径为10至50埃的孔的第一分布和中等孔径为1至500埃的孔的第二分布。 孔的第二分布的中值孔径与气体的流量成反比。

公开(公告)号：US6090959A

公开(公告)日：2000-07-18

申请号：US146166

申请日：1998-09-03

Applicant: Takenori Hirano ,  Keiichi Tsuto

Inventor： Takenori Hirano ,  Keiichi Tsuto

IPC: B01J21/06 ,  B01J23/04 ,  B01J23/78 ,  C11C3/04 ,  C11C3/10 ,  C11C3/00

CPC classification number: B01J21/066 ,  B01J23/04 ,  B01J23/78 ,  C11C3/04 ,  C11C3/10

Abstract: In a method of producing a fatty acid lower alkylester according to the invention, a fat & oil and a lower alcohol are caused to react with each other in the presence of a catalyst, in which triglyceride contained in the fat & oil undergoes a transesterification. The catalyst to be used in the reaction is a solid basic catalyst consisting essentially of a potassium compound and iron oxide, of a calcium compound and iron oxide, or of a potassium compound and zirconium oxide. It is possible to produce the fatty acid lower alkylester at a high reaction efficiency by this method as well as to simplify or eliminate the need of catalyst separation and recovery processes.

Abstract translation: 在制备本发明的脂肪酸低级烷基酯的方法中，使脂肪和油和低级醇在催化剂的存在下相互反应，其中脂肪和油中含有的甘油三酯经历酯交换反应。 在反应中使用的催化剂是基本上由钾化合物和氧化铁，钙化合物和氧化铁，或钾化合物和氧化锆组成的固体碱性催化剂。 可以通过该方法以高反应效率制备脂肪酸低级烷基酯，并且简化或消除催化剂分离和回收方法的需要。

公开(公告)号：US6028027A

公开(公告)日：2000-02-22

申请号：US29643

申请日：1998-03-17

Applicant: Michael Baier ,  Christopher William Rieker ,  Otto Hofstadt ,  Wolfgang Buchele ,  Wolfgang Jurgen Popel ,  Hermann Petersen ,  Norbert Neth

Inventor： Michael Baier ,  Christopher William Rieker ,  Otto Hofstadt ,  Wolfgang Buchele ,  Wolfgang Jurgen Popel ,  Hermann Petersen ,  Norbert Neth

IPC: B01J23/78 ,  B01J23/80 ,  B01J23/84 ,  B01J23/85 ,  B01J37/00 ,  C07C5/333 ,  C07C15/46 ,  B01J23/00 ,  B01J23/58 ,  C07C2/00 ,  C07C15/00

CPC classification number: B01J37/0009 ,  B01J23/78 ,  C07C5/3332

Abstract: Catalysts comprising iron and potassium and, if desired, further elements, which catalysts are suitable for dehydrogenating hydrocarbons to give the corresponding olefinically unsaturated hydrocarbons, are prepared by calcining a finely divided dry or aqueous mixture of an iron compound with a potassium compound and, if desired, compounds of further elements in a first step that agglomerates having a diameter of from 5 to 50 .mu.m and formed from smaller individual particles are obtained and, in a second step, preferably after shaping, calcining it at from 300 to 1000.degree. C., with the maximum calcination temperature in the second step preferably being at least 30.degree. below the calcination temperature in the first step. The catalysts thus prepared are useful, in particular, for dehydrogenating ethylbenzene to give styrene.

Abstract translation: PCT No.PCT / EP96 / 04028 Sec。 371日期：1998年3月17日 102（e）1998年3月17日PCT PCT 1996年9月13日PCT公布。 公开号WO97 / 10898 日期1997年3月27日包含铁和钾以及如果需要的其它元素的催化剂是通过将细碎的干燥或含水混合物与铁化合物的焙烧而制备的，该催化剂适用于使烃脱氢得到相应的烯属不饱和烃 钾化合物，并且如果需要，获得在第一步骤中的另外的元素的化合物，其具有直径为5至50μm并且由较小的单个颗粒形成的附聚物，并且在第二步中，优选在成型之后，从其煅烧 300〜1000℃，第二步骤中的最高煅烧温度优选在第一步骤的煅烧温度以下至少30℃。 因此制备的催化剂特别适用于使乙苯脱氢得到苯乙烯。