公开(公告)号：US20130008827A1

公开(公告)日：2013-01-10

申请号：US13636182

申请日：2011-03-24

申请人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

发明人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

IPC分类号： B01J29/74 ,  C10G49/00 ,  C10G65/02

CPC分类号： C10G45/64 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7661 ,  B01J29/7684 ,  B01J29/7692 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/30 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2708 ,  C07C5/2775 ,  C10G45/62 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/1081 ,  C10G2300/30 ,  C10G2300/70 ,  C10G2400/10

摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.

摘要翻译： 本发明的加氢异构化催化剂是用于烃的加氢异构化的催化剂，包括含有由选自Na，K，Cs，Mg，Ca，Ba和K中的至少一种金属改性的煅烧沸石的载体 并且具有包括在350℃以上的加热的热历史，以及选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆，氧化镁，二氧化铈，氧化锌，氧化磷和氧化铝中的至少一种无机氧化物 包含这些氧化物中的至少两种以上的组合的复合氧化物; 以及至少一种负载在载体上并选自元素周期表第8至10族的元素，钼和钨的金属。

公开(公告)号：US20110270010A1

公开(公告)日：2011-11-03

申请号：US13140144

申请日：2009-12-25

申请人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

发明人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

IPC分类号： B01J29/072 ,  C07C7/148

CPC分类号： C10M177/00 ,  B01J29/7261 ,  B01J29/7284 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/1022 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2400/10 ,  C10N2270/00

摘要： A first hydroisomerization catalyst contains a support being a extruded product prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more and at least one metal supported on the support and selected from the group consisting of metals belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten, wherein the support contains (a1) a calcined zeolite prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of an ion-exchanged zeolite obtained by ion exchange of an organic template-containing zeolite containing an organic template and having a 10-membered ring one-dimensional porous structure in a solution containing ammonium ions and/or protons, and (b1) a calcined inorganic oxide prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of two or more of these oxides, wherein the thermal treatment to which the calcined zeolite has been subjected includes calcination in which the ion-exchanged zeolite that has not been thermally treated at 350° C. or more is heated within the range of 350° C. to 450° C.

摘要翻译： 第一加氢异构化催化剂含有载体，其为通过煅烧制备的挤出产物，该热处理包括在350℃或更高温度下热处理和至少一种负载在载体上的金属，并且选自属于第8族的金属 至（10）的元素周期表中的钼和钨，其中所述载体包含（a1）通过煅烧制备的煅烧沸石，其具有热处理，所述热处理包括在350℃或更高温度下热处理通过离子交换获得的离子交换沸石 含有有机模板的沸石，含有有机模板，并且在含有铵离子和/或质子的溶液中具有10元环一维多孔结构，（b1）通过煅烧制备的煅烧无机氧化物，其具有热处理，所述热处理包括 在350℃以上的一种无机氧化物热处理，其选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆 ，氧化镁，二氧化铈，氧化锌，氧化磷和包含两种或更多种这些氧化物的组合的复合氧化物，其中经受煅烧沸石的热处理包括煅烧，其中没有离子交换的沸石 在350℃下进行热处理或更高温度在350℃至450℃的范围内加热。

公开(公告)号：US09598650B2

公开(公告)日：2017-03-21

申请号：US13636182

申请日：2011-03-24

申请人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

发明人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

IPC分类号： B01J29/06 ,  C10G45/00 ,  C07C5/27 ,  C10G45/64 ,  C10G45/62 ,  C10G65/04 ,  B01J29/76 ,  B01J29/78 ,  B01J29/74 ,  B01J37/02 ,  B01J37/18 ,  B01J37/30 ,  B01J37/00

摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.

公开(公告)号：US09458387B2

公开(公告)日：2016-10-04

申请号：US14007396

申请日：2012-03-14

申请人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

发明人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC分类号： B01J21/00 ,  C07C27/00 ,  C10G2/00 ,  B01J21/06 ,  B01J23/00 ,  B01J23/75 ,  B01J35/00 ,  B01J37/18 ,  B01J21/08

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。

公开(公告)号：US20140018454A1

公开(公告)日：2014-01-16

申请号：US14007396

申请日：2012-03-14

申请人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

发明人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC分类号： C10G2/00 ,  B01J23/75

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。

公开(公告)号：US20120322899A1

公开(公告)日：2012-12-20

申请号：US13581948

申请日：2011-02-14

申请人： Hideki Ono ,  Yoshiyuki Nagayasu ,  Kazuaki Hayasaka

发明人： Hideki Ono ,  Yoshiyuki Nagayasu ,  Kazuaki Hayasaka

IPC分类号： B01J23/96 ,  C07C27/00 ,  B01J23/94

CPC分类号： B01J37/18 ,  B01J23/462 ,  B01J23/75 ,  B01J23/8913 ,  B01J23/94 ,  B01J23/96 ,  B01J35/1061 ,  B01J37/10 ,  B01J38/02 ,  B01J38/06 ,  B01J38/10 ,  C10G2/332 ,  C10G2/333

摘要： A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.

摘要翻译： 一种生产通过再生费 - 托合成反应中使用的废催化剂而获得的再生费 - 托合成催化剂的方法，包括使上述废催化剂与含有1〜30体积％ 蒸汽和惰性气体，在大气压至5MPa的压力和150至350℃的温度下，上述废催化剂是废催化剂，其中钴和/或钌负载在包含二氧化硅的载体上，平均 基于相应的未使用的催化剂的活性，通过4〜25nm的氮吸附法测定的孔径，其初始一氧化碳转化率表示的活性为40〜95％。

公开(公告)号：US20120217186A1

公开(公告)日：2012-08-30

申请号：US13391067

申请日：2010-08-06

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

IPC分类号： C10G73/38

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.

摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

公开(公告)号：US20120216449A1

公开(公告)日：2012-08-30

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C10L1/188

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base includes obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6A of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种航空燃料油基料的制造方法，其特征在于，通过使来自动物或植物油脂的含氧烃化合物的原料与第一双官能催化剂接触而进行加氢处理，得到第一产生油， 脱氢和氢化功能，其包括周期表第6A族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触来获得包含航空燃料油基的第二产生的油，该第二双功能催化剂包括周期性的第8族金属 表和结晶固体酸性物质，在氢的存在下。

公开(公告)号：US20110042267A1

公开(公告)日：2011-02-24

申请号：US12865921

申请日：2009-02-04

申请人： Kazuaki Hayasaka

发明人： Kazuaki Hayasaka

IPC分类号： B01J29/74 ,  B01J37/30 ,  B01J37/10 ,  B01J37/08 ,  C10G73/02

CPC分类号： C10G45/64 ,  B01J29/064 ,  B01J29/068 ,  B01J29/076 ,  B01J29/7284 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/48 ,  C10G2300/1022 ,  C10G2300/1085 ,  C10G2400/10

摘要： A hydroisomerization catalyst of the present invention is obtained by calcining a catalyst composition containing an ion-exchanged molecular sieve or a calcined product thereof, and at least one metal selected from the group consisting of metals of Groups 8 to 10 in Periodic Table of the elements, molybdenum and tungsten, carried on the ion-exchanged molecular sieve or the calcined product thereof, wherein the ion-exchanged molecular sieve is obtained by ion-exchanging a molecular sieve, which includes nanocrystals having a pore structure of ten-membered rings or eight-membered rings and having a ratio of the pore volume to the external surface area ([pore volume]/[external surface area]) of 2.0×10−4 mL/m2 to 8.0×10−4 mL/m2 and contains an organic template, in a solution containing a cationic species.

摘要翻译： 通过煅烧含有离子交换分子筛或其煅烧产物的催化剂组合物和选自元素周期表第8〜10族金属中的至少一种金属，得到本发明的加氢异构化催化剂 ，钼和钨载带在离子交换分子筛或其煅烧产物上，其中离子交换分子筛是通过离子交换分子筛获得的，分子筛包括具有十元环或八元孔结构的纳米晶体 具有2.0×10 -4 mL / m 2的孔体积与外表面积（[孔体积] / [外表面积]）的比例为8.0×10 -4 mL / m 2，并且含有有机物 模板，在含有阳离子物质的溶液中。

公开(公告)号：US07429550B2

公开(公告)日：2008-09-30

申请号：US11567374

申请日：2006-12-06

申请人： Hideshi Iki ,  Kazuaki Hayasaka ,  Kazuo Fukazawa

发明人： Hideshi Iki ,  Kazuaki Hayasaka ,  Kazuo Fukazawa

IPC分类号： B01J21/12 ,  B01J27/18 ,  C10G47/18 ,  C10G47/20 ,  C10G45/12

CPC分类号： C10G49/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J27/182 ,  B01J27/19 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/03 ,  C10G49/08

摘要： A hydrogenation catalyst for a hydrocarbon oil, includes an inorganic porous support composed of at least the oxides of aluminum, phosphorus, and silicon, and supporting at least one active metal selected from the metals of Group 8 of the periodic table, at least one active metal selected from the metals of Group 6 of the periodic table, and phosphorus, the phosphorus chemical shift value of the inorganic support determined by 31P-CPMAS-NMR having the peak within the range of 0 to −20 ppm. The catalyst can achieve an extremely high level of hydrogenation wherein the hydrocarbon is decreased in sulfur content to 10 ppm by mass or less and in nitrogen content to 3 ppm by mass or less.

摘要翻译： 用于烃油的氢化催化剂包括至少由铝，磷和硅的氧化物组成的无机多孔载体，并且支持选自元素周期表第8族金属中的至少一种活性金属，至少一种活性 选自元素周期表第6族金属的金属和磷，由POD-NMR-NMR确定的无机载体的磷化学位移值，峰值在0至 - 20 ppm。 催化剂可以实现极高的氢化水平，其中烃的含量降低到10质量ppm以下，氮含量降低到3质量ppm以下。