Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream
    12.
    发明申请
    Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream 有权
    用于从含H 2 S的气流中回收硫的装置和催化部分氧化方法

    公开(公告)号:US20060051275A1

    公开(公告)日:2006-03-09

    申请号:US11225355

    申请日:2005-09-13

    IPC分类号: C01B17/16

    摘要: A process for purifying a light hydrocarbon stream containing H2S is disclosed in which the selective catalytic partial oxidation of the H2S component is carried out while the hydrocarbon components slip through substantially unconverted. A catalyst that favors the partial oxidation of H2S over conversion of the hydrocarbon component of a gaseous H2S-light hydrocarbon mixture is employed. Apparatus for selectively cleaning up light hydrocarbon streams containing low concentrations (e.g., less than 25 vol. %), and apparatus for selectively cleaning up light hydrocarbon streams having higher concentrations (e.g., greater than 25 vol. %) of H2S are also disclosed.

    摘要翻译: 公开了一种用于纯化含有H 2 S的轻质烃流的方法,其中进行H 2 S 2组分的选择性催化部分氧化,同时烃组分滑过 基本未转换 采用有利于H 2 S 2部分氧化的催化剂超过气态H 2 S-S / S轻烃混合物的烃组分的转化。 用于选择性清洁含有低浓度(例如小于25体积%)的轻质烃流的装置,以及用于选择性清洗具有较高浓度(例如大于25体积%)H 2的轻烃流的装置 还公开了S。

    Desulfurization of H.sub.2 S-containing gases
    13.
    发明授权
    Desulfurization of H.sub.2 S-containing gases 失效
    含H2S的气体脱硫

    公开(公告)号:US4507274A

    公开(公告)日:1985-03-26

    申请号:US473533

    申请日:1983-03-09

    摘要: H.sub.2 S-containing gases are desulfurized by direct catalytic oxidation of the H.sub.2 S to elementary sulfur by means of oxygen-containing gases in a tube reactor, with indirect removal of the heat of reaction by means of a coolant and with condensation of the sulfur formed, wherein either the catalyst is present in the jacket space around the tubes and the coolant is present in the tubes of the reactor or the coolant is present in the jacket space around the tubes and the catalyst is present in the tubes of the reactor, and the catalyst fills the tubes of the tube reactor or the jacket space around the tubes over the entire cross-section of the tubes or the jacket space respectively, the exit temperature of the gaseous reaction mixture leaving the tube reactor is kept at 180.degree.-400.degree. C. and the sulfur formed in the tube reactor is separated out of the reaction mixture, obtained in the reactor, in a condensation stage downstream of the reactor.

    摘要翻译: 含H2S的气体通过在管式反应器中通过含氧气体将H2S直接催化氧化成元素硫进行脱硫,通过冷却剂间接除去反应热并与所形成的硫冷凝,其中 催化剂存在于管周围的护套空间中,并且冷却剂存在于反应器的管中,或者冷却剂存在于管周围的护套空间中,并且催化剂存在于反应器的管中,并且催化剂 在管或套管空间的整个横截面上分别填充管式反应器管或围绕管的护套空间,离开管式反应器的气态反应混合物的出口温度保持在180°-400℃ 并且在反应器中形成的硫在反应器中获得的反应混合物中,在反应器下游的冷凝段中分离。

    Process for purifying geothermal steam
    14.
    发明授权
    Process for purifying geothermal steam 失效
    地热蒸汽净化方法

    公开(公告)号:US4196183A

    公开(公告)日:1980-04-01

    申请号:US5942

    申请日:1979-01-24

    申请人: Charles T. Li

    发明人: Charles T. Li

    摘要: Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

    摘要翻译: 通过使化学计量的氧气将硫化氢氧化成吸附在床上的元素硫,通过使蒸汽通过填充有活性炭的反应器来纯化含硫化氢的蒸汽和硫回收。 在通过真空蒸馏,惰性气体夹带或溶剂萃取回收硫之后,可以再循环碳。 该方法适用于从也能含有其它不可冷凝气体的地热源净化蒸汽。

    Process for producing hydrogen, sulfur and sulfur dioxide from hydrogen sulfide-containing gas streams
    20.
    发明授权
    Process for producing hydrogen, sulfur and sulfur dioxide from hydrogen sulfide-containing gas streams 有权
    从含硫化氢的气流中生产氢,硫和二氧化硫的方法

    公开(公告)号:US08562928B2

    公开(公告)日:2013-10-22

    申请号:US13238837

    申请日:2011-09-21

    申请人: Puneet Gupta

    发明人: Puneet Gupta

    摘要: A process for making molecular hydrogen, elemental sulfur and sulfur dioxide from hydrogen sulfide. The process involves contacting a gas stream of hydrogen sulfide within a contacting zone with a contacting composition comprising metal sulfide in a lower sulfided state and yielding from the contacting zone a product gas stream comprising hydrogen and a recovered contacting composition comprising metal sulfide in a higher sulfided state. The higher metal sulfide is regenerated with oxygen to yield elemental sulfur and sulfur dioxide.

    摘要翻译: 从硫化氢制造分子氢,元素硫和二氧化硫的方法。 该方法包括使接触区内的硫化氢气体与包含金属硫化物在较低硫化状态的接触组合物接触,并从接触区产生包含氢气的产物气流和回收的接触组合物,其包含较高硫化物中的金属硫化物 州。 较高的金属硫化物用氧再生,产生元素硫和二氧化硫。