Hydrogen separation alloy and method for producing same
    19.
    发明授权
    Hydrogen separation alloy and method for producing same 有权
    氢分离合金及其制造方法

    公开(公告)号:US09266071B2

    公开(公告)日:2016-02-23

    申请号:US13389618

    申请日:2011-05-31

    Abstract: Disclosed is a hydrogen separation alloy which is adoptable to a product having a large surface area of a side where hydrogen permeates and which has such a metallographic structure as to improve hydrogen permeability and to improve hydrogen-embrittlement resistance. The hydrogen separation alloy used herein is represented by the compositional formula: Nb100−(α+β)M1αM2β where M1 is at least one element selected from the group consisting of Ti, Zr and Hf; M2 is at least one element selected from the group consisting of Ni, Co, Cr, Fe, Cu and Zn; 10≦α≦60, 10≦β≦50, and α+β≦80. The alloy contains inevitable impurities. And the alloy includes two phases, i.e., an Nb-M1 phase serving as a hydrogen-permeable phase, and a M2-M1 phase serving as a hydrogen-embrittlement-resistant phase. The hydrogen-permeable phase and the hydrogen-embrittlement-resistant phase have an elongated structure resulting from rolling. The hydrogen-permeable phase occupies 35% to 70% of an arbitrary 10 μm×10 μm region in a 50 μm×50 μm observation plane of a cross section of the alloy under an electron microscopic observation, the cross section is taken in a direction of thickness reduced by the rolling and in a direction of rolling and flattening.

    Abstract translation: 公开了一种氢分离合金,其可以用于氢渗透的一侧的大表面积的产品,并且具有提高氢渗透性和提高耐氢脆性的金相组织。 本文使用的氢分离合金由组成式表示:Nb100-(α+&bgr;)M1αM2&bgr; 其中M1是选自Ti,Zr和Hf中的至少一种元素; M2是选自Ni,Co,Cr,Fe,Cu和Zn中的至少一种元素; 10≦̸α≦̸ 60,10和nlE;&bgr;≦̸ 50和α+&bgr;≦̸ 80。 该合金含有不可避免的杂质。 该合金包括两相,即用作氢可渗透相的Nb-M1相和用作耐氢脆相的M2-M1相。 氢渗透相和耐氢脆相具有由轧制产生的细长结构。 在电子显微镜观察的合金的截面的50μm×50μm的观察平面中,氢渗透相占据任意10μm×10μm的任意的10μm×10μm的35%〜70%,横截面为 的厚度通过轧制和轧制和扁平化的方向减小。

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