公开(公告)号：US08435910B2

公开(公告)日：2013-05-07

申请号：US12734955

申请日：2008-12-02

申请人： Nobuo Iyi ,  Takayoshi Sasaki

发明人： Nobuo Iyi ,  Takayoshi Sasaki

IPC分类号： B01J21/16

CPC分类号： C01F7/005 ,  B01D53/62 ,  B01D2251/40 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2253/104 ,  B01D2253/112 ,  B01D2257/504 ,  B01J20/0277 ,  B01J20/041 ,  B01J20/043 ,  B01J20/06 ,  B01J20/08 ,  B01J41/10 ,  C01G9/006 ,  C01G53/006 ,  C01P2002/22 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/03 ,  C02F2001/422 ,  Y02C10/04 ,  Y02P20/152

摘要： The invention has for its object to provide a preparation method for preparing an anion-exchangeable LDH by decarbonation of a carbonate ion type LDH, which makes sure de carbonation is implemented with safety in a continuous manner while crystal shape, crystal structure and crystallinity are kept intact.The invention provides a preparation method for preparing an anion-exchangeable, layered double hydroxide wherein a carbonate ion type layered double hydroxide (LDH) having a composition represented by a general formula: QxR(OH)z(CO32−)0.5-y/2(X−)y.nH2O where x is indicative of a numeral range of 1.8≦x≦4.2; z is indicative of 2(x+1); y is indicative of a minimum value of at least 0 that increases to less than 1 when anions (X−) remain or a part of anions is introduced; Q is a divalent metal ion; R is a trivalent metal ion; and n is 2±2 is used as a starting material, and y in said general formula increases to a maximum of 1 by substitution of a minus monovalent anion (X−1) at a carbonate ion site thereby implementing substitution, characterized in that the starting material is dispersed in an aqueous solution mixed with a salt containing minus monovalent anions (X−) in an amount enough for substitution at the carbonate ion site while said aqueous solution is kept at a pH (hydrogen ion exponent) of greater than 4 to less than 7.

摘要翻译： 本发明的目的是提供一种通过碳酸根离子型LDH的脱碳制备可阴离子交换的LDH的制备方法，其确保以连续方式安全地进行脱碳酸化，同时保持晶体形状，晶体结构和结晶度 完整。 本发明提供一种制备阴离子交换性层状双氢氧化物的制备方法，其中具有由以下通式表示的组成的碳酸根离子型层状双氢氧化物（LDH）：QxR（OH）z（CO32-）0.5-y / 2 （X-）y.nH 2 O，其中x表示1.8 @ x @ 4.2的数字范围; z表示2（x + 1）; y表示当阴离子（X）保留或部分阴离子被引入时，至少为0的最小值增加到小于1; Q是二价金属离子; R是三价金属离子; 并且使用n为2±2作为起始原料，通过在碳酸根离子位置取代负一价阴离子（X-1）从而实现取代，所述通式中的y增加到最大值1，其特征在于： 将原料分散在与含有负一价阴离子（X-X）的盐混合的水溶液中，其量足以在碳酸盐离子位置进行取代，同时所述水溶液保持在大于4至大约4的pH（氢离子指数）至 小于7。

公开(公告)号：US20110147060A1

公开(公告)日：2011-06-23

申请号：US12993952

申请日：2009-05-25

申请人： Minoru Osada ,  Takayoshi Sasaki

发明人： Minoru Osada ,  Takayoshi Sasaki

IPC分类号： H05K1/00 ,  B32B5/00 ,  B32B37/00 ,  B05D1/18 ,  B05D1/20 ,  C04B35/462

CPC分类号： C01G33/00 ,  B82Y10/00 ,  B82Y30/00 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/20 ,  C01P2004/20 ,  C01P2004/61 ,  C01P2004/62 ,  C04B35/462 ,  C04B35/495 ,  C04B2235/3201 ,  C04B2235/3234 ,  C04B2235/3255 ,  C04B2235/5292 ,  C04B2235/5454 ,  H01G4/10 ,  H01G4/1218 ,  H01G4/1254 ,  H01G4/30 ,  H01G4/33 ,  H01L21/02175 ,  H01L21/02186 ,  H01L21/02194 ,  H01L21/31604 ,  H01L21/31691 ,  H01L28/40 ,  Y10T156/10

摘要： A monolayer or a multilayer of niobic acid nanosheets is attached to form a dielectric film, and other electrode is arranged on the surface of the dielectric film to construct a dielectric element, and the dielectric element thus provided realizes both high permittivity and good insulating properties even in a nano-region. Also provided is a method of producing the element at low temperatures with no influence of substrate interface deterioration and composition deviation thereof. The method entirely solves the problems of substrate interface deterioration and the accompanying composition deviation and electric incompatibility, and solves the intrinsic problem of “size effect” that the film thickness reduction to a nano-level lowers the specific permittivity and increases the leak current, and the method takes advantage of the peculiar properties and good ability of texture and structure regulation that the niobic acid nanosheet has.

摘要翻译： 连接单层或多层铌酸纳米片以形成电介质膜，其它电极布置在电介质膜的表面上以构成电介质元件，由此提供的电介质元件即使实现了高电容率和良好的绝缘性能 在纳米区域。 还提供了在低温下制造元件的方法，而不影响基板界面劣化及其组成偏差。 该方法完全解决了基板界面退化和伴随的组成偏差和电不相容性的问题，解决了膜厚降低到纳米级的“尺寸效应”的内在问题，降低了比电容率并增加了漏电流， 该方法利用铌酸纳米片具有的特殊性质和良好的织构和结构调节能力。

公开(公告)号：US20110114175A1

公开(公告)日：2011-05-19

申请号：US12737370

申请日：2009-07-13

申请人： Tadashi Ozawa ,  Takayoshi Sasaki

发明人： Tadashi Ozawa ,  Takayoshi Sasaki

IPC分类号： H01L31/0232 ,  H01J1/62 ,  C09K11/78 ,  H01L31/04 ,  B82Y20/00

CPC分类号： C09K11/7729 ,  C01G35/006 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/24 ,  C09D5/22 ,  H01L31/02322

摘要： The invention provides a novel luminescent nanosheet, and applications to that luminescent nanosheet. The invention also breaks down conventional common knowledge of nanosheet solutions to provide a nanosheet paint that makes use of a high-concentration nanosheet solution suitable for dispersion of a luminescent nanosheet or the like.The invention provides a luminescent nanosheet having perovskite octahedral crystals combined together in a planar configuration, characterized in that the octahedral crystals each have a multistacked crystal sheet structure wherein the octahedral crystals are multistacked over at least 3 high in the direction vertical to a sheet plane, and an element providing a luminescence center is solid-solubilized between the multistacked octahedral crystals (see FIG. 8).The invention also provides a nanosheet paint having a nanosheet dispersed in a disperse medium, characterized in that an X value in the following equation 1 found from the vapor pressure of the disperse medium and the concentration of the nanosheet is in a range of less than 4.9×106 to greater than 3.8×103: X=C×V4.01   1 where C is the concentration (M) of the nanosheet, and V is the saturation vapor pressure (torr) of the solvent at 25° C. and 1 atm.

摘要翻译： 本发明提供了一种新型发光纳米片，以及该发光纳米片的应用。 本发明还分解了纳米片溶液的常规常识，以提供使用适合于发光纳米片等的分散的高浓度纳米片溶液的纳米片涂料。 本发明提供了一种具有以平面构型组合在一起的钙钛矿八面体晶体的发光纳米片，其特征在于，所述八面体晶体各自具有多层结晶片结构，其中所述八面体晶体在垂直于片材平面的方向上至少高3个以上， 并且提供发光中心的元件在多层八面体晶体之间固溶（参见图8）。 本发明还提供一种具有分散在分散介质中的纳米片的纳米片涂料，其特征在于根据分散介质的蒸汽压力和纳米片的浓度得到的下列等式1中的X值在小于4.9的范围内 ×106〜大于3.8×103：X = C×V4.01 1其中C是纳米片的浓度（M），V是溶剂在25℃和1atm下的饱和蒸气压（托） 。

公开(公告)号：US20100279848A1

公开(公告)日：2010-11-04

申请号：US12734955

申请日：2008-12-02

申请人： Nobuo Iyi ,  Takayoshi Sasaki

发明人： Nobuo Iyi ,  Takayoshi Sasaki

IPC分类号： B01J37/30

CPC分类号： C01F7/005 ,  B01D53/62 ,  B01D2251/40 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2253/104 ,  B01D2253/112 ,  B01D2257/504 ,  B01J20/0277 ,  B01J20/041 ,  B01J20/043 ,  B01J20/06 ,  B01J20/08 ,  B01J41/10 ,  C01G9/006 ,  C01G53/006 ,  C01P2002/22 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/03 ,  C02F2001/422 ,  Y02C10/04 ,  Y02P20/152

摘要： The invention has for its object to provide a preparation method for preparing an anion-exchangeable LDH by decarbonation of a carbonate ion type LDH, which makes sure de carbonation is implemented with safety in a continuous manner while crystal shape, crystal structure and crystallinity are kept intact.The invention provides a preparation method for preparing an anion-exchangeable, layered double hydroxide wherein a carbonate ion type layered double hydroxide (LDH) having a composition represented by a general formula: QxR(OH)z(CO32−)0.5-y/2(X−)y.nH2O where x is indicative of a numeral range of 1.8≦x≦4.2; z is indicative of 2(x+1); y is indicative of a minimum value of at least 0 that increases to less than 1 when anions (X−) remain or a part of anions is introduced; Q is a divalent metal ion; R is a trivalent metal ion; and n is 2±2 is used as a starting material, and y in said general formula increases to a maximum of 1 by substitution of a minus monovalent anion (X−1) at a carbonate ion site thereby implementing substitution, characterized in that the starting material is dispersed in an aqueous solution mixed with a salt containing minus monovalent anions (X−) in an amount enough for substitution at the carbonate ion site while said aqueous solution is kept at a pH (hydrogen ion exponent) of greater than 4 to less than 7.

摘要翻译： 本发明的目的是提供一种通过碳酸根离子型LDH的脱碳制备可阴离子交换的LDH的制备方法，其确保以连续方式安全地进行脱碳酸化，同时保持晶体形状，晶体结构和结晶度 完整。 本发明提供一种制备阴离子交换性层状双氢氧化物的制备方法，其中具有由以下通式表示的组成的碳酸根离子型层状双氢氧化物（LDH）：QxR（OH）z（CO32-）0.5-y / 2 （X）y.nH 2 O其中x表示数值范围为1.8＆amp; nlE; x＆nlE; 4.2; z表示2（x + 1）; y表示当阴离子（X）保留或部分阴离子被引入时，至少为0的最小值增加到小于1; Q是二价金属离子; R是三价金属离子; 并且使用n为2±2作为起始原料，通过在碳酸根离子位置取代负一价阴离子（X-1）从而实现取代，所述通式中的y增加到最大值1，其特征在于： 将原料分散在与含有负一价阴离子（X-X）的盐混合的水溶液中，其量足以在碳酸盐离子位置进行取代，同时所述水溶液保持在大于4至大约4的pH（氢离子指数）至 小于7。

公开(公告)号：US20100226067A1

公开(公告)日：2010-09-09

申请号：US12448528

申请日：2007-12-20

申请人： Minoru Osada ,  Yasuo Ebina ,  Takayoshi Sasaki

发明人： Minoru Osada ,  Yasuo Ebina ,  Takayoshi Sasaki

IPC分类号： H01G4/08 ,  B32B37/00 ,  B32B38/10

CPC分类号： H01L27/10873 ,  C04B35/016 ,  C04B35/462 ,  C04B35/495 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3227 ,  C04B2235/3251 ,  C04B2235/3262 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3296 ,  C04B2235/764 ,  H01G4/1209 ,  H01G4/33 ,  H01L21/31691 ,  H01L27/1085 ,  H01L28/55 ,  H01L29/513 ,  H01L29/517 ,  Y10T156/10

摘要： Provided is a dielectric element comprising a dielectric thin film formed of a layer of perovskite nanosheets. The dielectric element has the advantages of inherent properties and high-level texture and structure controllability of the perovskite nanosheets, therefore realizing both a high dielectric constant and good insulating properties in a nano-region.

摘要翻译： 提供一种电介质元件，其包括由钙钛矿纳米片层形成的电介质薄膜。 电介质元件具有钙钛矿纳米片的固有性质和高水平织构和结构可控性的优点，因此在纳米区域既实现了高介电常数又具有良好的绝缘性能。

公开(公告)号：US20080311429A1

公开(公告)日：2008-12-18

申请号：US12135472

申请日：2008-06-09

申请人： Tadao KATSURAGAWA ,  Takayoshi Sasaki ,  Minoru Osada

发明人： Tadao KATSURAGAWA ,  Takayoshi Sasaki ,  Minoru Osada

IPC分类号： G11B5/66 ,  G11B5/706

CPC分类号： G11B11/10545 ,  G11B5/65 ,  G11B11/10584 ,  G11B11/10586 ,  H01F10/193 ,  H01F10/265 ,  Y10T428/12056 ,  Y10T428/12201 ,  Y10T428/12465

摘要： The disclosure provides a magnetic film which includes a titania nanosheet which is formed on a transparent substrate and contains a layered titanium oxide in which at least one magnetic element is substituted for a Ti lattice position, the titanium oxide being expressed by a formula: Ti2-xMxO4 where M is at least one kind of transition metal elements chosen from among V, Cr, Mn, Fe, Co, Ni, and Cu, and 0

摘要翻译： 本发明提供一种磁性膜，其包括二氧化钛纳米片，该二氧化钛纳米片形成在透明基板上并且含有至少一个磁性元素代替Ti晶格位置的层状氧化钛，所述氧化钛由下式表示：Ti2- xMxO4其中M是选自V，Cr，Mn，Fe，Co，Ni和Cu中的至少一种过渡金属元素，0

公开(公告)号：US06534176B2

公开(公告)日：2003-03-18

申请号：US09729822

申请日：2000-12-06

申请人： Kunihiko Terase ,  Masaki Inoue ,  Atsunari Fujii ,  Takayoshi Sasaki ,  Shikou Minohara ,  Yoshimi Ohba

发明人： Kunihiko Terase ,  Masaki Inoue ,  Atsunari Fujii ,  Takayoshi Sasaki ,  Shikou Minohara ,  Yoshimi Ohba

IPC分类号： C09C104

CPC分类号： C09J11/04 ,  C01B33/12 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2996 ,  Y10T428/2998 ,  Y10T428/31627 ,  Y10T428/31656 ,  Y10T428/31794

摘要： Scaly silica particles having a laminated structure, consisting essentially of secondary particles of foliar silica, each formed by a plurality of flaky primary particles of scaly silica which are overlaid one on another and aligned face-to-face in parallel with one another, said secondary particles being present independent of one another.

摘要翻译： 具有叠层结构的鳞状二氧化硅颗粒，主要由叶片二氧化硅的二次颗粒组成，各自由鳞片状二氧化硅的多个片状原始颗粒形成，它们彼此重叠并彼此平行地对齐，所述二次 颗粒彼此独立存在。

公开(公告)号：US5746002A

公开(公告)日：1998-05-05

申请号：US710557

申请日：1996-09-19

申请人： Hiroshi Murakami ,  Masanori Tsutsui ,  Katsumi Asai ,  Takayoshi Sasaki

发明人： Hiroshi Murakami ,  Masanori Tsutsui ,  Katsumi Asai ,  Takayoshi Sasaki

IPC分类号： G01B5/00 ,  F16C33/14 ,  G01B5/02 ,  G01B21/02 ,  G01B21/32 ,  G01B5/06 ,  G01B13/02 ,  G01B121/20

CPC分类号： F16C33/14 ,  G01B21/32

摘要： A measuring apparatus for speedily measuring a bearing height is disclosed. A plunger of a movable cylinder is extended with a test load P by a constant pressure applying mechanism S. The movable cylinder is ascended from a receded position to a measuring position by a slide cam. A bearing half W disposed on a pushing member is fitted in a receiving cavity of a standard tool in such a manner that an end of the bearing half W slightly protrudes from the receiving cavity portion. When the movable cylinder slightly exceeds the measuring position, a plunger is pressed for the length of the end protruded from the receiving cavity portion. At this point, the bearing half W is held with the test load P. Thus, the bearing height can be immediately measured by a length sensor.

摘要翻译： 公开了一种用于快速测量轴承高度的测量装置。 可移动气缸的柱塞通过恒压施加机构S由试验载荷P延伸。可动气缸通过滑动凸轮从后退位置上升到测量位置。 设置在推动构件上的轴承半体W以使得轴承半体W的端部从容纳腔部分稍微突出的方式装配在标准工具的容纳腔中。 当可动圆筒稍微超过测量位置时，在从接收腔部分突出的端部的长度处按压柱塞。 此时，轴承半部W与试验载荷P保持一致。因此，可以通过长度传感器立即测量轴承高度。

公开(公告)号：US09082551B2

公开(公告)日：2015-07-14

申请号：US14118354

申请日：2012-05-18

申请人： Minoru Osada ,  Yasuo Ebina ,  Takayoshi Sasaki

发明人： Minoru Osada ,  Yasuo Ebina ,  Takayoshi Sasaki

IPC分类号： H01G4/10 ,  H01L49/02 ,  B82Y30/00 ,  H01L21/02 ,  B32B18/00 ,  C04B35/495 ,  C04B35/626 ,  C01G33/00 ,  H01L21/8234 ,  H01L27/08

CPC分类号： H01G4/10 ,  B32B18/00 ,  B82Y30/00 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/34 ,  C01P2004/24 ,  C01P2006/40 ,  C04B35/495 ,  C04B35/62685 ,  C04B2235/3201 ,  C04B2235/3208 ,  C04B2235/768 ,  C04B2237/34 ,  C04B2237/345 ,  C04B2237/704 ,  H01L21/02197 ,  H01L21/02285 ,  H01L21/823462 ,  H01L27/0805 ,  H01L28/56 ,  Y10T156/10

摘要： A high dielectric nanosheet laminate is produced by laminating nanosheets, each of which has a thickness of 10 nm or less and is formed of an oxide that has a perovskite structure wherein at least four NbO6 octahedrons, TaO6 octahedrons or TiO6 octahedrons are included in a unit lattice. Consequently, the high dielectric nanosheet laminate is capable of achieving a high dielectric constant and a satisfactory insulation property, which are preferable for high dielectric nanosheet multilayer capacitors or the like, at the same time even if formed very thin.

摘要翻译： 高介电纳米片层叠体通过层压纳米片而制成，每个纳米片的厚度为10nm以下，由具有钙钛矿结构的氧化物形成，其中至少四个NbO 6八面体，TaO 6八面体或TiO 6八面体包含在单元中 格子。 因此，高电介质纳米片层叠体即使形成得非常薄，也能够实现高介电常数和令人满意的绝缘性，这对于高介电纳米片多层电容器等是优选的。

公开(公告)号：US09012354B2

公开(公告)日：2015-04-21

申请号：US12526150

申请日：2008-02-08

申请人： Christopher Cordonier ,  Tetsuya Shichi ,  Kenichi Katsumata ,  Yasuhiro Katsumata ,  Akira Fujishima ,  Takafumi Numata ,  Takayoshi Sasaki

发明人： Christopher Cordonier ,  Tetsuya Shichi ,  Kenichi Katsumata ,  Yasuhiro Katsumata ,  Akira Fujishima ,  Takafumi Numata ,  Takayoshi Sasaki

IPC分类号： B01J35/00 ,  B01J23/20 ,  B01J37/02 ,  C03C17/25 ,  C03C21/00

CPC分类号： B01J35/004 ,  B01J23/20 ,  B01J37/0215 ,  C03C17/25 ,  C03C21/001 ,  C03C2217/218 ,  C03C2217/228 ,  C03C2217/23 ,  C03C2217/71 ,  C03C2218/111

摘要： Disclosed is a method for forming a photocatalyst thin film, which is characterized in that a photocatalyst thin film containing a niobium-alkali metal complex oxide is formed by forming and then firing a layer containing a niobia nanosheet on the surface of a base containing an alkali metal.

摘要翻译： 公开了形成光催化剂薄膜的方法，其特征在于，通过在含有碱的碱的表面上形成并焙烧含有铌氧化物纳米片的层来形成含有铌 - 碱金属络合氧化物的光催化剂薄膜 金属。