TOTAL ORGANIC CARBON (TOC) REDUCTION IN BRINE VIA CHLORINOLYSIS
    21.
    发明申请
    TOTAL ORGANIC CARBON (TOC) REDUCTION IN BRINE VIA CHLORINOLYSIS 审中-公开
    总有机碳(TOC)通过氯化锌在锌中的还原

    公开(公告)号:US20100193443A1

    公开(公告)日:2010-08-05

    申请号:US12670142

    申请日:2008-08-18

    CPC分类号: C01D3/14 C01B11/062 C01D3/16

    摘要: A plurality of stages is employed to reduce the total organic carbon (TOC) content of a brine by-product stream to produce a recyclable brine stream having a TOC content of less than about 10 ppm. In a first stage treatment, a brine by-product stream may be subjected to chlorinolysis at a temperature of less than about 125 0C to obtain a chlorinolysis product having a TOC content of less than about 100 ppm, which may be treated in a second stage with activated carbon to obtain a TOC content of less than about 10 ppm. The chlorinolysis may be a reaction with sodium hypochlorite, which may be produced in situ by treatment of the brine by-product stream with chlorine gas and sodium hydroxide. The brine by-product stream may contain a high amount of difficult to remove glycerin, such as a brine by-product stream from the production of epichlorohydrin from glycerin.

    摘要翻译: 采用多个阶段来降低盐水副产物流的总有机碳(TOC)含量,以产生TOC含量小于约10ppm的可再循环盐水。 在第一阶段处理中,盐水副产物流可以在小于约125℃的温度下进行氯解,得到TOC含量小于约100ppm的氯解产物,其可以在第二阶段 用活性炭获得小于约10ppm的TOC含量。 氯解可能是次氯酸钠的反应,其可以通过用氯气和氢氧化钠处理盐水副产物流而原位产生。 盐水副产物流可能含有大量难以除去甘油,例如从丙三醇生产表氯醇的盐水副产物流。

    Chromium-containing catalysts for polymerizing olefins
    26.
    发明授权
    Chromium-containing catalysts for polymerizing olefins 失效
    用于聚合烯烃的含铬催化剂

    公开(公告)号:US4362654A

    公开(公告)日:1982-12-07

    申请号:US263642

    申请日:1981-05-14

    CPC分类号: B01J23/26 C08F10/00

    摘要: Inorganic oxide supported chromium-containing catalysts are improved by depositing the chromium onto the inorganic oxide support in the vapor phase rather than as an inorganic or organic compound. Polymers resulting from polymerizing one or more .alpha.-olefins in the presence of such catalysts exhibit a higher molecular weight as compared to those polymers prepared in the presence of such chromium-containing catalysts prepared in the conventional manner.

    摘要翻译: 无机氧化物负载的含铬催化剂通过将铬沉积在气相中的无机氧化物载体上而不是无机或有机化合物而得到改善。 与在常规方法制备的这种含铬催化剂存在下制备的那些聚合物相比,在这种催化剂存在下聚合一种或多种α-烯烃产生的聚合物表现出较高的分子量。

    Method of disposing of spent organic complexing solutions containing
cuprous halides
    27.
    发明授权
    Method of disposing of spent organic complexing solutions containing cuprous halides 失效
    处理含有卤化铜的废有机络合溶液的方法

    公开(公告)号:US4249939A

    公开(公告)日:1981-02-10

    申请号:US109376

    申请日:1980-01-03

    IPC分类号: C22B15/00 C22B15/12

    摘要: Copper is removed from spent solutions of complexing agents containing cuprous aluminum tetrahalide, such as CuAlCl.sub.4.toluene by (1) contacting said solutions with water so as to form a precipitate of cuprous halide, an aqueous phase and an organic phase; (2) oxidizing the cuprous halide to cupric halide thereby rendering it water soluble; (3) separating the organic phase and aqueous phase, (4) contacting the aqueous phase with an environmentally suitable metal higher than copper from the electromotive series, such as aluminum, thereby precipitating copper metal and (5) separating the precipitated copper metal from the aqueous salt-containing mixture.Alternatively, the spent complex solutions can be contacted with 1 molar to 6 molar aqueous solution of a non-oxidizing acid such as HCl thereby eliminating the necessity of the oxidizing step (2) since the cuprous halide is soluble in the acidified aqueous phase.

    摘要翻译: 通过(1)使所述溶液与水接触以形成卤化亚铜,水相和有机相的沉淀物,从含有四卤化亚铜铝(例如CuAlCl 4·甲苯)的络合剂的废溶液中除去铜。 (2)将卤化亚铜氧化为二卤化铜,使其呈水溶性; (3)分离有机相和水相,(4)使水相与电动系列如铝等高于铜的环境合适的金属接触,从而沉淀铜金属,(5)将沉淀的铜金属从 含水盐混合物。 或者,废复合溶液可以与1摩尔至6摩尔的非氧化性酸如HCl的水溶液接触,从而消除氧化步骤(2)的必要性,因为卤化亚铜可溶于酸化水相。

    Vehicular glass adhesive and method of adhering said glass
    28.
    发明授权
    Vehicular glass adhesive and method of adhering said glass 有权
    汽车玻璃粘合剂和粘附玻璃的方法

    公开(公告)号:US08729168B2

    公开(公告)日:2014-05-20

    申请号:US13093013

    申请日:2011-04-25

    IPC分类号: C08K5/00

    摘要: The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.

    摘要翻译: 本发明是一种粘合剂组合物,其包含:a)具有约10,000至约80,000g /摩尔的z分子量平均值(Mz)的异氰酸酯官能聚醚基预聚物; 平均吸油量为每100克炭黑至少约80至至多约400立方厘米邻苯二甲酸二丁酯的炭黑; (c)反应性硅,其量为粘合剂组合物重量的约0.001%至约10%; 和(d)用于使异氰酸酯与羟基反应的一种或多种催化剂。 当加热时,本发明的粘合剂组合物令人惊奇地具有改善的下垂性能(即,减小的下垂),同时也使它们更容易地泵送。