公开(公告)号：US20160347871A1

公开(公告)日：2016-12-01

申请号：US14948734

申请日：2015-11-23

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Jeffrey M. Sullivan

IPC: C08F2/58 ,  C09J4/00 ,  C08L35/02 ,  C08K3/04 ,  C08F2/38 ,  C08F2/44

CPC classification number: C25B3/10 ,  C08F2/38 ,  C08F2/44 ,  C08F2/58 ,  C08F20/16 ,  C08K3/04 ,  C08K3/36 ,  C08K5/42 ,  C08L35/02 ,  C08L2201/10 ,  C09J4/00 ,  C25B9/04 ,  C25B9/06

Abstract: Electropolymerizable compositions are disclosed. Certain electropolymerizable compositions include one or more 1,1-disubstituted alkene compounds and one or more conductive synergists. Other certain electropolymerizable compositions include one or more 1,1-disubstituted alkene compounds and one or more acid stabilizers and one or more free radical stabilizers.

Abstract translation: 公开了可电聚合的组合物。 某些电聚合组合物包括一种或多种1,1-二取代烯烃化合物和一种或多种导电增效剂。 其它某些电聚合组合物包括一种或多种1,1-二取代烯烃化合物和一种或多种酸稳定剂和一种或多种自由基稳定剂。

公开(公告)号：US09334430B1

公开(公告)日：2016-05-10

申请号：US14725532

申请日：2015-05-29

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Aniruddha Sudhir Palsule ,  Jeffrey M. Sullivan

IPC: C08K9/10 ,  C09J135/02 ,  C08K3/00 ,  C08K5/00

CPC classification number: C09J135/02 ,  C08F222/14 ,  C08K3/01 ,  C08K5/0008 ,  C08K5/11 ,  C08L27/06 ,  C09J4/06

Abstract: An encapsulated initiator particle includes one or more polymerization initiators encapsulated by a cured composition. The cured composition includes one or more 1,1-disubstituted alkene compounds. Polymerizable systems can include one or more encapsulated initiator particles and a polymerizable composition. The polymerizable composition can include one or more 1,1-disubstituted alkene compounds. Methods for forming an encapsulated initiator particle are also described herein.

Abstract translation: 包封的引发剂颗粒包括由固化的组合物包封的一种或多种聚合引发剂。 固化的组合物包括一种或多种1,1-二取代烯烃化合物。 可聚合体系可以包括一种或多种包封的引发剂颗粒和可聚合组合物。 可聚合组合物可以包括一种或多种1,1-二取代烯烃化合物。 本文还描述了形成包封的引发剂颗粒的方法。

公开(公告)号：US20160068621A1

公开(公告)日：2016-03-10

申请号：US14859992

申请日：2015-09-21

Applicant: Sirrus, Inc.

Inventor： Jeffrey M. Sullivan ,  Aniruddha Palsule ,  Alexander R. Holzer ,  Kshitij K. Parab ,  Ami Doshi

IPC: C08F22/10

CPC classification number: C08F22/10 ,  C07C69/593 ,  C08F2/06 ,  C08F222/14 ,  C09J135/02

Abstract: The disclosure relates to compositions containing 1,1-disubstituted alkene compounds capable of preparing polymers having glass transition temperatures above room temperature. The present teaching also relates to polymers prepared 1,1-disubstituted alkene compounds which exhibit glass transition temperatures of 60° C. The disclosure also relate to methods for enhancing the glass transition temperatures of polymers prepared from 1,1-disubstituted alkene compounds.

Abstract translation: 本公开涉及含有能够制备玻璃化转变温度高于室温的聚合物的1,1-二取代烯烃化合物的组合物。 本教导还涉及制备出玻璃化转变温度为60℃的1,1-二取代烯烃化合物的聚合物。本公开还涉及用于增强由1,1-二取代烯烃化合物制备的聚合物的玻璃化转变温度的方法。

公开(公告)号：US20160068616A1

公开(公告)日：2016-03-10

申请号：US14810741

申请日：2015-07-28

Applicant: Sirrus, Inc.

Inventor： Aniruddha Palsule ,  Alexander R. Holzer ,  Peter Rulon Stevenson ,  Kshitij Kishen Parab ,  Jeffrey M. Sullivan

IPC: C08F2/06 ,  C09J153/00 ,  C09J135/02

CPC classification number: C08F2/06 ,  B05D3/007 ,  C08F2/26 ,  C08F222/14 ,  C08F297/02 ,  C09D135/02 ,  C09D153/00 ,  C09J135/02 ,  C09J153/00

Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in a solution (for example using one or more solvents). Polymerization of 1,1-disubstituted alkene compounds in an solution provides opportunities to better control the polymerization compared with bulk polymerization. The solution polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US20150343415A1

公开(公告)日：2015-12-03

申请号：US14823581

申请日：2015-08-11

Applicant: Sirrus, Inc.

Inventor： Bernard Miles Malofsky ,  Adam Gregg Malofsky ,  Jeffrey M. Sullivan ,  Philip B. Kisanga ,  John Joseph Anderson ,  Michael Charles Milner Cockrem ,  Philip Jay Carlberg

IPC: B01J19/24 ,  B01J8/06

CPC classification number: B01J19/245 ,  B01J8/067 ,  B01J29/40 ,  B01J2208/00168 ,  B01J2208/065 ,  B01J2219/00033 ,  B01J2219/0004 ,  B01J2219/00087 ,  B01J2219/00177 ,  B01J2219/24 ,  C07C67/31 ,  C07C67/327 ,  C07C67/333 ,  C07C67/56 ,  C07C69/593 ,  C08F222/14 ,  C09D4/00 ,  C09J4/00

Abstract: Method to obtain methylene malonate and related monomers following a bis(hydroxymethyl) malonate pathway. A bis(hydroxymethyl) malonate intermediary is subsequently reacted (i.e., subjected to thermolysis) to provide a methylene malonate monomer species. A source of formaldehyde (e.g., formalin) is provided in the presence of a basic catalyst (e.g., calcium hydroxide), to which a malonate (e.g., diethyl malonate) is added under suitable reaction conditions to obtain the desired intermediary (e.g., dialkyl bis(hydroxymethyl) malonate). The intermediary is reacted (i.e., subjected to thermolysis) under suitable conditions in the presence of a suitable catalyst (e.g., a zeolite) to obtain a methylene malonate monomer. In an exemplary embodiment, the thermolysis reaction includes the addition of the bis(hydroxymethyl) malonate intermediary onto a heated catalyst. The reaction product is collected and purified. The disclosed methods may be performed in a continuous operation. Discrete steps may be performed by using modular units within a plant.

Abstract translation: 获得二（羟甲基）丙二酸酯途径后亚甲基丙二酸酯和相关单体的方法。 随后将双（羟甲基）丙二酸酯中间体反应（即进行热解）以提供亚甲基丙二酸酯单体种类。 在碱性催化剂（如氢氧化钙）的存在下提供甲醛源（如福尔马林），在合适的反应条件下加入丙二酸酯（如丙二酸二乙酯），得到所需的中间体（如二烷基 双（羟甲基）丙二酸酯）。 在合适的条件下，在合适的催化剂（例如沸石）的存在下，使中间体反应（即进行热解），得到亚甲基丙二酸酯单体。 在一个示例性实施方案中，热解反应包括在加热的催化剂上加入双（羟甲基）丙二酸酯中间体。 收集并纯化反应产物。 所公开的方法可以在连续操作中执行。 离散步骤可以通过使用工厂内的模块化单元来执行。

公开(公告)号：US20190202947A1

公开(公告)日：2019-07-04

申请号：US15857808

申请日：2017-12-29

Applicant: SIRRUS, INC.

Inventor： Jeffrey M. Sullivan ,  Aniruddha Palsule ,  Alexander R. Holzer ,  Kshitij K. Parab ,  Ami Doshi

IPC: C08F22/10 ,  C07C69/593 ,  C08F2/06 ,  C09J135/02 ,  C08F222/14

CPC classification number: C08F22/10 ,  C07C69/593 ,  C08F2/06 ,  C08F222/14 ,  C09J135/02

Abstract: The disclosure relates to compositions containing 1,1-disubstituted alkene compounds capable of preparing polymers having glass transition temperatures above room temperature. The present teaching also relates to polymers prepared 1,1-disubstituted alkene compounds which exhibit glass transition temperatures of 60° C. The disclosure also relate to methods for enhancing the glass transition temperatures of polymers prepared from 1,1-disubstituted alkene compounds.

公开(公告)号：US10150886B2

公开(公告)日：2018-12-11

申请号：US15638290

申请日：2017-06-29

Applicant: SIRRUS, INC.

Inventor： Aniruddha S. Palsule ,  Jeffrey M. Sullivan ,  Katherine E. Vanderpool ,  Alexander R. Holzer ,  Anushree Deshpande ,  John Klier

IPC: C09D167/06 ,  C08L67/06 ,  C08L33/14 ,  C09D133/06 ,  C08G63/00 ,  C08G63/78 ,  C12P7/62 ,  C08G63/553 ,  C08G63/676 ,  C09D167/02

Abstract: Compositions comprising a) one or more polyester macromers containing one or more chains of the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols; and b) one or more polymers having pendant Michael Addition donor groups. Disclosed are coating prepared from these compositions.

公开(公告)号：US10086355B2

公开(公告)日：2018-10-02

申请号：US15345976

申请日：2016-11-08

Applicant: SIRRUS, INC.

Inventor： Bernard Miles Malofsky ,  Adam Gregg Malofsky ,  Jeffrey M. Sullivan ,  Philip B. Kisanga ,  John Joseph Anderson ,  Michael Charles Milner Cockrem ,  Philip Jay Carlberg

IPC: B01J8/06 ,  B01J19/24 ,  B01J29/40 ,  C07C67/31 ,  C07C67/327 ,  C07C67/333 ,  C07C67/56 ,  C07C69/593 ,  C09J4/00 ,  C09D4/00 ,  C08F222/14

Abstract: Method to obtain methylene malonate and related monomers following a bis(hydroxymethyl) malonate pathway. A bis(hydroxymethyl) malonate intermediary is subsequently reacted (i.e., subjected to thermolysis) to provide a methylene malonate monomer species. A source of formaldehyde (e.g., formalin) is provided in the presence of a basic catalyst (e.g., calcium hydroxide), to which a malonate (e.g., diethyl malonate) is added under suitable reaction conditions to obtain the desired intermediary (e.g., dialkyl bis(hydroxymethyl) malonate). The intermediary is reacted (i.e., subjected to thermolysis) under suitable conditions in the presence of a suitable catalyst (e.g., a zeolite) to obtain a methylene malonate monomer. In an exemplary embodiment, the thermolysis reaction includes the addition of the bis(hydroxymethyl) malonate intermediary onto a heated catalyst. The reaction product is collected and purified. The disclosed methods may be performed in a continuous operation. Discrete steps may be performed by using modular units within a plant.

公开(公告)号：US09969819B2

公开(公告)日：2018-05-15

申请号：US15589364

申请日：2017-05-08

Applicant: Sirrus, Inc.

Inventor： Aniruddha Palsule ,  Alexander R. Holzer ,  Peter Rulon Stevenson ,  Kshitij Kishen Parab ,  Jeffrey M. Sullivan

IPC: C09J7/38 ,  C08F2/06 ,  C08F222/14 ,  C09J153/00 ,  C09J135/02

CPC classification number: C08F2/06 ,  B05D3/007 ,  C08F2/26 ,  C08F222/14 ,  C08F297/02 ,  C09D135/02 ,  C09D153/00 ,  C09J135/02 ,  C09J153/00

Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in a solution (for example using one or more solvents). Polymerization of 1,1-disubstituted alkene compounds in an solution provides opportunities to better control the polymerization compared with bulk polymerization. The solution polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US20170349781A1

公开(公告)日：2017-12-07

申请号：US15638290

申请日：2017-06-29

Applicant: SIRRUS, INC.

Inventor： Aniruddha S. Palsule ,  Jeffrey M. Sullivan ,  Katherine E. Vanderpool ,  Alexander R. Holzer ,  Anushree Deshpande ,  John Klier

IPC: C09D167/06 ,  C08L67/06 ,  C08G63/78 ,  C12P7/62 ,  C08G63/00

CPC classification number: C09D167/06 ,  C08G63/00 ,  C08G63/553 ,  C08G63/676 ,  C08G63/78 ,  C08L67/06 ,  C09D133/06 ,  C09D167/02 ,  C12P7/625 ,  C08L83/04 ,  C08L79/02

Abstract: Compositions comprising a) one or more polyester macromers containing one or more chains of the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols; and b) one or more polymers having pendant Michael Addition donor groups. Disclosed are coating prepared from these compositions.