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    Reactivating iridium-containing catalysts with hydrogen halide and oxygen
    21.
    发明授权
    Reactivating iridium-containing catalysts with hydrogen halide and oxygen 失效
    用卤化氢和氧气再活化含铱催化剂

    公开(公告)号：US4444897A

    公开(公告)日：1984-04-24

    申请号：US374978

    申请日：1982-05-05

    申请人： Shun C. Fung ,  Walter Weissman ,  James L. Carter ,  Walter S. Kmak

    发明人： Shun C. Fung ,  Walter Weissman ,  James L. Carter ,  Walter S. Kmak

    IPC分类号： B01J23/96 ,  B01J23/46 ,  B01J23/64 ,  C10G35/085

    CPC分类号： B01J23/96

    摘要： A process is disclosed for reactivating an agglomerated iridium-containing catalyst and particularly platinum-iridium on alumina reforming catalysts. The process includes contacting a substantially decoked agglomerated catalyst with a reducing gas such as hydrogen to reduce agglomerated iridium oxides present to the free metal, a hydrogen halide pretreatment step to increase the halogen level of the catalyst to about 1.3 weight percent and above, and a redispersion step involving hydrogen halide and elemental oxygen. Use of hydrogen halide and elemental oxygen in the redispersion treatment eliminates the need for use of elemental chlorine gas. If no iridium oxides are initially present, the hydrogen reduction step is optional.

    摘要翻译： 公开了一种重新激活含铱的催化剂，特别是在氧化铝重整催化剂上的铂 - 铱的方法。 该方法包括将基本上已经过的团聚的催化剂与诸如氢的还原气体接触以减少存在于游离金属中的附聚的铱氧化物，将催化剂的卤素水平提高至约1.3重量％以上的卤化氢预处理步骤，以及 再分散步骤涉及卤化氢和元素氧。 在再分散处理中使用卤化氢和元素氧消除了使用元素氯气的需要。 如果最初不存在氧化铱，氢还原步骤是任选的。

    Catalytic cracking process with simultaneous production of a low BTU fuel gas and catalyst regeneration
    22.
    发明授权
    Catalytic cracking process with simultaneous production of a low BTU fuel gas and catalyst regeneration 失效
    催化裂化过程同时生产低BTU燃料气体和催化剂再生

    公开(公告)号：US4421637A

    公开(公告)日：1983-12-20

    申请号：US332161

    申请日：1981-12-18

    申请人： Dane C. Grenoble ,  Walter Weissman

    发明人： Dane C. Grenoble ,  Walter Weissman

    IPC分类号： C01B3/36 ,  C01B3/38 ,  C10G11/04

    CPC分类号： C10G11/04 ,  C01B3/363 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0811 ,  C01B2203/1041 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1247 ,  C01B2203/1258 ,  Y02P20/584

    摘要： A process for catalytically cracking a hydrocarbon with simultaneous production of a low BTU fuel gas and catalyst regeneration comprising contacting a hydrocarbon feed, at elevated temperature and in a cracking zone, with a solid acid catalyst comprising a catalytic metal oxide component wherein said metal is selected from the group consisting essentially of (a) tungsten, niobium and mixtures thereof (b) mixture of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, said oxide component being supported on a silica-containing inorganic refractory metal oxide support having a silica content less than 50 wt. % of the total support, to produce a cracked product and a deactivated catalyst and regenerating the deactive catalyst to produce a low BTU gas rich in CO, a gas rich in H.sub.2, or both and recirculating the regenerated catalyst back to the cracking zone, said catalyst being steamed prior to use at a temperature at least 600.degree. C. In a preferred embodiment, the catalyst support will comprise a mixture of silica and .gamma.-alumina.

    摘要翻译： 一种同时生产低BTU燃料气体和催化剂再生的催化裂化烃的方法，包括使烃进料在升高的温度和在裂化区中与包含催化金属氧化物组分的固体酸催化剂接触，其中所述金属被选择 由（a）钨，铌及其混合物组成的组（b）（a）与钽，铪，铬，钛，​​锆及其混合物的混合物，所述氧化物组分负载在含二氧化硅的无机难熔金属 氧化物载体，其二氧化硅含量小于50wt。 产生裂化产物和失活的催化剂并再生该活性催化剂以产生富含CO，富含H 2的二氧化碳或二者的低BTU气体，并将再生催化剂再循环回裂化区，所述 催化剂在使用前在至少600℃的温度下蒸发。在优选的实施方案中，催化剂载体将包含二氧化硅和γ-氧化铝的混合物。

    Biomass conversion process
    24.
    发明授权
    Biomass conversion process 有权
    生物质转换过程

    公开(公告)号：US08658025B2

    公开(公告)日：2014-02-25

    申请号：US13038118

    申请日：2011-03-01

    申请人： Michael Siskin ,  Glen E. Phillips ,  Simon R. Kelemen ,  Walter Weissman

    发明人： Michael Siskin ,  Glen E. Phillips ,  Simon R. Kelemen ,  Walter Weissman

    IPC分类号： C10L1/02

    CPC分类号： C10B55/00 ,  C10B53/02 ,  C10B55/10 ,  C10B57/045 ,  C10B57/06 ,  C10G3/00 ,  C10G3/57 ,  C10G2300/1014 ,  C10G2300/1037 ,  C10G2300/708 ,  C10L1/00 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

    摘要： Biomass is used as a co-feed for a heavy petroleum oil coking process to improve the operation of the coking process and to utilize biomaterial for the production of transportation fuels. The coking process may be a delayed coking process or a fluidized bed coking process and in each case, the presence of the biomass will decrease the coke drying time so reducing coke handling problems in the unit besides forming a superior coke product. In the case of a fluidized bed coking process using a gasifier for the coke, the addition of an alkali metal salt improves the operation of the gasifier.

    摘要翻译： 生物质用作重石油炼焦过程的共同进料，以改善焦化过程的运行并利用生物材料生产运输燃料。 焦化方法可以是延迟焦化方法或流化床焦化方法，并且在每种情况下，生物质的存在将降低焦炭干燥时间，从而减少除了形成高级焦炭产物之外的单元中的焦炭处理问题。 在使用气化炉用于焦炭的流化床焦化方法的情况下，加入碱金属盐改善了气化器的操作。

    Sulfur oxide/nitrogen oxide trap system and method for the protection of nitrogen oxide storage reduction catalyst from sulfur poisoning
    25.
    发明授权
    Sulfur oxide/nitrogen oxide trap system and method for the protection of nitrogen oxide storage reduction catalyst from sulfur poisoning 有权
    硫氧化物/氮氧化物捕集系统和氮氧化物储存还原催化剂从硫中毒的保护方法

    公开(公告)号：US07389638B2

    公开(公告)日：2008-06-24

    申请号：US11179372

    申请日：2005-07-12

    申请人： Walter Weissman ,  El Mekki El Malki

    发明人： Walter Weissman ,  El Mekki El Malki

    IPC分类号： F01N3/00

    CPC分类号： F01N3/0814 ,  F01N3/035 ,  F01N3/0842 ,  F01N3/085 ,  F01N3/106 ,  F01N13/009 ,  F01N2240/40 ,  F01N2510/0684 ,  F01N2570/04 ,  F01N2610/04

    摘要： The present invention relates to an improved exhaust gas cleaning system and method for a combustion source comprising a hydrogen generation system, a sulfur oxides trap, and a nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning system and method of the present invention also provides for a water-gas-shift catalyst between the sulfur oxides trap and the NSR catalyst trap, and a clean-up catalyst downstream of the NSR catalyst trap. The invention provides also a sulfur trap regenerable at moderate temperatures with rich pulses, rather than at high temperatures. The improved exhaust gas cleaning system of the present invention provides for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NOx storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.

    摘要翻译： 本发明涉及一种用于燃烧源的改进的废气净化系统和方法，其包括氢气产生系统，硫氧化物捕集器和氮储存还原（NSR）催化剂阱。 本发明的改进的废气净化系统和方法还提供了硫氧化物捕集器和NSR催化剂捕集器之间的水煤气变换催化剂以及NSR催化剂捕集器下游的净化催化剂。 本发明还提供了在中等温度下可富含脉冲而不是在高温下可再生的硫阱。 本发明的改进的废气净化系统提供从硫阱中释放的硫通过氮氧化物捕集器，没有或少量存在和少量的NO x x储存和还原位点，这显着地改善了NSR 催化剂陷阱寿命和性能，以满足未来的排放标准。 所公开的废气清洁系统适用于在大部分操作周期内以稀薄空气/燃料比运行的内燃机（例如柴油，汽油，CNG）。

    Service station for serving requirements of multiple vehicle technologies
    26.
    发明申请
    Service station for serving requirements of multiple vehicle technologies 有权
    服务站用于满足多种车辆技术的要求

    公开(公告)号：US20070144605A1

    公开(公告)日：2007-06-28

    申请号：US11301199

    申请日：2005-12-12

    申请人： Alan Horowitz ,  Walter Weissman ,  Charles Schleyer

    发明人： Alan Horowitz ,  Walter Weissman ,  Charles Schleyer

    IPC分类号： B65B3/26

    CPC分类号： G06Q50/30 ,  B60L11/1824 ,  B67D2007/0444 ,  B67D2007/0446 ,  Y02T10/7005 ,  Y02T10/7072 ,  Y02T90/12 ,  Y02T90/121 ,  Y02T90/14 ,  Y02T90/16

    摘要： A service station is provided with a plurality of vehicle servicing islands including liquid fuel blending pumps for dispensing and blending fuel components from underground tanks for refueling standard gasoline engine driven vehicles, standard diesel engine vehicles, vehicles with engines requiring dual fuels, vehicles with HCCI engines requiring low octane gasoline blended with standard diesel fuel, and fuel cell powered vehicles having onboard reformers. Other service islands include pumps for dispensing compressed hydrogen to fuel cell powered vehicles that do not include onboard reformers. In addition, service islands are provided for recharging the batteries of pure electric powered vehicles.

    摘要翻译： 服务站设有多个车辆维修岛，包括液体燃料混合泵，用于分配和混合来自地下罐的燃料组分，用于加油标准汽油发动机驱动的车辆，标准柴油机车辆，具有需要双重燃料的发动机的车辆，具有HCCI发动机的车辆 需要与标准柴油混合的低辛烷值汽油，以及具有船上重整器的燃料电池动力车辆。 其他服务岛包括用于将压缩氢气分配给不包括机载重整器的燃料电池动力车辆的泵。 另外，提供服务岛用于为纯电动车辆的电池充电。

    Reactivation process for iridium-containing catalysts using low halogen flow rates
    28.
    发明授权
    Reactivation process for iridium-containing catalysts using low halogen flow rates 失效
    使用低卤素流速的含铱催化剂的再活化方法

    公开(公告)号：US4444895A

    公开(公告)日：1984-04-24

    申请号：US374976

    申请日：1982-05-05

    申请人： Shun C. Fung ,  Walter Weissman ,  James L. Carter

    发明人： Shun C. Fung ,  Walter Weissman ,  James L. Carter

    IPC分类号： B01J23/96 ,  B01J23/46 ,  B01J23/64

    CPC分类号： B01J23/96

    摘要： A process is described for reactivating agglomerated iridium-containing catalysts such as Pt-Ir on Al.sub.2 O.sub.3 reforming catalyst. The agglomerated catalyst is decoked to remove carbon deposits; treated with hydrogen to reduce metal oxides to the free metals; pretreated with hydrogen halide to provide at least about a 1.3 weight percent halide content; and treated with a low mass flow rate of chlorine of about one gram chlorine per 100 grams catalyst per hour. Use of a low mass halogen flow rate significantly retards ferrous metal corrosion and significantly reduces the quantity of chlorine normally used in achieving high redispersion values.

    摘要翻译： 描述了一种用于在Al 2 O 3重整催化剂上再结合含铱的催化剂如Pt-Ir的方法。 烧结催化剂以除去碳沉积物; 用氢气处理以将金属氧化物还原成游离金属; 用卤化氢预处理以提供至少约1.3重量％的卤化物含量; 并以每小时100克催化剂的约1克氯的低质量流量氯处理。 使用低质量卤素流速显着延缓黑色金属腐蚀，并显着降低通常用于实现高再分散值的氯的量。

    Process for producing low sulfur coke
    29.
    发明授权
    Process for producing low sulfur coke 失效
    生产低硫焦炭的方法

    公开(公告)号：US4007092A

    公开(公告)日：1977-02-08

    申请号：US559588

    申请日：1975-03-18

    申请人： William J. Metrailer ,  Walter Weissman

    发明人： William J. Metrailer ,  Walter Weissman

    IPC分类号： C10B55/10

    CPC分类号： C10B55/10

    摘要： A low sulfur coke product is obtained in an integrated fluid coking and gasification process in which an oxygen-containing gas is introduced into the upper portion of the gasification zone and steam is introduced into the lower portion of the gasification zone. The desired degree of coke desulfurization is controlled by controlling the thickness of the gasifier coke layer on the gaseous reactor leaving solids per pass.

    摘要翻译： 在其中将含氧气体引入气化区的上部并将蒸汽引入气化区的下部的集成流体焦化和气化过程中获得低硫焦炭产物。 焦炭脱硫的期望程度通过控制气态反应器上的气化器焦炭层的厚度来控制，每次通过留下固体。