Methods for selecting and applying a layer of Cu—Mn spinel phase to ZPGM catalyst systems for TWC application
    36.
    发明授权
    Methods for selecting and applying a layer of Cu—Mn spinel phase to ZPGM catalyst systems for TWC application 有权
    选择和应用一层Cu-Mn尖晶石相到ZPGM催化剂体系用于TWC应用的方法

    公开(公告)号:US09433930B2

    公开(公告)日:2016-09-06

    申请号:US14090809

    申请日:2013-11-26

    Inventor: Zahra Nazarpoor

    Abstract: The present disclosure relates to selecting the layer of applying ZPGM active phase in washcoat, or applying ZPGM active phase in overcoat, for achieving optimized performance and enhanced thermal stability. Applying ZPGM active phase catalyst in overcoat shows improvements compare to applying ZPGM active phase in washcoat. The selected active phase material may include a chemical composition that is substantially free from PGM, including a formulation of stoichiometric Cu—Mn spinel structure active phase deposited on Niobium-Zirconium support oxide. The selected active phase layer applied in overcoat may include a washcoat of alumina coated on a suitable ceramic substrate. The disclosed active phase may be applied in overcoat to maximize efficiency of catalyst systems, which may exhibit enhanced catalytic activity properties, which may stable after aging and under steady state and oscillating condition, showing optimized performance purifying gases in TWC condition.

    Abstract translation: 本公开涉及选择在修补基面涂层中施加ZPGM活性相的层,或在外涂层中施加ZPGM活性相,以实现优化的性能和增强的热稳定性。 与在涂层中应用ZPGM活性相相比,在外涂层中使用ZPGM活性相催化剂显示出改进。 选择的活性相材料可以包括基本上不含PGM的化学组合物,包括沉积在铌 - 锆担载氧化物上的化学计量的Cu-Mn尖晶石结构活性相的配方。 施加在外涂层中的所选活性相层可以包括涂覆在合适的陶瓷基底上的氧化铝的修补基面涂层。 所公开的活性相可以施加在外涂层中以使催化剂体系的效率最大化,其可以表现出增强的催化活性性质,其在老化和稳定状态和振荡条件之后可以稳定,在TWC条件下显示优化的性能净化气体。

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