摘要:
An oxidation-corrosion additive for enhancing the stability of PFPAEs which has the formula: wherein Q is —Rf or —S—Rf, Rf is a perfluoroalkyl or perfluoroalkylether group having 1 to 30 carbon atoms, x and y are integers, each having a value of 0-5, wherein the sum of x and y is in the range of 1 to 10. In the formula above, Rf may be linear or branched. The additive can be a single component or a mixture of components varying in the number and relative positions of x and y. The additive can be used alone or with other suitable additives in PFPAE base fluids.
摘要:
A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species selected from the group consisting of a metallic salt of an inorganic phosphoric acid, e.g. potassium phosphate, an amine salt of an inorganic phosphoric acid, e.g. octylamine phosphate, a metallic salt of an organic phosphoric acid, e.g. dipotassium lauryl phosphate, an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate, a metallic salt of an organic phosphonic acid, e.g. dipotassium oleyl phosphonate, an amine salt of an organic phosphonic acid, e.g. octylamine dilauryl phosphonate, a metallic salt of an organic phosphorous acid, e.g. sodium dioleyl phoshite, and an amine salt of an organic phosphorous acid, e.g. octylamene dioleyl phosphate.The refrigerating machine oil composition according to the present invention has excellent lubricating performance, enhances lubricity between an aluminum material and steel material, can suppress seizure and wear therebetween, does not bring about environmental pollution and thus is well suited as the lubricating oil for a refrigerating machine using, as the refrigerant, a hydrogen-containing Flon compound such as R134a.
摘要:
Phosphorus-free and ashless high-temperature aircraft and turbo engine lubricant that contains no halogens or hazardous substances is disclosed. The phosphorus-free lubricating oil may be prepared from pentaerythritol tetraester, methylolpropane triester, or their combinations, ashless dithiocarbamate additives, a dialkydiphenylamine, an alkylphenylnaphthylamine, a triazole derivative, a rest inhibitor or metal deactivator, and an anti-foam. The use of this lubricating oil in addition to its superior wear and friction performance over the standard lubricating oil provides a safe and an environmentally benign gas turbine engine oil for aircraft and turbo engines.
摘要:
New phosphazene derivatives, fully substituted by aromatic groups and perfluoropolyethereal chains, are utilized as stabilizers for oils and greases based on perfluoropoyethers. Such derivatives inhibit the degradation process affecting the perfluoropolyethereal chains when these are subjected to high temperatures in an oxidizing atmosphere and in the presence of metals, such as for example aluminium, titanium, vanadium and their alloys, or steels.
摘要:
The present invention provides a specific hybrid series of transition metal polymer matrix composite sets which create durable friction reducing, wear, and corrosion resistance characteristics which can be used in a powder or liquid form, or, which can be bonded to a desired surface at ambient temperature. The specific components are combinations of polytetrafluoroethylene and molybdenum disulfide, polytetrafluoroethylene and tungsten disulfide, or tungsten disulfide and molybdenum disulfide. This invention brings together the unique properties of organic chemistry (polytetrafluoroethylene) and inorganic chemistry (tungsten disulfide, or molybdenum disulfide). This invention creates a synergistic interaction which enhances the wear resistance properties of polytetrafluoroethylene while simultaneously improving the friction reducing properties of molybdenum disulfide, or tungsten disulfide. The material functionality of this invention is greatly improved over the individual friction-reducing and wear-resistance capabilities of its constituent components being use independently. The invention comprises varying mixture sets of polytetrafluoroethylene and molybdenum disulfide, polytetrafluoroethylene and tungsten disulfide, or molybdenum disulfide and tungsten disulfide, depending upon the desired friction and wear-resistance needed. This invention can be introduced into the lubrication of mechanical components in powder form, in a colloidal dispersion, or, can be applied and caused to bond directly to a substrate surface through a variety of mechanisms and manners to form a lubricious and wear-resistant layer ranging from 0.5 microns to 60 microns thick.
摘要:
A lubricant composition comprises a perfluorinated polyalkylether base fluid (PFPAE) and an oxidation-corrosion inhibiting amount of a perfluoro-substituted benzothiazole or bis-benzothiazole. The benzothiazole compound additive exhibits excellent solubility in the base fluid and possesses outstanding low volatility characteristics. As a result, the lubricant composition functions as a noncorrosive, stable material suitable for long term applications over a wide temperature range (-65.degree. F. to >600.degree. F.) in an oxidative environment.The perfluoro-substituted benzothiazoles and bis-benzothiazoles have the formula: Q--R.sub.f or Q--R.sub.f '--Q, wherein Q is ##STR1## wherein R.sub.f is a linear or branched perfluoroalkylether group containing at least one ether linkage and R.sub.f ' is a linear or branched perfluoroalkyleneeher group containing at least one ether linkage.In formulating the lubricant composition of this invention, an oxidation-corrosion inhibiting amount of the substituted benzothiazole is dissolved in the PFPAE base fluid. The amount of the benzothiazole employed generally ranges from about 0.05 to 5.0 weight percent, preferably about 0.5 to 2.0 weight percent, based on the weight of the base fluid. This provides a lubricant containing an amount of oxidation-corrosion inhibiting additive that is adequate for long term applications at elevated temperatures while maintaining excellent formulation stability after storage at low temperatures for long periods of time.
摘要:
New phosphazene derivatives, fully substituted by aromatic groups and perfluoropolyethereal chains, are utilized as stabilizers for oils and greases based on perfluoropolyethers. Such derivatives inhibit the degradation process affecting the perfluoropolyethereal chains when these are subjected to high temperatures in an oxidizing atmosphere and in the presence of metals, such as for example aluminum, titanium, vanadium and their alloys, or steels.
摘要:
Compounds which can be defined by the formula (I):CF.sub.3 --C.sub.n F.sub.2n --C.sub.m H.sub.2m --CH.sub.3 (I)wherein:n is a numeral comprised within the range of from 1 to 21;m is a numeral comprised within the range of from 3 to 25;n+m is a numeral equal to, or higher than, 18;with the chain of carbon atoms being either linear or branchedare used as agents affording sliding characteristics (ski-waxes) for skis, to be applied onto the ski sole, and/or to be incorporated inside the ski sole.A sliding composition is also disclosed, which contains a paraffinic wax and at least one compound with formula (I).
摘要翻译:可以由式(I)定义的化合物:CF 3 -C n F 2n-C m H 2m-CH 3(I)其中:n是1至21的范围; m为3〜25的数字; n + m是等于或高于18的数字; 碳链的直链或支链链用作提供滑雪特征的滑雪板(滑雪板),用于滑雪鞋,和/或被纳入滑雪鞋底内。 还公开了含有链烷烃蜡和至少一种式(I)化合物的滑动组合物。
摘要:
A rubber composition made of a diene rubber having such excellent properties as heat resistance and mechanical strength and organopolysiloxane or fluoropolymer as a lubricating substance. The lubricating substance may contain isocyanate or cyanate groups, which will react with the hydroxy groups which exist on the surface of a filler usually applied to the diene rubber, thus securely keeping the lubricating substance in the molecular structure of the composition. A liquid diene polymer containing hydroxy groups and having a good compatibility with the diene rubber may be further added to the composition so that its hydroxy groups will react with the isocyanate or cyanate groups in the lubricating substance.The liquid diene polymer may contain epoxy groups instead of hydroxy groups, whereas the lubricating substance containing such functional groups as amino, carboxyl, hydroxy or mercapto groups so that the exoxy groups in the former and the functional groups in the latter will react with each other. The composition may further contain an isocyanate compound containing isocyanate groups, with the liquid diene polymer containing hydroxy groups. In this arrangement, the hydroxy groups in the liquid diene polymer will be replaced with the isocyanate groups, which in turn will react with the functional groups in the lubricating substance.